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11.
The use of continuous-flow isotope-ratio mass spectrometry (CF-IRMS) as a tool in soil analysis has been assessed as part of a larger study using a number of geological techniques applied in a forensic context. Carbon and nitrogen isotopic ratios, delta13C and delta15N, have been analysed to investigate situations which have arisen from crime casework. Three questions have been addressed: the role of spatial variation found over the short-scale (less than 20 m), temporal variation over a period of almost 2 years, and the variation found between source soils and soil transferred to footwear soles during a simple one-stage transfer process. Results are presented for the three experiments. The use of carbon and nitrogen isotopes has been shown to be useful in discriminating between soil types and sample locations, even when sampling occurs at a different time (as might be the case with a crime scene). In cases of primary transfer (from a source soil by a one-stage transfer to another surface, in this case, shoes and boots), the combination of carbon and nitrogen isotope ratios is a valuable tool in discriminating between sites and in showing the relationship of the transferred samples to the relevant source soils. Used in combination with other analytical techniques, isotopic analysis may prove to be a useful tool in a forensic context. 相似文献
12.
13.
Thomas W. Gero Larry W. Jaques Richard P. Mays Debra H. Reid Dwight A. Shamblee Young S. Lo 《合成通讯》2013,43(3-4):553-559
A convenient method to prepare 5-halo-2-hydroxy-nicotinic acid is described. 相似文献
14.
Long JW Logan MS Rhodes CP Carpenter EE Stroud RM Rolison DR 《Journal of the American Chemical Society》2004,126(51):16879-16889
We have developed crystalline nanoarchitectures of iron oxide that exhibit superparamagnetic behavior while still retaining the desirable bicontinuous pore-solid networks and monolithic nature of an aerogel. Iron oxide aerogels are initially produced in an X-ray-amorphous, high-surface-area form, by adapting recently established sol-gel methods using Fe(III) salts and epoxide-based proton scavengers. Controlled temperature/atmosphere treatments convert the as-prepared iron oxide aerogels into nanocrystalline forms with the inverse spinel structure. As a function of the bathing gas, treatment temperature, and treatment history, these nanocrystalline forms can be reversibly tuned to predominantly exhibit either Fe(3)O(4) (magnetite) or gamma-Fe(2)O(3) (maghemite) phases, as verified by electron microscopy, X-ray and electron diffraction, microprobe Raman spectroscopy, and magnetic analysis. Peak deconvolution of the Raman-active Fe-O bands yields valuable information on the local structure and vacancy content of the various aerogel forms, and facilitates the differentiation of Fe(3)O(4) and gamma-Fe(2)O(3) components, which are difficult to assign using only diffraction methods. These nanocrystalline, magnetic forms retain the inherent characteristics of aerogels, including high surface area (>140 m(2) g(-1)), through-connected porosity concentrated in the mesopore size range (2-50 nm), and nanoscale particle sizes (7-18 nm). On the basis of this synthetic and processing protocol, we produce multifunctional nanostructured materials with effective control of the pore-solid architecture, the nanocrystalline phase, and subsequent magnetic properties. 相似文献
15.
A geometric graph is a simple graph drawn on points in the plane, in general position, with straightline edges. A geometric homomorphism from to is a vertex map that preserves adjacencies and crossings. This work proves some basic properties of geometric homomorphisms and defines the geochromatic number as the minimum n so that there is a geometric homomorphism from to a geometric n‐clique. The geochromatic number is related to both the chromatic number and to the minimum number of plane layers of . By providing an infinite family of bipartite geometric graphs, each of which is constructed of two plane layers, which take on all possible values of geochromatic number, we show that these relationships do not determine the geochromatic number. This article also gives necessary (but not sufficient) and sufficient (but not necessary) conditions for a geometric graph to have geochromatic number at most four. As a corollary, we get precise criteria for a bipartite geometric graph to have geochromatic number at most four. This article also gives criteria for a geometric graph to be homomorphic to certain geometric realizations of K2, 2 and K3, 3. © 2011 Wiley Periodicals, Inc. J Graph Theory 69:97‐113, 2012 相似文献
16.
Debra I. Johanning 《The Journal of Mathematical Behavior》2004,23(4):371-388
This study investigated how 31 sixth-, seventh-, and eighth-grade middle school students who had not previously, nor were currently taking a formal Algebra course, approached word problems of an algebraic nature. Specifically, these algebraic word problems were of the form x + (x + a) + (x + b) = c or ax + bx + cx = d. An examination of students’ understanding of the relationships expressed in the problems and how they used this information to solve problems was conducted. Data included the students’ written responses to problems, field notes of researcher-student interactions while working on the problems, and follow-up interviews. Results showed that students had many informal strategies for solving the problems with systematic guess and check being the most common approach. Analysis of researcher-student interactions while working on the problems revealed ways in which students struggled to engage in the problems. Support mechanisms for students who struggle with these problems are suggested. Finally, implications are provided for drawing upon students’ informal and intuitive knowledge to support the development of algebraic thinking. 相似文献
17.
We present a theory for the transport of molecules adsorbed in slit and cylindrical nanopores at low density, considering the axial momentum gain of molecules oscillating between diffuse wall reflections. Good agreement with molecular dynamics simulations is obtained over a wide range of pore sizes, including the regime of single-file diffusion where fluid-fluid interactions are shown to have a negligible effect on the collective transport coefficient. We show that dispersive fluid-wall interactions considerably attenuate transport compared to classical hard sphere theory. 相似文献
18.
Denis J. Evans E. G. D. Cohen Debra J. Searles F. Bonetto 《Journal of statistical physics》2000,101(1-2):17-34
A number of new relations between the Kaplan–Yorke dimension, phase space contraction, transport coefficients and the maximal Lyapunov exponents are given for dissipative thermostatted systems, subject to a small but non-zero external field in a nonequilibrium stationary state. A condition for the extensivity of phase space dimension reduction is given. A new expression for the linear transport coefficients in terms of the Kaplan–Yorke dimension is derived. Alternatively, the Kaplan–Yorke dimension for a dissipative macroscopic system can be expressed in terms of the linear transport coefficients of the system. The agreement with computer simulations for an atomic fluid at small shear rates is very good. 相似文献
19.
Nassimbeni Luigi R. Niven Margaret L. Stuart Debra A. Zemke Klaus J. 《Journal of chemical crystallography》1986,16(4):557-567
The crystal structure of the 21 channel complex of desoxycholic acid and ethyl acetate has been investigated at 298 and 163 K. The space group isP212121(No. 19) with four molecules of desoxycholic acid in the unit cell. The ethyl acetate molecules are enclathrated along the 21 axes parallel toc and exhibit differing degrees of disorder in the low- and room-temperature structures. Differences in the disorder imply that it is both statistical and dynamic in nature. Our best model for each structure yieldsR=0.064 [R
w
=0.058,w=(
2
F)–1] andR=0.068 [R
w
=0.064,w=(
2
F)
–1
] for the ambient- and low-temperature studies respectively.IUPAC Nomenclature: 3, 12-dihydroxy-5-cholan-24-oic acid. 相似文献
20.