Universality in lattice models of dynamic arrest: introduction of an order parameter

We introduce an order parameter for dynamical arrest. Dynamically available volume (unoccupied space that is available to the motion of particles) is expressed as holes for the simple lattice models we study. Near the arrest transition the system is dilute in holes, so we expand dynamical quantities in a series of hole density. Unlike the situation when presented in particle density, all cases of simple models that we examine have a quadratic dependence of the diffusion constant on hole density. This observation implies that in certain regimes ideal dynamical arrest transitions may possess a hitherto unnoticed degree of universality.     

碳酸钠-氧化锌熔矿离子交换电感耦合等离子体-质谱法测定土壤样品中的碘

通过碳酸钠-氧化锌熔矿,电感耦合等离子体-质谱法测量土壤样品中碘的含量。系统讨论分析了熔矿温度的影响、离子交换树脂用量及交换时间的优化、记忆效应消除、乙醇对灵敏度的增强效应、测量元素校准的选择以及标准曲线基体匹配等实验条件对分析结果的影响。经国家一级标准物质分析验证,该方法对于碘含量大于5μg／g的样品具有很大优势,不需稀释即可直接测量准确,结果较满意,对今后碘的分析测定时的注意事项有较好的引导作用。     

电化学方法制备Si阵列微孔的工艺研究

对用电化学方法制备Si大孔阵列管坑工艺进行了初步探索。 通过对Si在KOH溶液中各向异性湿法蚀刻和在HF酸溶液中的电化学蚀刻过程中各种参数的摸索, 确定在室温下制备大孔阵列的最佳配比浓度, 蚀刻出符合要求的管坑阵列, 为进一步制备结构化闪烁屏奠定了实验基础。 The 3 D structures in silicon are increasingly coming to use in many fields. For example, the high resolution X ray digital imaging detector can be made by coupling CCD and the scintillating screen which is made by the array trenches filled with CsI(Tl). In the present work, we explored the technology of etching micro array on the n type silicon with high resistance. By studying the relative parameters of anisotropic etching of KOH and electro chemical etching of HF, the optimized concentration of HF was determined and the micro pore array trenches with 200 μm in depth were realized. The results establish an experimental base for further fabrication of the scintillating screen.     

Photoluminescence properties of various CVD-grown ZnO nanostructures

We have studied systematically room-temperature photoluminescence (PL) properties of many nanostructured ZnO samples grown by chemical vapour deposition (CVD). Their PL spectra consist of two emissions peaked in the ultraviolet (UV) and green regions. The relative intensity of these emissions depends on the excitation energy density, size and morphology of ZnO nanostructures. Based on the excitation-density dependence of the integrated intensity ratio of UV-to-green emission, we could classify PL spectra of ZnO nanostructures into three groups characteristic of size and morphology. Our study also reveals that with increasing excitation density, the UV-peak position shifts slightly towards longer wavelengths while the green emission around 514-520 nm is almost unchanged. This green-luminescence emission is dominant when the nanostructure sizes range from 20 to 200 nm, which is related to a large surface-to-volume ratio.     

Synthesis, field emission and glucose-sensing characteristics of nanostructural ZnO on free-standing carbon nanotubes films

Free-standing multiwall carbon nanotubes (MWNTs) films were coated, using chemical vapor deposition method, with a thin layer of nanostructural ZnO. The morphology and crystal structure of the as-grown products were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Raman scattering analyses. Field emission (FE) results demonstrated that the needle-like and spherical ZnO-MWNTs composite structure films possessed good performance with a turn-on field of 1.3, 2.2 V μm⁻¹ and a threshold field of 2.6, 4.5 V μm⁻¹, respectively. The glucose-sensing characteristic has also been studied. The multi-layer electrode (PDDA/GOx/ZnO/MWNTs) exhibited significant electrocatalysis to the oxidation and reduction of H₂O₂ than the PDDA/GOx/MWNTs electrode, which provided wide potential applications in clinical, environmental, and food analysis.     

Investigation of Bessel beam propagation in scattering media with scalar diffraction method

Bessel beam propagation in scattering media is simulated using the angular spectrum method combined with slice-by-slice propagation model. Generating Bessel beams with a spatial light modulator, which provides a means to adjust flexibly the parameters of the Bessel beam, allows us to validate the simulation results experimentally. The study reveals that the self-reconstructing length changes oppositely with the axicon angle （i.e., the larger the axieon angle, the shorter the self-reconstructing length）. The radius of the incident beam has little influence on the self-reconstruction of the Bessel beam central lobe.     

聚合物波导型表面等离子体共振传感器的特性研究

基于表面等离子体共振理论,将SU-8作为波导芯层材料,以聚甲基丙烯酸甲酯(PMMA)为下包层材料,设计了一款聚合物波导型SPR传感器。理论计算了波导芯层折射率、被测物折射率、不同金属薄膜及其厚度等因素对表面等离子体共振曲线的影响。分析结果表明,在可测试范围内,被测物折射率越大,灵敏度越高;波导芯层折射率减小,共振峰向长波方向移动,被测物检测范围整体向折射率小的方向偏移,波导芯层折射率增大则相反。     

极谱分析法连续测定痕量铅和镉

研究了 Pb2 + 和 Cd2 + 与 KCl-酒石酸钠 -三乙醇胺 -明胶体系的二次导数极谱波。在 p H=4 .5的 HAc-Na Ac介质中 ,Pb2 + 和 Cd2 + 分别于 - 0 .4 6 V和 - 0 .6 4V电位处产生一良好的极谱波。峰电流与 Pb2 + 和Cd2 + 的浓度分别在 1× 10 -5— 3× 10 -1g· L-1和 5× 10 -5— 6× 10 -3 g· L-1范围内呈线性关系。 Pb2 + 和Cd2 +的检出限分别为 1× 10 -7g·L-1和 5× 10 -7g·L-1。本法准确、简便、快速、选择性高。已直接用于饮料中铅和镉的连续测定 ,同时也对酒及面粉样品进行了测定 ,回收率分别为 99.9%— 10 0 .1%和 97.0 %—10 4 .8%。     

Growth and spectroscopic characterization of Er: Sr3Y(BO3)3 crystal

This paper reports the growth and spectroscopic characterization of Er³⁺:Sr₃Y(BO₃)₃ crystal. Er³⁺:Sr₃Y(BO₃)₃ crystal with dimensions up to ∅20×35 mm³ has been grown by Czochralski method. The polarized spectroscopic properties of Er³⁺:Sr₃Y(BO₃)₃ crystal were investigated. Based on the Judd-Ofelt theory, the effective intensity parameters Ω_t were obtained: Ω₂=1.71×10⁻²⁰ cm², Ω₄=1.39×10⁻²⁰ cm², Ω₆=0.74×10⁻²⁰ cm² for π-polarization, and Ω₂=1.77×10⁻²⁰ cm², Ω₄=1.44×10⁻²⁰ cm², Ω₆=0.65×10⁻²⁰ cm² for σ-polarization. The emission cross-section σ_em was calculated to be 4.75×10⁻²¹ cm² for π-polarization at 1536 nm and 6.30×10⁻²¹ cm² for σ-polarization at 1537 nm. The investigated results showed that Er³⁺:Sr₃Y(BO₃)₃ crystal may be regarded as a potential laser host material for 1.55 μm IR solid-state lasers.     

统计平衡状态下扭秤热噪声对引力实验的限制

讨论了统计平衡状态下的耗散涨落理论,由此推导出扭秤的热噪声对引力实验的限制.