Optical study of single crystals grown by the Czochralski method from Yb3+-doped (Gd1−x Y x )2SiO5 solid solution

Yb³⁺-doped crystals were grown by the Czochralski method from (Gd_0.5Y_0.5)₂SiO₅ melt employing seeds cut out from single crystals of Yb:Gd₂SiO₅ and Yb:Y₂SiO₅. XRD analysis revealed that the structure of the solid solution crystals grown is consistent with the structure of the seed, namely C2/c for the Yb:Y₂SiO₅ seed and P2₁/c for the Yb:Gd₂SiO₅ seed. Optical absorption spectra, emission spectra and luminescence decay curves were recorded at 10 K and 300 K. Analysis of gathered spectroscopic data made it possible to evaluate radiative transition rates for the ²F_5/2 multiplet of Yb³⁺ in the two structures and to assess crystal field splitting of multiplets involved in radiative transitions. It has been concluded that transition intensities and relaxation dynamics of Yb³⁺ in the systems studied are similar but the intensity distribution of emission and absorption bands depends significantly on the system structure. This feature, combined with inhomogeneous broadening of spectral lines, may be advantageous for the tailoring of lasers employing ytterbium-doped crystals for specific applications.     

The effect of 3-aminopropyltrimethoxysilane on the formation of NiFe2O4/SiO2 nanocomposites

NiFe₂O₄/SiO₂ nanocomposites were prepared using a sol–gel method with the addition of 3-aminopropyltrimethoxysilane (APS). Different phases and morphologies of NiFe₂O₄/SiO₂ nanocomposites were obtained when different amounts of APS were used. The structural properties of the products were examined by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Sheet-like morphology was observed at higher molar ratio of APS to NiFe₂O₄, while spherical NiFe₂O₄/SiO₂ nanoparticles separated from each other were formed at lower molar ratio of APS to NiFe₂O₄. The magnetic properties of the nanocomposites were also investigated, indicating that the interparticle interactions exhibit strong dependence on the molar ratio of APS to NiFe₂O₄.     

Improved multiparty quantum key agreement in travelling mode

The need to simultaneously balance security and fairness in quantum key agreement (QKA) makes it challenging to design a flawless QKA protocol, especially a multiparty quantum key agreement (MQKA) protocol. When designing an MQKA protocol, two modes can be used to transmit the quantum information carriers: travelling mode and distributed mode. MQKA protocols usually have a higher qubit efficiency in travelling mode than in distributed mode. Thus, several travelling mode MQKA protocols have been proposed. However, almost all of these are vulnerable to collusion attacks from internal betrayers. This paper proposes an improved MQKA protocol that operates in travelling mode with Einstein-Podolsky-Rosen pairs. More importantly, we present a new travelling mode MQKA protocol that uses single photons, which is more feasible than previous methods under current technologies.     

基于基数排序及属性约简的雷电预报因子提取方法

雷电预报因子筛选是构建雷电预报模型的关键,也是提高雷电预报准确度的一个瓶颈问题。本文提出了一种基于粗糙集正域属性约简的雷电预报因子提取方法,该方法采用基数排序方法快速求解决策表的正域,引入可分辨度概念度量属性的重要性,提出了基于可分辨度的核属性与非核属性的提取方法,设计了相应的面向雷电预报因子提取的属性约简算法。真实气象数据集测试结果表明,该方法能有效提取最小集合的雷电预报因子,并较以往方法具有更好的性能。     

35MeV/u 40 Ar+197 Au反应中热核的碎裂密度

许多提取核反应过程中熵产生的方法只适用于高能核反应过程 ,而约化d的产额方法可以用于较低能量的重离子核反应中 .对于 3 5MeV/u40 Ar+ 197Au的核反应过程 ,利用这种方法所得的熵和约化带电粒子多重性提取的熵结果一致 .对于后角热核发射体系 ,实验提取的核温度为 ( 4.7± 1 .2 )MeV ,熵为S/A =2 .5± 0 .5,根据实验提取的熵和核温度可以确定其碎裂密度小于 0 .1 ρ0     

钕配合物宽波段光声光谱研究

利用紫外－可见、近红外及中红外光声光谱对钕配合物的激发态能级状况、驰豫过程,荧光性质进行探讨,并深入研究了钕离子和配体对彼此光声谱峰移动和峰强度的影响。     

光学非球面面形拟合方法研究

作者在研制一台高精度检测非球面仪器的过程中,探讨了二次和高次非球面面形方程参数的拟合方法。计算实例表明,线性化拟合法和非线性拟合法较圆满地达到了各种非球面面形拟合精度和实时处理的要求。     

Sonochemical and sonophotocatalytic degradation of malachite green: the effect of carbon tetrachloride on reaction rates

A comparative study between the sonolytic, photocatalytic and sonophotocatalytic oxidation processes of aqueous solutions of malachite green was carried out in the presence of carbon tetrachloride, under a low power ultrasonic field (<15 W) and using titanium dioxide as a photocatalyst. The effect of a number of parameters such as ultrasonic intensity, TiO2 crystalline structure and the presence of CCl4 were studied using an inexpensive reactor. Enhanced rates of sonolytic degradation of malachite green in the presence of CCl4 were demonstrated. On the other hand, the simultaneous use of sonolysis and photocatalysis in the presence of CCl4 does not improve the degradation rate of malachite green in comparison with the one obtained using only sonolysis, but it makes possible a faster oxidative degradation of some reaction intermediaries. Finally, in air saturated solutions both processes, the sonolytic and the photocatalytic one, follow a first-order rate law.     

非晶InGaZnO薄膜成分配比对透明性和迁移率的影响

利用固相反应法制备了富铟含量在不同成分配比下的高质量InGaZnO陶瓷靶材,采用脉冲激光沉积法,在基片温度为20 ℃、氧压为1 Pa条件下,在石英玻璃衬底上生长了非晶InGaZnO薄膜,并对薄膜进行X射线衍射、透射吸收光谱、拉曼光谱与霍尔效应测试。通过对InGaZnO薄膜的测试表征,在较低温度条件下,铟含量较高的薄膜样品保持了非晶结构、可见光的高透明性和高电子迁移率,InGaZnO薄膜有望应用于电子器件。     

Inactivation of bovine immunodeficiency virus by photodynamic therapy with HMME

To investigate the effect of photodynamic therapy (PDT) with hematoporphrin monomethyl ether (HMME) on bovine immunodeficiency virus (BIV) can provide the basis theory for photoinactivation of human immunodeficiency virus (HIV). To assess the protection of HMME-PDT on the cell line Cf2Th infected with BIVR29 by 3-(4,5)-dimethylthiahiazol-2-yl-3,5-di-phenytetrazolium bromide (MTT) with power density of 5 and 25 mW/cm2 and energy density from 0.6 to 3 J/cm<'2>. To observe the inhibition of membrane fusion using a new reporter cell line BIVE by fluorescence microscope. HMME-PDT has significant protectant effects on Cf2Th-BIVR29 with both power densities, especially in the group of high power density. Fluorescent microscope shows that there is no significant difference between the group of PDT and control, which means PDT could not inhibit the BIV-mediated membrane fusion.