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31.
Rudolph A. Abramovitch Suchet S. Mathur Daniel W. Saunders Danny P. Vanderpool 《Tetrahedron letters》1980,21(8):705-708
Pyridinium -toluenesulfonylmethylide serves as a formyl anion equivalent and, in the presence of an alcohol, undergoes 1,4-addition to -substituted maleimides to give alkoxy- (or aryloxy)-methylene-succinimides. The protected aldehyde group can be liberated readily. 相似文献
32.
U. Ritschel I. Stancu P. M. Stevenson 《Zeitschrift fur Physik C Particles and Fields》1992,54(4):627-634
In the conventional large-N limit the coupling constant is required to scale as 1/N. While the Gaussian effective potential (GEP) is known to contain the exact result in this limit, it shows a phase transition only when 1/N (in units of the renormalized mass in the symmetric vacuum). Here we determine the asymptotic behaviour, asN, of and other quantities at the phase transition of the GEP. We find crit to be finite in 0+1 dimensions; of order 1/lnN in 1+1 dimensions; 1/N
1/3 in 2+1 dimensions; and
in 3+1 dimensions. The GEP's first-order phase transition is shown to become asymptotically second-order in 1+1 dimensions and below. We also discuss non-integer dimensions and the approach to the non-trivial autonomous theory in 3+1 dimensions. 相似文献
33.
Danny K. Long Wolfgang Bangerth Derek R. Handwerk Christopher B. Whitehead Patrick D. Shipman Richard G. Finke 《Journal of computational chemistry》2022,43(1):43-56
In order to quantitatively predict nano- as well as other particle-size distributions, one needs to have both a mathematical model and estimates of the parameters that appear in these models. Here, we show how one can use Bayesian inversion to obtain statistical estimates for the parameters that appear in recently derived mechanism-enabled population balance models (ME-PBM) of nanoparticle growth. The Bayesian approach addresses the question of “how well do we know our parameters, along with their uncertainties?.” The results reveal that Bayesian inversion statistical analysis on an example, prototype nanoparticle formation system allows one to estimate not just the most likely rate constants and other parameter values, but also their SDs, confidence intervals, and other statistical information. Moreover, knowing the reliability of the mechanistic model's parameters in turn helps inform one about the reliability of the proposed mechanism, as well as the reliability of its predictions. The paper can also be seen as a tutorial with the additional goal of achieving a “Gold Standard” Bayesian inversion ME-PBM benchmark that others can use as a control to check their own use of this methodology for other systems of interest throughout nature. Overall, the results provide strong support for the hypothesis that there is substantial value in using a Bayesian inversion methodology for parameter estimation in particle formation systems. 相似文献
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Prof. Dr. Steven Stevenson Amanda J. Rothgeb Katelyn R. Tepper Prof. Dr. James Duchamp Prof. Dr. Harry C. Dorn Xian B. Powers Mrittika Roy Prof. Dr. Marilyn M. Olmstead Prof. Dr. Alan L. Balch 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(54):12545-12551
Purified samples of Ho3N@C2(22010)-C78 and Tb3N@C2(22010)-C78 have been isolated by two distinct processes from the rich array of fullerenes and endohedral fullerenes present in carbon soot from graphite rods doped with Ho2O3 or Tb4O7. Crystallographic analysis of the endohedral fullerenes as cocrystals with Ni(OEP) (in which OEP is the dianion of octaethylporphyrin) shows that both molecules contain the chiral C2(22010)-C78 cage. This cage does not obey the isolated pentagon rule (IPR) but has two sites where two pentagons share a common C−C bond. These pentalene units bind two of the metal ions, whereas the third metal resides near a hexagon of the cage. Inside the cages, the Ho3N or Tb3N unit is planar. Ho3N@C2(22010)-C78 and Tb3N@C2(22010)-C78 use the same cage previously found for Gd3N@C2(22010)-C78 rather than the IPR-obeying cage found in Sc3N@D3h-C78. 相似文献
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Cuprous acetylides react with aryl halides to yield aryl acetylenes and with o-halophenols to give benzofurans.1,2 The broad scope of this latter reaction for the synthesis of benzofuran natural products is shown by application inter alia to norlignans,3 euparinoids,4 phytoalexins,5 furanocoumarins,6 fomannoxin,7 isotubaic acid8 and machicendiol. 相似文献
40.
Danny Mortimer Matthew Whiting Joseph P.A. Harrity Simon Jones Iain Coldham 《Tetrahedron letters》2014
Lewis acid mediated intramolecular Mannich reaction between an azocinone and a 3-formylindole was investigated as part of a study towards the synthesis of actinophyllic acid. The intramolecular Mannich reaction resulted in a single diastereomer of the 1-azabicyclo[4.2.1]nonan-5-one core framework, although single crystal X-ray structure analysis revealed that this had the undesired stereochemistry in comparison with the natural product. 相似文献