Synergistic photocatalytic and Fenton-like degradation of MO by nanocatalyst La0.7Sr0.3Mn0.85Fe0.15O3

Journal of Nanoparticle Research - The studies on the utilisation of supercritical fluids (SCFs) in processing chemicals and materials have garnered significant attention in the past two decades....     

两端线型双量子点分子Aharonov-Bohm干涉仪电输运

设计一个两端线型双量子点分子Aharonov-Bohm (A-B)干涉仪. 采用非平衡格林函数技术, 理论研究无含时外场作用下的体系电导和引入含时外场作用下的体系平均电流. 在不考虑含时外场时, 调节点间耦合强度或磁通可以诱导电导共振峰劈裂. 控制穿过A-B干涉仪磁通的有无, 实现了共振峰电导数值在0与1之间的数字转换, 为制造量子开关提供了一个新的物理方案. 同时借助磁通和Rashba自旋轨道相互作用, 获得了自旋过滤. 当体系引入含时外场时, 平均电流曲线展示了旁带效应. 改变含时外场的振幅, 实现了体系平均电流的大小与位置的有效控制, 而调节含时外场的频率, 则可以实现平均电流峰与谷之间的可逆转换. 通过调节磁通与Rashba自旋轨道相互作用, 与自旋相关的平均电流亦得到有效控制. 研究结果为开发利用耦合多量子点链嵌入A-B 干涉仪体系电输运性质提供了新的认知. 上述结果可望对未来的量子器件设计与量子计算发挥重要的指导作用.     

Bolund岛的DES数值模拟研究

目前很大一部分风电场都处于复杂地形中,处于山后的背风区域具有大分离的流动特征。为把DES方法应用到复杂地形模拟中去,采用带有壁面函数的DES方法对具有几乎垂直的悬崖地貌特征的Bolund岛进行了数值模拟。计算中采用了不同密度的网格。计算采用中心差分格式。在山后的大分离区,当网格大小为山高的5%时,可以获得很好的计算结果。在模拟大分离流动时,DES较RANS模拟方法具有显著的优势。     

多个硅通孔引起的热应力对迁移率和阻止区的影响

本文主要讨论了多个硅通孔引起的热应力对迁移率和阻止区的影响, 得到了器件沟道沿[100]方向时, 硅通孔之间的角度和间距对电子迁移率和阻止区的影响. 设定两种阻止区区域, 即迁移率变化分别为5%和10%的区域, 且主要考虑相邻TSV之间的区域. 仿真结果表明: 当硅通孔和X轴所成角度为π/4时, 电子迁移率变化和阻止区区域最小, 但是可布置器件区域不规则, 不易于布局. 随着间距的增加, 电子迁移率变化和阻止区区域逐渐增大, 趋向于单个TSV的情况; 当角度为0 时, 电子迁移率变化和阻止区区域变大, 可布置器件区域为硅通孔围成的中心小区域上, 形状比较规则, 便于布局. 而且随着间距的增加, 电子迁移率变化和阻止区区域越来越小, 趋向于单个硅通孔的情况.     

ARCJET ABLATION EXPERIMENT TO SIMULATE THE CHELYABINSK ASTEROID ENTRY 1)

烧蚀是小行星极高速进入地球大气层后最重要的现象之一,在很大程度上决定了小行星的质量/尺寸变化、飞行轨迹、甚至光辐射特性. 为观测小行星材料在超高速高温流场中的烧蚀现象,在电弧加热器上开展了模拟Chelyabinsk小行星事件典型弹道状态(速度约5.6 km/s,高度17 km,流星体直径1 m)的烧蚀实验. 试件为钝头外形,头部半径20 mm,半锥角18$^\circ$. 作为对比,试件分别采用玄武岩和碳钢材料. 成功记录了清晰的烧蚀动态过程,观察到两种材料试件表面的熔融损失流动、以及玄武岩试件的蒸发喷射和崩裂剥落等现象,全程测得烧蚀气体发射光谱、试件实时外形变化、表面热图变化等数据. 分析结果显示了两种材料明显不同的烧蚀现象和质量损失机制：碳钢在高温气流冲击作用下溅射成大量微小液滴,跟随气流高速流失;玄武岩质量损失以熔融物剪切流动为主,并伴随少量块状剥落及蒸发喷射. 烧蚀时间为4 s,玄武岩和碳钢的质量损失及驻点后退量分别为37.9 g,72.7 g以及7.3 mm,13.1 mm,估算玄武岩材料的有效烧蚀焓约为2.6 MJ/kg,两种材料的烧蚀光谱测量组分与电镜能谱扫描结果吻合.     

Finite element equilibrium analysis of creep using the mean value of the equivalent shear modulus

Summary The paper deals with the nonlinear creep analysis using equilibrium finite elements. In adopting a concept of the mean value of the equivalent shear modulus, a direct iterative procedure is proposed with the minimum calculation in the modification of the global stiffness matrix. The difficulties due to the incompressibility of the creep flow are overcome by a numerical artifice where the hydrostatic stress component is considered as a Lagrange parameter. Some numerical results are shown and compared with the analytical method.

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Sommario La memoria tratta l'analisi dello scorrimento viscoso non lineare usando l'equilibrio di elementi finiti. Adottando il concetto di valore medio di un modulo di taglio equivalente, si propone un procedimento iterattivo diretto con il minimo di calcolo nella modificazione della matrice di rigidezza globale. Le difficoltà dovute alla incomprimibilità dello scorrimento viscoso sono superate con un artificio numerico in cui la componente di sollecitazione idro-statica è considerata come un parametro di Lagrange. Vengono mostrati alcuni risultati numerici, e confrontati con il metodo analitico.

     

空间技术用固体润滑的发展现状与展望

本文对固体润滑在宇宙飞行器、人造卫星、空间站及空间运载系统中的应用进行了概述,并就其在降低空间机械部件的摩擦磨损、延长使用寿命、提高材料的耐高低温性和对宇宙气体或真空及储存环境的适应性等方面的研究工作发展现状作了评述,还对其未来的发展前景作了展望,指出其研究工作很有可能朝着润滑剂专业化的方向发展,预料固体润滑剂的复合效应将在解决许多新的空间机械润滑问题上发挥有效作用。作者认为,近几十年来在空间技术用固体润滑方面取得了长足的进步,但也还有大量的问题需要研究。     

Crosslinked nanofibrillated cellulose: poly(acrylic acid) nanocomposite films; enhanced mechanical performance in aqueous environments

Nanofibrillated cellulose (NFC) was compounded with poly(acrylic acid) (PAA) via solvent casting. Nanocomposite films were thermally-crosslinked to allow the formation of ester bonds between NFC and PAA, as confirmed by ¹³CNMR and infrared spectroscopy. The network morphology of the cellulose nanofibrils was left intact by the introduction of PAA and crosslinking. Water absorption and swelling was diminished by the introduction of crosslinking, due to the reduced number of vacant hydroxyl and carboxyl groups available to interact with water molecules. Crosslinking with PAA increased the activation energy required for thermal degradation. PAA effectively reinforced NFC, increasing Young’s modulus, tensile strength and glass transition temperature. Crosslinking imparted restraints on segmental motion of polymer chains, further enhancing the thermomechanical properties and retaining elasticity. Wet-strength properties were enhanced due to the reduced hydrophilicity of crosslinked nanocomposite films.     

内给电子体对Ziegler-Natta催化剂性能的影响

研究了5种新型内给电子体对Ziegler-Natta催化剂结构和催化性能的影响.结果表明,使用两种不同制备工艺制备的氯化镁载体均为δ晶型,而不同的内给电子体的加入使得催化剂的氯化镁载体具有不同的微晶结构和形态.在催化剂制备阶段中,内给电子体的加入方式对催化剂的性能有很大的影响.在5种内给电子体中,以cis-1,2-环己二甲酸二异丁酯为内给电子体时,催化剂的聚合活性和PP等规度最高,性能与工业催化剂相当;当选用cis-1,2-环己二甲酸二异丁酯为内给电子体,CMMS为外给电子体,硅钛物质的量之比为10及铝钛物质的量之比为100时,催化剂的聚合活性和PP等规度达到最高.     

Stability of solutions of a class of nonlinear fractional diffusion equations with respect to a pseudo‐differential operator

In this paper, we study the forward and the backward in time problems for a class of nonlinear diffusion equations with respect to the pseudo‐differential operator. Herein, we investigate the stability of the solution of the forward problem in relationship with parameters of the pseudo‐differential operator and initial data. Besides, as known, the backward in time problem is instability. Hence, we give a method to regularize the solution of the backward problem in the case of the parameters are perturbed.