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51.
The broken symmetric phase of scalar models exhibits an infrared fixed point which is induced by the degenerate effective potential. The definition of the correlation length in the infrared regime enables us to determine the type of the phase transition in the model. It is shown that the massive sine-Gordon model exhibits a continuous, while the layered sine-Gordon model has an infinite order Kosterlitz–Thouless type phase transition. 相似文献
52.
Mass action type deterministic kinetic models of ion channels are usually constructed in such a way as to obey the principle of detailed balance (or, microscopic reversibility) for two reasons: first, the authors aspire to have models harmonizing with thermodynamics, second, the conditions to ensure detailed balance reduce the number of reaction rate coefficients to be measured. We investigate a series of ion channel models which are asserted to obey detailed balance, however, these models violate mass conservation and in their case only the necessary conditions (the so-called circuit conditions) are taken into account. We show that ion channel models have a very specific structure which makes the consequences true in spite of the imprecise arguments. First, we transform the models into mass conserving ones, second, we show that the full set of conditions ensuring detailed balance (formulated by Feinberg) leads to the same relations for the reaction rate constants in these special cases, both for the original models and the transformed ones. 相似文献
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Numerical Algorithms - This paper describes a new MATLAB software package of iterative regularization methods and test problems for large-scale linear inverse problems. The software package, called... 相似文献
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Omer A. Akrawi Gergő Z. Nagy Tamás Patonay Alexander Villinger Peter Langer 《Tetrahedron letters》2012,53(26):3206-3209
Suzuki–Miyaura reactions of 4-trifluoromethylsulfonyloxy-6-bromocoumarin provide a convenient access to arylated coumarins. The reactions proceed with excellent chemoselectivity in favour of position 4. 相似文献
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Miklós Nagy László Szöllösi Sándor Kéki Rudolf Faust Miklós Zsuga 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(4):331-338
A series of amphiphilic polyisobutylene-block-poly(vinyl alcohol) (PIB-b-PVA) copolymers of constant PIB and varying PVA block length was synthesized by living carbocationic polymerization and their solution behavior was studied. The synthesis involved the preparation of polyisobutylene-b-poly(tert.-butyl vinyl ether) followed by hydrolysis with hydrogen bromide. The copolymers were characterized by gel permeation chromatography, 1H-NMR, and MALDI-TOF MS methods. The micellization behavior of the copolymers was investigated in aqueous media by direct dissolution and dialysis using static and dynamic light scattering. The critical micelle concentration, micelle size, aggregation number, and micelle shape were determined. The ability of the aggregates as drug carrying nanodevices was also investigated by doping them with indomethacin. UV-Vis measurements showed that the solubility of indomethacine increased significantly. Our findings suggest that the solubility is largely dependent upon the block segment ratios. 相似文献
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Ákos Kuki Ghazaleh Shemirani Lajos Nagy Borbála Antal Miklós Zsuga Sándor Kéki 《Journal of the American Society for Mass Spectrometry》2013,24(7):1064-1071
A simple collision model for multiple collisions occurring in quadrupole type mass spectrometers was derived and tested with leucine enkaphalin a common mass spectrometric standard with well-characterized properties. Implementation of the collision model and Rice-Ramsperger-Kassel-Marcus (RRKM) algorithm into a spreadsheet software allowed a good fitting of the calculated data to the experimental survival yield (SY) versus collision energy curve. In addition, fitting also ensured to estimate the efficiencies of the kinetic to internal energy conversion for Leucine enkephalin in quadrupole-time-of-flight and triple quadrupole instruments. It was observed that the experimental SY versus collision energy curves for the leucine enkephalin can be described by the Rice-Ramsperger-Kassel (RRK) formalism by reducing the total degrees of freedom (DOF) to about one-fifth. Furthermore, this collision model with the RRK formalism was used to estimate the critical energy (E o ) of lithiated polyethers, including polyethylene glycol (PEG), polypropylene glycol (PPG), and polytetrahydrofurane (PTHF) with degrees of freedom similar to that of leucine enkephalin. Applying polyethers with similar DOF provided the elimination of the effect of DOF on the unimolecular reaction rate constant. The estimated value of E o for PEG showed a relatively good agreement with the value calculated by high-level quantum chemical calculations reported in the literature. Interestingly, it was also found that the E o values for the studied polyethers were similar. Figure
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