Chiral II-VI semiconductor nanostructure superlattices based on an amino acid ligand

Reaction of L-cysteine with M(NO3)2 x xH2O (M = Cd, Zn) generates M(L-cysteinate), which feature one-dimensional substructures that can be viewed as fragments of bulk structures of CdS (rock salt high pressure phase) and ZnS (wurtzite) because of the bridging modes accessible to the sulfur atom of L-cysteine. The MS substructures are arranged in a regular and periodic fashion within the crystal via the carboxylate function of L-cysteine. Considering the structural similarities with bulk materials, the optical properties of M(L-cysteinate) were studied and indicate blue shifts of the band gap of 2.59 eV (M = Cd, compared to CdS rock salt) and 1.37 eV (M = Zn, compared to ZnS wurtzite) with respect to the bulk MS structures, due to the low dimensionality of the metal-sulfur arrangement. The chelating nature of the cysteine ligand imposes an unusual mer arrangement of three binding S moieties at Cd with a correspondingly high Cd coordination number in a chalcogenide-based material. Density of states calculations show strong electronic structure similarities with the bulk phases and rationalize the band gap changes.     

Electronic structure, magnetic ordering, and formation pathway of the transition metal oxide hydride LaSrCoO(3)H(0.7)

The role of the hydride anion in controlling the electronic properties of the transition metal oxide hydride LaSrCoO(3)H(0.7) is investigated theoretically by full potential DFT band structure calculation and experimentally by determination of the Neel temperature for three-dimensional magnetic ordering. The mechanism by which hydrogen is introduced into the solid is addressed by in situ X-ray diffraction studies of the formation of the oxide hydride, which reveal both a relationship between the microscopic growth of the observed oxide hydride order and the anisotropic broadening of the diffraction profile, and the existence of a range of intermediate compositions.     

Generalized Weighted Morrey Estimates for Marcinkiewicz Integrals with Rough Kernel Associated with Schrödinger Operator and Their Commutators

Let L =-?+V(x) be a Schr?dinger operator, where ? is the Laplacian on ■~n,while nonnegative potential V(x) belonging to the reverse H?lder class. The aim of this paper is to give generalized weighted Morrey estimates for the boundedness of Marcinkiewicz integrals with rough kernel associated with Schr?dinger operator and their commutators.Moreover, the boundedness of the commutator operators formed by BMO functions and Marcinkiewicz integrals with rough kernel associated with Schr?dinger operators is discussed on the generalized weighted Morrey spaces. As its special cases, the corresponding results of Marcinkiewicz integrals with rough kernel associated with Schr?dinger operator and their commutators have been deduced, respectively. Also, Marcinkiewicz integral operators, rough Hardy-Littlewood(H-L for short) maximal operators, Bochner-Riesz means and parametric Marcinkiewicz integral operators which satisfy the conditions of our main results can be considered as some examples.     

Molecular orientation by surface forces: I. On the replication of surface forces by plastic materials

We have attempted to replicate the surface electrical profile of freshly cleaved sodium chloride crystals using materials with known electret characteristics such as; polyethylene; polyvinyl acetate; polymethyl methacrylate; polyvinyl chloride; polystyrene and carnauba wax. Only P.V.C. replicas exhibit surface orientational properties. A theory is presented to account for the orientation of polar organic molecules on polyvinyl chloride replicas of sodium chloride surfaces and evidence is reported for the existence of long range surface forces arising from gross crystallographic defects.     

Search for rare and forbidden Charm Meson decays D0 --> Vl+l- and hhll

We report results of a search for flavor-changing neutral current (FCNC), lepton flavor, and lepton-number violating decays of the D0 (and its antiparticle) into three and four bodies. Using data from Fermilab charm hadroproduction experiment E791, we examine modes with two leptons (muons or electrons) and a rho(0), K( *0), or straight phi vector meson or a nonresonant pi(pi), Kpi, or KK pair of pseudoscalar mesons. No evidence for any of these decays is found. Therefore, we present branching-fraction upper limits at 90% confidence level for the 27 decay modes examined (18 new).     

Study of the D(+)(s)-->pi(-)pi(+)pi(+) decay and measurement of f(0) masses and widths

From a sample of 848+/-44 D(+)(s)-->pi(-)pi(+)pi(+) decays, we find gamma(D(+)(s)-->pi(-)pi(+)pi(+))/gamma(D(+)(s)-->straight phipi(+)) = 0.245+/-0.028(+0.019)(-0.012). Using a Dalitz plot analysis of this three body decay, we find significant contributions from the channels rho(0)(770)pi(+), rho(0)(1450)pi(+), f(0)(980)pi(+), f(2)(1270)pi(+), and f(0)(1370)pi(+). We also present the values obtained for masses and widths of the resonances f(0)(980) and f(0)(1370).     

Wetting of mixed OHH(2)O layers on Pt(111)

We describe the effect of growth temperature and OHH(2)O composition on the wetting behavior of Pt(111). Changes to the desorption rate of ice films were measured and correlated to the film morphology using low energy electron diffraction and thermal desorption of chloroform to measure the area of multilayer ice and monolayer OHH(2)O exposed. Thin ice films roughen, forming bare (radical39 x radical39)R16 degrees water monolayer and ice clusters. The size of the clusters depends on growth temperature and determines their kinetic stability, with the desorption rate decreasing when larger clusters are formed by growth at high temperature. Continuous films of more than approximately 50 layers thick stabilize an ordered incommensurate ice film that does not dewet. OH coadsorption pins the first layer into registry with Pt, forming an ordered hexagonal (OH+H(2)O) structure with all the H atoms involved in hydrogen bonding. Although this layer has a similar honeycomb OH(x) skeleton to ice Ih, it is unable to reconstruct to match the bulk ice lattice parameter and does not form a stable wetting layer. Water aggregates to expose bare monolayer (OH+H(2)O), forming bulk ice crystallites whose size depend on preparation temperature. Increasing the proportion of water in the first layer provides free OH groups which stabilize the multilayer. The factors influencing multilayer wetting are discussed using density functional theory calculations to compare water adsorption on top of (OH+H(2)O) and on simple models for commensurate water structures. We show that both the (OH+H(2)O) structure and "H-down" water layers are poor proton acceptors, bonding to the first layer being enhanced by the presence of free OH groups. Formation of an ordered ice multilayer requires a water-metal interaction sufficient to wet the surface, but not so strong as to prevent the first layer relaxing to stabilize the interface between the metal and bulk ice.     

Chemical control of electronic structure and superconductivity in layered borides and borocarbides: understanding the absence of superconductivity in LixBC

The synthetic search for materials related to the 39 K superconductor MgB2 has been difficult. The most promising theoretical suggestion, hole doping of LiBC, does not lead to a new superconductor. We show here that a combination of density functional theory (DFT) calculations, materials synthesis, and structural characterization reveals the origin of the puzzling absence of superconductivity in Li1/2BC as a subtle change in the electronic structure driven by structural response to the introduction of holes. This indicates that the unique aspects of the electronic structure of MgB2 will be demanding to replicate in other systems.