Pressure dependence of the electric field gradient and knight shift tensors of single crystal gallium

Nuclear pure quadrupole resonance has been observed in single crystal gallium as a function of hydrostatic pressure up to 7 kbar at temperatures of 77, 198 and 273 K. The resonance frequency v_Q increases linearly with pressure and the slope ($\text{δv}{}_{\mathrm{O}}\text{δP}$)_T is 13.7, 15.5 and 16.3 Hz/bar at 77, 198 and 273 K respectively. The asymmetry parameter decreases nonlinearly with pressure. Using compressibility and thermal expansion data, the volume dependence of the major principle component of the electric field gradient was deduced. The principal components K_x, K_y and K_z of the Knight shift tensor have been measured as a function of pressure to 6 kbar at 77 K. The isotropic and anisotropic components of the Knight shift were deduced as a function of pressure, and K_iso is found to vary with volume as V^{4.95 ± 0.80}.     

Bistable stochastic biochemical networks: highly specific systems with few chemicals

In this paper we describe a class of stochastic biochemical systems exhibiting bistable behavior, in the sense that the invariant measure associated to the system is concentrated near two different classes of states of the system. We develop methods that allow us to describe the behavior of the invariant measure in some suitable asymptotic limits, as well as the switching times for the transitions between the states close to each of the states with high probability. Due to the discrete character of the problem, switching times cannot be computed using the classical Kramers’ formula, and alternative methods are required.     

Inclusion of thymol into cucurbiturils: density functional theory approach with dispersion correction and natural bond orbital analysis

Journal of Inclusion Phenomena and Macrocyclic Chemistry - Stability of inclusion complexes of thymol (a natural flavour) with cucurbit[n]urils was interpreted by using density functional theory...     

Domain-Specific On-Device Object Detection Method

Object detection is a significant activity in computer vision, and various approaches have been proposed to detect varied objects using deep neural networks (DNNs). However, because DNNs are computation-intensive, it is difficult to apply them to resource-constrained devices. Here, we propose an on-device object detection method using domain-specific models. In the proposed method, we define object of interest (OOI) groups that contain objects with a high frequency of appearance in specific domains. Compared with the existing DNN model, the layers of the domain-specific models are shallower and narrower, reducing the number of trainable parameters; thus, speeding up the object detection. To ensure a lightweight network design, we combine various network structures to obtain the best-performing lightweight detection model. The experimental results reveal that the size of the proposed lightweight model is 21.7 MB, which is 91.35% and 36.98% smaller than those of YOLOv3-SPP and Tiny-YOLO, respectively. The f-measure achieved on the MS COCO 2017 dataset were 18.3%, 11.9% and 20.3% higher than those of YOLOv3-SPP, Tiny-YOLO and YOLO-Nano, respectively. The results demonstrated that the lightweight model achieved higher efficiency and better performance on non-GPU devices, such as mobile devices and embedded boards, than conventional models.     

Blue electroluminescent materials based on indeno[1,2-a]arene derivatives for Organic Light-Emitting Diodes

Abstract

In this study, as a continuous effort for searching efficient blue-emitting materials, we designed and synthesized materials based on indeno[1,2-a]arene. OLED devices using these materials were fabricated in the following sequence; ITO (180?nm)/N,N'-diphenyl-N,N'-(2-napthyl)-(1,1'-phenyl)-4,4'-diamine (NPB) (50?nm)/emitting materials (30?nm)/4,7-diphenyl-1,10-phenanthroline (Bphen) (30?nm)/Liq/Al (2/100?nm). Particularly, a device using 7,7-dimethyl-7H-indeno[1,2-a]pyrene as emitter showed maximum values of luminous efficiency, power efficiency, and external quantum efficiency of 1.10?cd/A, 0.49?lm/W, 1.47% at 20?mA/cm², respectively with CIE (x,y) coordinates of (0.15, 0.08) at 6.0V.     

Thermal diffusion of dilute aqueous NH4Cl,Me4NCl,Et4NCl,n-Pr4NCl,andn-Bu4NCl solutions at 25°C

The Soret effect (thermal diffusion) of dilute aqueous solutions of NH₄Cl, Me₄NCl, Et₄NCl, n-Pr₄NCl, and n-Bu₄NCl has been investigated potentiometrically using the silver, silver chloride thermocell. The molar entropies (heats) of transport have been derived from the initial and final thermoelectric powers. The concentration dependence of the entropy of transport has been examined and the effect of the ionic size on the heat of transport is discussed. The molar entropy of tetrabutylammonium chloride exhibits a sharp minimum in the neighborhood of 0.002M, the reason of which is as yet unclear.     

Soft‐Chemical Exfoliation Route to Layered Cobalt Oxide Monolayers and Its Application for Film Deposition and Nanoparticle Synthesis

A colloidal suspension of exfoliated, layered cobalt oxide nanosheets has been synthesized through the intercalation of quaternary tetramethylammonium ions into protonated lithium cobalt oxide. According to atomic force microscopy, exfoliated nanosheets of layered cobalt oxide show a plateau‐like height profile with nanometer‐level height, underscoring the formation of unilamellar 2D nanosheets. The exfoliation of layered cobalt oxide was cross‐confirmed by X‐ray diffraction, UV/Vis spectroscopy, and transmission electron microscopy. The maintenance of the hexagonal in‐plane structure of the cobalt oxide lattice after the exfoliation process was evidenced by selected‐area electron diffraction and Co K‐edge X‐ray absorption near‐edge structure analysis. The zeta‐potential measurements clearly demonstrated the negative surface charge of cobalt oxide nanosheets. Adopting the nanosheets of layered cobalt oxide as a precursor, we were able to prepare the monodisperse CoO nanocrystals with a particle size of ≈10 nm as well as the heterolayered film composed of cobalt oxide monolayer and polycation.     

Enhanced self-diffusion on Cu(111) by trace amounts of s: chemical-reaction-limited kinetics

We find that less than 0.01 monolayer of S can enhance surface self-diffusion on Cu(111) by several orders of magnitude. The measured dependence of two-dimensional island decay rates on S coverage (theta(S)) is consistent with the proposal that Cu3S3 clusters are responsible for the enhancement. Unexpectedly, the decay and ripening are diffusion limited with very low and very high theta(S) but not for intermediate theta(S). To explain this result we propose that surface mass transport in the intermediate region is limited by the rate of reaction to form Cu3S3 clusters on the terraces.     

Synchronizing weighted complex networks

Real networks often consist of local units, which interact with each other via asymmetric and heterogeneous connections. In this work, we explore the constructive role played by such a directed and weighted wiring for the synchronization of networks of coupled dynamical systems. The stability condition for the synchronous state is obtained from the spectrum of the respective coupling matrices. In particular, we consider a coupling scheme in which the relative importance of a link depends on the number of shortest paths through it. We illustrate our findings for networks with different topologies: scale free, small world, and random wirings.     

A novel three-dimensional digital watermarking scheme basing on integral imaging

A novel integral imaging-based three-dimensional (3D) digital watermarking scheme is presented. In the proposed method, an elemental image array (EIA) obtained by recording the rays coming from a 3D object through a pinhole array in the integral imaging system is employed as a new 3D watermark. The EIA is composed of a number of small elemental images having their own perspectives of a 3D object, and from this recorded EIA various depth-dependent 3D object images can be reconstructed by using the computational integral imaging reconstruction (CIIR) technique. This 3D property of the EIA watermark can make a robust reconstruction of the watermark image available even though there are some data losses in the embedded watermark by attacks. To show the robustness of the proposed scheme against attacks, some experiments are carried out and the results are discussed.