苯甲酸及其一氯代衍生物与邻菲罗啉或联吡啶的稀土铕三元配合物的荧光性质

本文报道合成了八种苯甲酸及其一氯代衍生物与邻菲罗啉或联吡啶的稀土铕三元配合物并测得了荧光光谱。通过改变第一和第二配体,研究了配合物发光峰强度、位置和分裂间隔等的变化情况,依据荧光发射峰的分裂推断出Eu~(3 )离子所处的局域环境对称性大致都是C_1,C_2或C_s。虽然配合物的局域对称性大致相同,但由于配体场作用和能级匹配等原因,发光峰位置和强度是不同的;讨论了第一配体分子结构的变化对荧光性能的影响,认为分子自身结构的对称性可能对提高配合物发光性能有较大影响;实验还观察到第二配体也参与配位且对发光性能影响较大。同时看到发光峰的分裂间隔大小变化和发光峰的相对强度的变化是一致的。     

强电磁脉冲(激光、微波)在高温离解氮气中的击穿效应

 通过对电子能量分布函数所满足的Boltzmann方程的求解，在理论上分析了强电磁脉冲(激光、微波)在高温氮气中的击穿效应。高温气体的一个主要特征是其中的部分气体分子会离解为原子，这一离解效应会对强电磁脉冲在气体中发生电离击穿的阈值产生影响。计算表明：随着温度的升高，氮分子的离解度增大，强电磁脉冲的击穿阈值下降；击穿阈值的下降幅度与电磁波的频率有关，对频率较高的红外激光，击穿阈值下降明显；而对微波，击穿阈值所受影响较小。     

目标辐射噪声中线谱序列的提取方法

不同类型目标辐射噪声包络谱中的线谱及其谐波分布存在较大差异，是进行目标检测和分类识别的重要线索。本文提出了一种基于能量判据和子频带综合的线谱序列提取方法，并利用实测数据进行了比较分析。仿真和对实际数据分析的结果表明，该方法能够较准确、稳定提取线谱序列，为目标检测和分类识别提供了可靠依据。     

Capillary Zone Electrophoresis Investigation of Interactions between Granulocyte-colony Stimulating Factor and Dextran Sulfate／Carrageenan Oligosaccharide

Granulocyte-colony stimulating factor (G-CSF) is an O-glycosylated glycoprotein. G-CSF stimulates the proliferation and differentiation of hematopoietic progenitor cells committed to the neutrophil/granulocyte lineage in a dose-dependent manner. The most important application of G-CSF is in the treatment of transient phases of leukopenia following chemotherapy and/or radiotherapy. Using capillary zone electrophoresis (CZE), former studies showed that G-CSF could interact with polysulfa…     

超临界水中纤维素气化制氢的实验研究

在500～650℃、20-35 MPa条件下,对超临界水- 纤维素混合物进行气化反应实验,发现压力、温度、反应停留时间、物料浓度等参数对纤维素的气化率和气态产物的组成都有明显影响,得出上述因素的影响规律。结果表明纤维素在超临界水中具有较高的气化率,生成以H2和CO2为丰要成份的气态产物。     

Successive projection method for solving the unbalanced Procrustes problem

We present a successive projection method for solving the unbalanced Procrustes problem: given matrix A∈Rn×n and B∈Rn×k, n>k, minimize the residual‖AQ-B‖F with the orthonormal constraint QTQ = Ik on the variant Q∈Rn×k. The presented algorithm consists of solving k least squares problems with quadratic constraints and an expanded balance problem at each sweep. We give a detailed convergence analysis. Numerical experiments reported in this paper show that our new algorithm is superior to other existing methods.     

Magnetic Properties of Melted ThMn12-Type Carbides and Their Nitrides

The carbides of NdDy0.2Fe12-yMoyC0.6 （y = 1.5, 2） crystallized in the ThMn12-type structure have been successfully synthesized by arc melting method, followed by a heat treatment. The magnetic properties are strongly enhanced with the addition of carbon. Upon the carbonation the saturation magnetization Ms is increased by about 20emu/g and the Curie temperature Tc is enhanced by 40-70K. The spin reorientation （SR） temperature decreases from 125 K for NdDy0.2Fe10Mo2 to 55 K for NdDy0.2Fe10MO2C0.6 indicating the change of magnetocrystalline anisotropy in the Nd sublattice. It is found that the intrinsic magnetic properties of the carbides can be improved by further nitrogenation, The composite carbon-nitrogen compounds show a Tc - 560K, M8 - 105 emu/g and Ha （anisotropy field） - 86kOe for NdDy0.2Fe10Mo2Co.6Nz and a Tc- 628K, M8 - 119 emu/g and Ha - 115kOe for NdDy0.2Fe10.5Mo1.5C0.6Nz. These magnetic properties are even better than those of simple nitrides, suggesting that these compounds can be considered as a good candidate for permanent magnet applications.     

EFFECT OF THERMAL TREATMENTS ON THE SUPERCONDUCTIVITY OF UNDOPED AND WO3 DOPED Y-Ba-Cu-O SYSTEM

Undoped and WO₃-doped Y-Ba-Cu-O ceramics have been slowly cooled in flowing oxygen or quenched in air from 900℃ to room temperature, after sintering at 900℃ for 3Oh in flowing oxygen. The ac susceptibility measurements show that the T_c of the quenched WO₃-doped Y-Ba-Gu-O superconductor can reach 88K, while the undoped Y-Ba-Cu-O ceramic quenched in air is a non-superconductor. X-ray diffraction data show that WO₃ does not enter into the YBa₂Cu₃O_7-x lattice but forms all impurity phase. The WO₃-doped YBCO specimens quenched in air consist of orthorhombic YBa₂Cu₃O_7-x phase and an impurity phase which increases with increasing WO₃ content. Raman spectra chow that oxygen contents are different for undoped and WO₃-doped samples. It la suggested that suitable doping with WO₃ can change the oxygen content and reduce the effect of thermal treatments on the superconductivity of Y-Ba-Cu-O system.     

一个可能的有四代轻费米子的SU(7)大统一模型

本文提出了一个可能的SU(7)大统一理论的模型,其中包含四代轻费米子,它们的弱作用是V—A型式的。在此模型中,可以得到所期望的m_μ～3m_s,m_em_μ～m_dm_s,Cabibbo角sinθ₁～(m_d/m_s)^1/2和SU(5)标准模型中得到的所有符合实验的结果。