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991.
New series of phenylantimony chloride and antimony chloride with Schiff base ligands, L1H and L2H having N∩S and N∩O donor systems were synthesized under microwave irradiation using a domestic microwave oven. The reaction time was brought down from hours to a few seconds with improved yield as compared with conventional heating. All the ligands and their antimony(III) derivatives were characterized on the basis of microanalysis, elemental analyses, molecular weight determinations and spectral studies including IR, NMR (1H and 13C) and electronic spectral studies. A distorted trigonal bipyramidal and pseudo‐octahedral geometry around the antimony atom was tentatively proposed for these derivatives. The compounds were screened in vitro against bacteria and fungi to test their antimicrobial property and in vivo in male albino rats to test their antifertility properties. The treatment with the ligands and their phenylantimony derivatives at dose levels of 20 mg per rat per day did not cause any significant change in body weight, but a significant reduction in the weights of reproductive organs was observed. Arrest of spermatogenesis was noted at various stages with production of primary spermatocytes (preleptotene and pachytene), secondary spermatocytes and step‐19 spermatids found to be decreased. Biochemical parameters of tissues, i.e. protein, sialic acid, cholesterol content of testes and seminal vesicular fructose also showed significant reduction. Further, the serum testosterone concentrations were also decreased after treatment with ligands and their antimony(III) derivatives. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
992.
K. Singh S.M. Pande S.W. Anwane S.S. Bhoga 《Applied Physics A: Materials Science & Processing》1998,66(2):205-215
2 SO4. The solid solubility limits up to x≤3 mole% for monovalent, x≤5.27 mole% for divalent and x≤3.63 mole% for trivalent cation
doped Ag2SO4 are set with XRD, SEM, IR and DSC techniques. A predominant dependence of conductivity on the ionic size of iso- and alio-valent
cations is observed. In particular, the conductivity enhances in both α and β phases, despite having a lower ionic-size dopant
cation (relative to that of Ag+) in the transition element cation doped Ag2SO4. Ca2+, Ba2+, Y3+ and Dy3+ doped samples show depature from the regular behaviour in the β-phase. The conductivity behaviour is discussed considering
ionic size, valence and electronic structure of the guest cations.
Received: 3 February 1997/Accepted: 27 May 1997 相似文献
993.
Manganese(III) acetate mediated oxidation of aporphines to oxoaporphines is described. The developed methodology was conveniently applied for the synthesis of naturally occurring oxoaporphine alkaloids, oxoglaucine, and atheroline, starting from commercially available boldine. 相似文献
994.
The influence of analyte mass concentration on determination of detection limits in X-ray fluorescence spectrometry has been investigated experimentally. Both the total reflection X-ray fluorescence (TXRF) and the conventional energy-dispersive X-ray fluorescence techniques have been used to derive the dependence of analyte mass concentration on the values of detection limits. Results obtained indicate that values of detection limits are optimum, or in other words, they are closer to the true detection limit of the technique, when analyte concentrations are in the range of 10 times of the detection limit. 相似文献
995.
The LR-115 type-II plastic track detector has been used for measuring the indoor radon levels in the dwellings of some villages of Punjab and Himachal Pradesh. In Punjab, the villages surveyed are Rampura Phul, Lehra Mahabat and Pitho (villages in Bathinda district), and Amritsar city. The average indoor radon levels in these areas are found to vary from 64 to 152 Bq/m3, which are quite within the safe limits recommended by International Commission on Radiological Protection (Ann. ICRP 23(2)). The indoor radon levels have also been measured in the dwellings of Hamirpur district of Himachal Pradesh. The villages surveyed in this area are Nukhel, Badarn, Galore-Khas, Har-Upper, Tikker Brahamana and Awah-Lower where radon concentration has been found to vary from 261 to 724 Bq/m3. These values are higher than the recommended limit. 相似文献
996.
997.
Misra N. L. Singh Mudher K. D. Venugopal V. 《Journal of Thermal Analysis and Calorimetry》2004,76(3):737-746
Preparation and characterization of four new hydrated alkali metal molybdates Na2Mo4O13·6H2O, K2Mo4O13·3H2O, Rb2Mo4O13·2H2O and Cs2Mo4O13·2H2O are described. The compounds were prepared by crystallizing the solution obtained by dissolving MoO3 and corresponding alkali metal carbonates A2CO3 or molybdate A2MoO4 in stoichiometric amount in distilled water. The hydrated molybdates were characterized by thermal (TG/DTA) and X-ray diffraction
(XRD) methods. The number of water molecules in the compounds were determined from their TG /DTA curves recorded in air and
identification of their dehydration products was done by XRD. The cell parameters of the compounds were obtained by indexing
their XRD patterns. Attempt to prepare the corresponding hydrated compound of lithium was not successful.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
998.
The paper treats the question of robust control of chaos in Chua’s circuit based on the internal model principle. The Chua’s diode has polynomial non-linearity and it is assumed that the parameters of the circuit are not known. A robust control law for the asymptotic regulation of the output (node voltage) along constant and sinusoidal reference trajectories is derived. For the derivation of the control law, the non-linear regulator equations are solved to obtain a manifold in the state space on which the output error is zero and an internal model of the k-fold exosystem (k = 3 here) is constructed. Then a feedback control law using the optimal control theory or pole placement technique for the stabilization of the augmented system including the Chua’s circuit and the internal model is derived. In the closed-loop system, robust output node voltage trajectory tracking of sinusoidal and constant reference trajectories are accomplished and in the steady state, the remaining state variables converge to periodic and constant trajectories, respectively. Simulation results are presented which show that in the closed-loop system, asymptotic trajectory control, disturbance rejection and suppression of chaotic motion in spite of uncertainties in the system are accomplished. 相似文献
999.
1000.
Debajyoti Choudhury Saurabh D. Rindani B. Ananthanarayan K. R. S. Balaji Debajyoti Choudhury Manuel Drees Shashikant Dugad Gautam Dutta Sukanta Dutta Naveen Gaur Ambar Ghosal Walter Grimus Ernest Ma Shubhendra Mohanty P. N. Pandita M. K. Parida Subhendu Rakshit Saurabh D. Rindani D. P. Roy Probir Roy Sarira Sahu N. N. Singh Sudhir K. Vempati Francesco Vissani 《Pramana》1998,51(1-2):305-311
This report summarises the activities of the working group on ‘Physics beyond the Standard Model’. The results of investigations
in incorporatingR-parity in grand unification, the possibility of a light charged Higgs boson in extension of MSSM and radiative generation
of neutral vector boson self-couplings within the MSSM are described. Also given is an account of activities in neutrino physics,
namely a proposal for a study of the atmospheric muon anomaly in deep underground mines, a field theoretic study of neutrino
oscillations and a mechanism to generate appropriate masses of three active plus one sterile neutrino species. 相似文献