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A. M. A. Melo D. L. Alexandre M. R. F. Oliveira R. F. Furtado M. F. Borges P. R. V. Ribeiro A. Biswas H. N. Cheng C. R. Alves E. A. T. Figueiredo 《Journal of Solid State Electrochemistry》2018,22(5):1321-1330
The performance of biosensors depends directly on the strategies adopted during their development. In this paper, a fast and sensitive biosensor for Salmonella Typhimurium detection was assembled by using optimization studies in separate stages. The pre-treatment assays, biomolecular immobilization (primary antibody and protein A concentrations), and analytical response (hydroquinone and hydrogen peroxide concentrations) were optimized via voltammetric methods. In the biosensor assembly, a gold surface was modified via the self-assembled monolayer technique (SAM) using cysteamine thiol and protein A for immobilization of anti-Salmonella antibody. The analytical response of the biosensor was obtained through the use of a secondary antibody labeled with a peroxidase enzyme, and the signal was evaluated by applying the chronoamperometry technique. The biosensor was characterized by infrared spectroscopy and cyclic voltammetry. Optimization of protein A and primary antibody concentrations enabled higher analytical signals of 7.5 and 75 mg mL?1, respectively, to be achieved. The hydroquinone and H2O2 concentrations selected were 3 and 300 mM, respectively. The biosensor developed attained a very low detection limit of 10 CFU mL?1 and a fast response with a final detection time of 125 min. These results indicate that this biosensor is very promising for the food safety and emergency response applications. 相似文献
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Ashutosh Agrawal K. Biswas S. K. Srivastava Sudipto Ghosh 《Journal of Solid State Electrochemistry》2018,22(11):3443-3455
Using an improved single-step hydrothermal method, mesoporous hard carbon nano-balls, with nitrogen doping, have been successfully synthesized. These materials exhibit good reversible charge capacity during half-cell tests. Gravimetric capacity for undoped nano-sized and micron-sized mesoporous hard carbon balls is 506 and 475 mAh g?1, respectively. After nitrogen doping, the specific gravimetric capacities of both nano- and micron-sized carbon balls increase by 6.9 and 8%, respectively. Nitrogen doping enhances retention in specific capacity of both anode materials, particularly in nano-sized carbon balls with capacity retention of 83.9% after 100 cycles. The enhancement is attributed to a significant decrease in volume expansion due to the nitrogen doping. Density functional theory-based computation confirms the reduction of volume expansion by 60%. Improved electrochemical performance of nitrogen-doped hard carbon is due to the drop in volume expansion rate during lithiation along with increased porosity and electronic conductivity. Furthermore, this one-step synthesis can be extended to other carbon sources to get nitrogen-doped hard carbon with sizes varying from micro to nano. 相似文献
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Soft Phonon Modes Leading to Ultralow Thermal Conductivity and High Thermoelectric Performance in AgCuTe 下载免费PDF全文
Subhajit Roychowdhury Manoj K. Jana Jaysree Pan Satya N. Guin Prof. Dirtha Sanyal Prof. Umesh V. Waghmare Prof. Kanishka Biswas 《Angewandte Chemie (International ed. in English)》2018,57(15):4043-4047
Crystalline solids with intrinsically low lattice thermal conductivity (κL) are crucial to realizing high‐performance thermoelectric (TE) materials. Herein, we show an ultralow κL of 0.35 Wm?1 K?1 in AgCuTe, which has a remarkable TE figure‐of‐merit, zT of 1.6 at 670 K when alloyed with 10 mol % Se. First‐principles DFT calculation reveals several soft phonon modes in its room‐temperature hexagonal phase, which are also evident from low‐temperature heat‐capacity measurement. These phonon modes, dominated by Ag vibrations, soften further with temperature giving a dynamic cation disorder and driving the superionic transition. Intrinsic factors cause an ultralow κL in the room‐temperature hexagonal phase, while the dynamic disorder of Ag/Cu cations leads to reduced phonon frequencies and mean free paths in the high‐temperature rocksalt phase. Despite the cation disorder at elevated temperatures, the crystalline conduits of the rigid anion sublattice give a high power factor. 相似文献
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Jnan P. Naskar Chiranjan Biswas Nirmalya Bandyopadhyay James P. S. Walsh Floriana Tuna Miaoli Zhu 《Journal of Coordination Chemistry》2016,69(15):2329-2341
Reaction of the Schiff base, 1-(4-methylimidazol-5-yl) phenylhydrazonopropane-2-one oxime (LH), with copper(II) perchlorate hexahydrate and copper(II) nitrate trihydrate in a 1 : 1 M proportion in methanol affords [Cu2L2(H2O)(ClO4)](ClO4) (1) and [Cu2L2(H2O)2](NO3)2] (2) in moderate yields. Both 1 and 2 have been characterized by elemental analysis, ESI-MS, FT-IR, UV–vis absorption spectroscopy, EPR, electric conductivity, and magnetic susceptibility measurements. The X-ray crystal structures of 1·CH3COCH3 and 2 have been determined. Both compounds are dinuclear copper(II) complexes, with each copper μ2-bridged by two oxime ligands in a μ2-η1,η2 fashion. Variable temperature magnetic studies on 1 and 2 show that both compounds are dominated by an antiferromagnetic coupling through the oxime bridges. 相似文献
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This paper is a review of some of the most important concepts and phenomena for relativistic solitons. The Sine-Gordon equation and the pseudo Sine-Gordon equations are studied in this context. A final discussion is conducted in the for soliton in more than one spatial dimensions. 相似文献
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Size distributions of nanoparticles in the vicinity of synthesis reactors will provide guidelines for safe operation and protection of workers. Nanoparticle concentrations and size distributions were measured in a research academic laboratory environment with two different types of gas-phase synthesis reactors under a variety of operating conditions. The variation of total particle number concentration and size distribution at different distances from the reactor, off-design state of the fume hood, powder handling during recovery, and maintenance of reactors are established. Significant increases in number concentration were observed at all the locations during off-design conditions (i.e., failure of the exhaust system). Clearance of nanoparticles from the work environment was longer under off-design conditions (20 min) compared to that under normal hood operating conditions (4–6 min). While lower particle number concentrations are observed during operation of furnace aerosol reactors in comparison to flame aerosol reactors, the handling, processing, and maintenance operations result in elevated concentrations in the work area. 相似文献