首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1243篇
  免费   139篇
  国内免费   112篇
化学   840篇
晶体学   20篇
力学   58篇
综合类   8篇
数学   237篇
物理学   331篇
  2023年   21篇
  2022年   42篇
  2021年   42篇
  2020年   53篇
  2019年   47篇
  2018年   50篇
  2017年   44篇
  2016年   69篇
  2015年   57篇
  2014年   65篇
  2013年   86篇
  2012年   76篇
  2011年   102篇
  2010年   64篇
  2009年   61篇
  2008年   65篇
  2007年   58篇
  2006年   67篇
  2005年   54篇
  2004年   36篇
  2003年   26篇
  2002年   19篇
  2001年   15篇
  2000年   23篇
  1999年   18篇
  1998年   14篇
  1997年   14篇
  1996年   20篇
  1995年   23篇
  1994年   12篇
  1993年   16篇
  1992年   16篇
  1991年   17篇
  1990年   9篇
  1989年   5篇
  1988年   4篇
  1987年   5篇
  1986年   6篇
  1985年   8篇
  1984年   5篇
  1983年   8篇
  1982年   7篇
  1981年   4篇
  1980年   5篇
  1978年   7篇
  1977年   6篇
  1976年   6篇
  1975年   2篇
  1974年   3篇
  1973年   5篇
排序方式: 共有1494条查询结果,搜索用时 15 毫秒
161.
The paper is concerned with the non-linear backward heat equation in the rectangle domain. The problem is severely ill-posed. We shall use a modified integral equation method to regularize the nonlinear problem. The error estimates of Hölder type of the regularized solutions are obtained. Numerical results are presented to illustrate the accuracy and efficiency of the method. This work is a generalization of many earlier papers, including the recent paper [D.D. Trong, N.H. Tuan, Regularization and error estimate for the nonlinear backward heat problem using a method of integral equation, Nonlinear Anal. 71 (9) (2009) 4167-4176].  相似文献   
162.
Pyrido[3,2,1‐jk]carbazoles 1 , synthesized from carbazoles and alkyl‐ or arylmalonates, gave regioselective electrophilic substitution reactions at position 5 such as chlorination to 5‐chloro derivatives 2 , nitration to 5‐nitro compounds 3 , or hydroxylation to 5‐hydroxy derivatives 4 . 5‐Hydroxy compounds 4 gave on treatment with strong bases ring contraction to 5 , 6 or the ring opening product 7 . Exchange of the chloro group in 2 with azide or amines gave the corresponding azides 8 and the 5‐amino derivatives 9 and 10 . Alkylation of 1 with benzyl chloride or allyl bromide resulted in the formation of 5‐C‐alkylated products 11 together with 4‐alkyloxy derivatives 12 . J. Heterocyclic Chem., 48, 1039 (2011).  相似文献   
163.
The generation of a hidden Br?nsted acid as a true catalytic species in hydroalkoxylation reactions from metal precatalysts has been clarified in case studies. The mechanism of triflic acid (CF(3)SO(3)H or HOTf) generation starting either from AgOTf in 1,2-dichloroethane (DCE) or from a Cp*RuCl(2)/AgOTf/phosphane combination in toluene has been elucidated. The deliberate and controlled generation of HOTf from AgOTf and cocatalytic amounts of tert-butyl chloride in the cold or from AgOTf in DCE at elevated temperatures results in a hidden Br?nsted acid catalyst useful for mechanistic control experiments or for synthetic applications.  相似文献   
164.
The first near-infrared luminescent ytterbium metal-organic framework has been realized for the highly selective and sensitive sensing of small molecules.  相似文献   
165.
Two new copper(II) complexes Cu(NCS)2(4-Bzpy)2 (1) and Cu(NO3)2(4-Bzpy)4 (2) (4-Bzpy=4-benzoylpyridine) have been synthesized and characterized by IR, UV, elemental analysis and X-ray crystallography. Cu(II) atom has a square planar environment for 1 and an distorted octahedral environment for 2, respectively. In solid state there are C-H?π interactions and C-H?S hydrogen bonds between adjacent molecules in complex 1. The molecule of complex 2 is further connected by multiform π-π interactions, C-H?π interactions and C-H?O hydrogen bonds to form a three-dimensional supramolecular structure. The luminescent properties of the complexes 1 and 2 were both investigated in H2O solution and in solid state at room temperature, respectively.  相似文献   
166.
Numerical Algorithms - The purpose of this paper is to study and analyze two different kinds of extragradient-viscosity-type iterative methods for finding a common element of the set of solutions...  相似文献   
167.
In this paper, we complete the study of the dynamics of a recognized continuous‐time model for the Babesiosis disease. The local and global asymptotic stability of the endemic state are established theoretically and experimentally. In addition, to restrain the disease in the original model when the endemic state exists, we propose and study the continuous model with feedback controls. The global stability of the boundary‐equilibrium point of this model is analyzed by means of rigorous mathematical methods. As an important consequence of this result, we propose a strategy to select feedback control variables in order to restrain the disease in the original model. This strategy allows us to make the disease vanish completely. In other words, the feedback controls are specially effective for restraining disease in the model. The validity of the established theoretical result is supported by a set of numerical simulations.  相似文献   
168.
Dang  Quang A  Dang  Quang Long 《Numerical Algorithms》2021,87(4):1479-1499
Numerical Algorithms - In this paper, we consider a fully third-order nonlinear boundary value problem that is of great interest of many researchers. First, we establish the existence and...  相似文献   
169.
In the present paper, a novel photonic crystal (PC) defect mode is designed by inserting a ferroelectric material layer (LiNbO3) into Si/C60 one-dimensional PCs. The band structure of the ferroelectric PCs is numerically analyzed by the transfer matrix method (TMM). The width of the photonic band gap increases by 80 nm and a defect mode appears at a central wavelength of 680 nm when a 150 nm LiNbO3 layer is inserted into the Si/C60 PC structure. The defect mode in the band gap shifts linearly with the change in electric field. The defect mode shifts by 11.2 nm toward shorter wavelengths when the thin film is subjected to a DC voltage of 1 KV.  相似文献   
170.
来志  郭亮  李小珍  党文佳 《物理学报》2013,62(18):184207-184207
提出一种应用机器视觉技术的激光干涉法, 可以研究压电材料的逆压电系数. 在传统干涉测量法中引入机器视觉实现干涉图像灰度最佳估计, 使用数字图像处理技术, 一方面应用降噪算法有效去除激光干涉图样中的噪声, 从而确定激光干涉场的光强分布, 另一方面将干涉图样的明暗变化进一步转化为可量度的灰度变化以提高测量分辨力. 通过合理设计算法, 该方法中对位移的理论测量分辨力可以提高达一个数量级, 为干涉光波长的1/1024, 因此在逆压电系数d31 的实验测量中可以有效提高分辨力. 关键词: 机器视觉 逆压电系数 双光束干涉 数字图像处理  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号