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41.
Treatment of α-hydroxy-α-phenyl-o-toluidide with phosphorus tribromide afforded a series of 4H-3,1-benzoxazines. These last, when reacted with potassium amide in liquid ammonia, ring contracted to 2,3-disubstituted 3H-indol-3-ols. The scope of this rearrangement was examined. The indolols on treatment with hot base were found to rearrange to indoxyls. Several of these as well as their N-alkylation products are described. 相似文献
42.
Trimethylsilyl bromide is an effective reagent for the deprotection of methoxymethyl ethers under mild conditions. 相似文献
43.
Hsiu-Pu Daniel Lee Larry S. Eichmeier David M. Piatak 《Journal of mass spectrometry : JMS》1985,20(3):247-252
The origin of the [M–69]+ and [M–111]+ signals in the mass spectrum of taraxasterol was studied through the use of C(18), (19), (21), (22) and/or (30) deuteriated derivatives. The generality of these signals for ring systems with an exocyclic methylene group and a methyl moiety on an adjacent carbon was verified with 2-methylmethylenecyclohexane, 1-methyl-2-methylene-trans-decalin, 1,10-dimethyl-2-methylene-trans-decalin and some of their deuteriated derivatives. The most plausible mechanism for the formation of the [M–69]+ ion appears to involve cleavage of both bonds allylic to the exocyclic methylene group with a 1,3-hydrogen transfer from the adjacent ring. Genesis of the [M–111]+ ion is more complicated but a five-membered allylic ion generated from ring D is proposed. 相似文献
44.
Daniel S. Trifan Ronald A. Shelden John J. Hoglen 《Journal of polymer science. Part A, Polymer chemistry》1968,6(6):1605-1614
1, 4-Pentadiene has been polymerized by Ziegler-Natta catalysts to give amorphous polymers which are up to 64 wt.-% soluble. The polymers all have residual unsaturation which is substantially less than one double bond per mer, some as low as 0.1 double bond per mer. The polymerizations proceed by an unusual double inter-, double intramolecular cyclopolymerization mechanism leading to the formation of [3.3.1] bicyclic repeat units. Some main-chain (internal) unsaturation as well as pendant-group (external) unsaturation is observed. The latter results from incompletely cyclized 1,4-pentadiene units. The former is due to some concurrent isomerization of 1,4- to 1,3 pentadiene, which then copolymerizes with the 1,4 diene. The extent of isomerization varied with the catalyst system used. The soluble polymer fractions were brittle for internal unsaturations of less than about 0.05 double bond per mer and were viscous for higher values. The insoluble fractions were brittle and are believed to be lightly crosslinked. 相似文献
45.
Daniel Raucher Moshe Levy 《Journal of polymer science. Part A, Polymer chemistry》1975,13(6):1339-1346
The photopolymerization of vinyl fluoride, in the presence of peroxide, was studied in dimethyl sulfoxide (DMSO) solution and in bulk. It was found that high rates of reaction could be obtained in spite of the fact that the polymer precipitates at an early stage. By continuous supply of monomer the precipitated polymer was converted into a transparent bulk polymer. 相似文献
46.
Stasko DJ Perzynski KJ Wasil MA Brodbeck JK Kirschbaum K Kim YW Lind C 《Inorganic chemistry》2004,43(13):3786-3788
The acid H(2)B(12)(OH)(12) can be isolated as a crystalline solid by protonation of the hydroxylated borane anion, B(12)(OH)(12)(2)(-). This acidic compound has low solubility in water, conducts protons in the solid state, and has thermal stability to a temperature of 400 degrees C. The conductivity mechanism is a Grotthuss mechanism with a low activation enthalpy (9-13 kcal/mol). This new acid represents an addition to the class of oxoacids, of which sulfuric and phosphoric acid are the most prominent examples. 相似文献
47.
The first examples of the use of racemic vinylaziridines in a Pd-catalyzed dynamic kinetic asymmetric transformation have been examined. Optimization studies of the Pd-catalyzed addition of vinylaziridines to isocyanates revealed that the chiral ligand between trans-1,2-diaminocyclohexane and 2-diphenylphosphino-1-naphthoic acid is superior to that involving 2-diphenylphosphino benzoic acid. Surprisingly, high ee's required the use of an acid whose pKa was about 4.7 +/- 0.1 as a cocatalyst. Both acetic acid and hydroxybenzotriazole meet this requirement. Less electrophilic isocyanates (e.g., benzyl, p-methoxyphenyl) gave higher ee's than more electrophilic ones (phenyl or benzoyl). Both N-benzyl and N-arylaziridines react well to give good yields and ee's, whereas N-tosylaziridines gave lower ee's. A 1,1-disubstituted aziridine led to the formation of a tertiary C-N bond with ee's comparable to the formation of the secondary C-N bond. The products were easily reduced almost quantitatively to the sensitive imidazolidines which can be readily hydrolyzed to the vicinal diamines. The reactivity pattern is consistent with a Curtin-Hammett situation wherein the enantiodiscriminating event is the cyclization of a rapidly equilibrating dynamic pi-allyl palladium intermediate. 相似文献
48.
The Suzuki cross-coupling methodology provides a facile synthetic approach for the modular preparation of meso-tetraaryl cofacial bisporphyrins anchored by xanthene and dibenzofuran. This synthetic method furnishes cofacial bisporphyrin templates with enhanced steric and electronic protection from mu-oxo formation and oxidative degradation. The ability of these platforms to support multielectron oxidation chemistry mediated by proton-coupled electron transfer (PCET) is demonstrated by their reactivity for the catalytic disproportionation of hydrogen peroxide to oxygen and water. 相似文献
49.
The model of Onsager in which a polar molecule undergoes a reaction field due to the polarization of the molecular surroundings is used to evaluate by a S.C.F. calculation (CNDO/2 approximation) the modifications of a molecular structure in the liquid state.Application to water molecule and to three polar dimers for values of the dielectric constant varying between 3 and 78, shows that most of geometric parameters and dipoles moments vary of few per cent when the molecule is inserted in a liquid. In the liquid state dipole moments do not depend very much on the dielectric constant but energies and relative stabilities of isomers are strongly dependent on the medium.[/p] 相似文献
50.
Thyagarajan S Shay DT Incarvito CD Rheingold AL Theopold KH 《Journal of the American Chemical Society》2003,125(15):4440-4441
Reaction of TpR,MeCo(I) dinitrogen complexes (R = iPr, tBu) with trimethylsilyl azide yields structurally characterized compounds that imply the formation of reactive intermediates of the type TpR,MeCo=NSiMe3. These cobalt imido species apparently abstract hydrogen from the 3-substituent of the Tp-ligand, leading to the formation of amido complexes accompanied by either Co-C bond formation (R = tBu) or C-C bond formation (R = iPr). 相似文献