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91.
This paper presents an analysis of the role of orientation on the rheology of discotic mesophases subjected to slow shear start-up flows, using a projection of the Landau-de Gennes equations of nematodynamics. Analysis of the shear stress surface as a function of tilt and twist orientation with respect to the shear plane shows that the stress surface is dense in well-oriented and periodically located sets of maxima and minima. Thus overshoots and undershoot stress responses to shear-start up are predicted to be the rule rather than the exception. In-plane (within the shear plane) shear start-up stress responses can exhibit multiple, single, or no overshoots, depending on the number of maxima traversed on the way to steady state. Responses originating from orientations close to the vorticity axis lead to stress undershoots. Complex stress responses, such as a weak overshoot-strong undershoot sequence, are found for intermediate tilt-twist initial states. In-plane modes lead to amplitude and strain scaling. Out-of-plane modes do not display amplitude or strain scaling. These results provide will be useful to interpret and use transient shear rheological data of carbonaceous mesophases and highly filled suspensions of disc-like particles. 相似文献
92.
[reaction: see text]. A new method was developed for the stereoselective synthesis of alpha-substituted serine amino acids. The strategy utilizes a common enantiomerically enriched intermediate obtained through an enzymatic desymmetrization. A variety of amino acids were synthesized in good ee's through nucleophilic acetylide addition reactions and palladium-catalyzed Sonogashira couplings. 相似文献
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94.
Weakly associative lattice rings (wal-rings) are non-transitive generalizations of lattice ordered rings (l-rings). As is known, the class of l-rings which are subdirect products of linearly ordered rings (i.e. the class of f-rings) plays an important role in the theory of l-rings. In the paper, the classes of wal-rings representable as subdirect products of to-rings and ao-rings (both being non-transitive generalizations of the class of f-rings) are characterized and the class of wal-rings having lattice ordered positive cones is described. Moreover, lexicographic products of weakly associative lattice groups are also studied here. 相似文献
95.
Hamilton equations based not only upon the Poincaré–Cartan equivalent of a first-order Lagrangian, but also upon its Lepagean equivalent are investigated. Lagrangians which are singular within the Hamilton–De Donder theory, but regularizable in this generalized sense are studied. Legendre transformation for regularizable Lagrangians is proposed and Hamilton equations, equivalent with the Euler–Lagrange equations, are found. It is shown that all Lagrangians affine or quadratic in the first derivatives of the field variables are regularizable. The Dirac field and the electromagnetic field are discussed in detail. 相似文献
96.
Astrid an Huef Iain Raeburn Dana P. Williams 《Transactions of the American Mathematical Society》2000,352(10):4759-4787
Suppose that is a second countable locally compact transformation group. We let denote the set of Morita equivalence classes of separable dynamical systems where is a -algebra and is compatible with the given -action on . We prove that is a commutative semigroup with identity with respect to the binary operation for an appropriately defined balanced tensor product on -algebras. If and act freely and properly on the left and right of a space , then we prove that and are isomorphic as semigroups. If the isomorphism maps the class of to the class of , then is Morita equivalent to .
97.
H. Tran V. Dana X. Thomas 《Journal of Quantitative Spectroscopy & Radiative Transfer》2007,108(3):342-362
Line intensities are measured for 546 transitions belonging to 13 bands of the main isotopologue 12C2H2 of the acetylene molecule, in the 1.5-μm spectral domain. A multispectrum fitting procedure is used to retrieve line parameters from Fourier transform spectra. Prior to this work, line intensities were known for only 4 bands in this spectral region, from the work of El Hachtouki and Vander Auwera [Absolute line intensities in acetylene: the 1.5 μm region. J Mol Spectrosc 2002;216:355-62]. An excellent agreement is found with the results of these authors, showing that the accuracy of both results is likely better than 1% for the strong bands. However, the spectrum becomes very crowded when one wants to study weaker bands, so that the average accuracy of the intensities reported in the present work is 5%. From these data, vibrational transition dipole moments squared and Herman-Wallis coefficients have been determined for all the bands. 相似文献
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100.
Valentina Uivarosi Mihaela Badea Rodica Olar Dana Marinescu Teodor Octavian Nicolescu George Mihai Nitulescu 《Journal of Thermal Analysis and Calorimetry》2011,105(2):645-650
Three new complexes with ligands belong to the fluoroquinolone class having the general formula [RuL2Cl2]Cl nH2O ((1) L: norfloxacin (nf), n = 4; (2) L: ciprofloxacin (cp), n = 3; (3) L: enrofloxacin (enro), n = 5) were synthesized and characterized by chemical analysis UV–Vis and IR spectroscopy. In all complexes fluoroquinolone
derivative acts as bidentate chelate ligand. The thermal behavior steps were investigated in synthetic air flow. The thermal
transformations are complex processes according to TG and DTG curves including dehydration, quinolone derivative degradation,
as well as RuCl3 conversion in RuO2. 相似文献