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121.
文章作者用磁镊与原子力显微镜研究了抗癌药物顺铂对单个DNA分子结构的影响.当顺铂浓度较低时,DNA链变得柔软,驻留长度从~52 nm显著缩短到~15 nm;当顺铂浓度较高时,DNA表现出凝聚现象.基于单分子拉伸和原子力显微镜(AFM)成像两方面的实验结果,文章作者提出一个顺铂导致的DNA变软(softening)-成环(looping)-缩短(shortening)-凝聚(condensing)模型(简写为SLSC模型)来解释观察到的DNA凝聚,并认为通过远程交联使DNA形成小环结构是铂类抗癌药物作用的重要特征. 相似文献
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123.
An ab initio calculation based on density functional theory is applied to study the doping stability and electronic structure of wurtzite Zn1−xCdxO alloys. It is found that the different alloy configurations of Zn1−xCdxO with a given Cd content are possible thermodynamically, but having different band gaps. With increasing Cd content, the formation enthalpy of Zn1−xCdxO alloy increases sharply. The Cd-content dependence of the band-gap values can be fitted with a second-order polynomial. The reduction of band gap can be attributed to the contributions of the hybridization of Zn-4s and Cd-5s, the enhancement of p-d repulsion, and the tensile strain due to Cd-doping. 相似文献
124.
由于碳交易市场价格的波动性大及相互影响关系的复杂性,本文试图构建碳价格长期和短期的最优预测模型。考虑到碳交易价格波动的趋势性和周期性特点,基于经验模态分解算法(EMD)、遗传算法(GA)—神经网络(BP)模型、粒子群算法(PSO)—最小二乘支持向量机(LSSVM)模型及由它们构建的组合预测模型,对中国碳市场交易价格进行短期预测和长期预测。实证分析中将影响碳交易价格的不同宏观经济因素和碳价格时间序列因素做为输入变量,分别代入组合模型进行预测。研究结果表明,在短期预测中,EMD-GA-BP模型预测效果优于GA-BP模型和PSO-LSSVM模型;而在长期预测中,组合模型EMD-PSO-LSSVM模型预测效果优于只考虑碳价格波动趋势性或周期性预测效果。 相似文献
125.
研究了一类二阶半线性时滞微分方程解的振动性质.在一定条件下,建立了两个新的振动性定理,推广和改进了已知的结果. 相似文献
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127.
研究了一阶常系数中立型时滞差分方程A[x(n)-px(n-τ)]+qx(n-σ)=0的振动性.通过构造若干适当的函数,分别得到了在0
1两种情况下该方程的一切解振动的充分必要条件. 相似文献
128.
We study the role of laser polarization in the diamagnetic spectrum for the transition from the ground state to the highly excited Rydberg states through a single photon absorption. For simplicity, one usually polarizes the irradiation laser to the selected main quantum axis, which is along the applied external electric or magnetic field. The transition selection rule is simply expressed as m = 0, which corresponds to the π transition. When the polarization is circularly polarized around the main axis, the σ+ or σ- transition occurs, corresponding to the selection rule of m = 1 or m = 1, respectively. A slightly more complex case is that the laser is linearly polarized perpendicular to the main axis. The numerical calculation shows that we can decompose the transition into the sum of σ+ and σ- transitions, it is noted as the σ transition. For the more complex case in which the laser is linearly polarized with an arbitrary angle with respect to the main axis, we have to decompose the polarization into one along the main axis and the other one perpendicular to the main axis. They correspond to π and σ transitions, respectively. We demonstrate that these transitions in the diamagnetic spectrum and the above spectral decomposition well explain the experimentally observed spectra. 相似文献
129.
The hydrated shell of both Fe2+ and Fe3+ aqueous solutions are investigated by using the molecular dynamics (MD) and X-ray absorption structure (XAS) methods. The MD simulations show that the first hydrated shells of both Fe2+ and Fe3+ are characterized by a regular octahedron with an Fe-O distance of 2.08 for Fe2+ and 1.96 for Fe3+, and rule out the occurrence of a Jahn-Teller distortion in the hydrated shell of an Fe2+ aqueous solution. The corresponding X-ray absorption near edge fine structure (XANES) calculation successfully reproduces all features in the XANES spectra in Fe2+ and Fe3+ aqueous solution. A feature that is located at energy 1 eV higher than the white line (WL) in an Fe3+ aqueous solution may be assigned to the contribution of the charge transfer. 相似文献
130.
Excitation power-dependent micro-photoluminescence spectra and photon-correlation measurement are used to study the optical properties and photon statistics of single InAs quantum dots. Exciton and biexciton emissions, whose photoluminescence intensities have linear and quadratic excitation power dependences, respectively, are identified. Under pulsed laser excitation, the zero time delay peak of second order correlation function corresponding to exciton emission is well suppressed, which is a clear evidence of single photon emission. 相似文献