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131.
Mingyan Zhang Wuchao Ma Chao Wang Ximing Yang Yuhang Lou Xinxiu Xia Hongyan Xu 《Molecules (Basel, Switzerland)》2021,26(7)
Pinus koraiensis nut-coated film is a kind of by-product of nut processing, which has been shown to contain flavonoids, polyphenols, and other substances that can be used to produce natural antioxidant extracts. In this study, response surface methodology (RSM) was used to optimize the extraction process of flavonoids of P. koraiensis nut-coated film (PNF), and macroporous resin HPD600 was used to purify PNF (P-PNF). Its antioxidant activity was examined by DPPH (1,1-diphenyl-2-picrylhydrazyl) radical scavenging capacity, oxygen free radical absorption capacity (ORAC), total oxygen radical capture (TRAP), and iron ion reduction capacity. Under the ideal extraction conditions comprising a cellulase dosage of 90 U/g, a material/liquid ratio of 1:20 (g/mL), and an extraction time of 2 h, the PNF yield was 3.37%. Purification conditions were sample concentration of 2.0 mg/mL, pH of 5, water washing volume of 3 bed volume (BV), eluent ethanol concentration of 50%, and volume of 2 BV. The P-PNF recovery was 84.32%, and purity increased from 33.80% to 61.70%. Additionally, P-PNF showed increased antioxidant activity compared to PNF. Cumulatively, this study obtained the optimal values for the process parameters in order to achieve the maximum rates of extraction of PNF for economically optimal production at an industrial scale. 相似文献
132.
Frontal polymerization (FP) is a process in which the heat generated by the self-reaction transforms monomers to cured polymers. Here, in order to improve the flexibility of polydicyclopentadiene, comonomers (norbornene-terminated polyether, ND-230,400,2000) are designed and synthesized, which can copolymerize with dicyclopentadiene (DCPD) by FP. The polymers (ND) prepared by ND-2000 and DCPD have tunable mechanical properties, from thermosets to elastomers. Specifically, the breaking elongation of the polymers can be varied 69-fold, from 6.1% to 423.4% by controlling the proportion of ND-2000. Among them, ND polymer with 50 wt% ND-2000 has good elastic behavior without yield. And, the reaction mixture solutions of DCPD and ND-2000 have the characteristics of controllable gel time and shear thinning, which make it have the potential of application in additive manufacturing. 相似文献
133.
Simultaneous determination of three chloroacetic acids,three herbicides,and 12 anions in water by ion chromatography
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An ion chromatography method was developed for the simultaneous detection of three soluble herbicides (glyphosate, bentazone and picloram), three chlorine disinfection byproducts (monochloroacetic acid, dichloroacetic acid and trichloroacetic acid) and 12 anions in water (Cl–, Br–, SO42–, CO32–, ClO3–, ClO4–, BrO3–, PO43–, NO2–, NO3–, CH3COO– and COO–). High linearity (r2 > 0.996) was observed for all target analytes for each respective concentration range. The limit of detection and limit of quantitation were between 0.21–0.85 and 0.06–25.46 μg/L, respectively. However, the interference effect of Cl–, NO3–, SO42– and CO32– on some target analytes must be considered during the analysis. Sample pre‐treatment by a hydrogen column (H‐column) required to reduce the negative effect of CO32–. Additionally, sample pre‐treatment by a sliver–hydrogen column (Ag–H‐column) is required when Cl– > 100 mg/L and SO42– < 50 mg/L, and pre‐treatment by both a barium column (Ba‐column) and an H‐column is required when Cl– > 100 mg/L and SO42– > 50 mg/L. When Cl– > 100 mg/L, SO42– > 50 mg/L and CO32– > 20 mg/L, the sample pre‐treatment by either an Ag–H–Ba‐column or an Ag–H‐column and Ba‐column is required to minimize interference. 相似文献
134.
135.
As a multi-particle entangled state, the Greenberger–Horne–Zeilinger (GHZ) state plays an important role in quantum theory and applications. In this study, we propose a flexible multi-user measurement-device-independent quantum key distribution (MDI-QKD) scheme based on a GHZ entangled state. Our scheme can distribute quantum keys among multiple users while being resistant to detection attacks. Our simulation results show that the secure distance between each user and the measurement device can reach more than 280 km while reducing the complexity of the quantum network. Additionally, we propose a method to expand our scheme to a multi-node with multi-user network, which can further enhance the communication distance between the users at different nodes. 相似文献
136.
提出一种新的求解约束优化问题的遗传算法,算法通过重新定义可行解与不可行解的适应度函数分别对它们进行选择,有效避免了惩罚函数法引入参数所带来的困难,重新设计的交叉算子使得算法对解空间的寻优范围扩大了.数值实验结果表明算法具有较好的鲁棒性,且对最优解位于约束边界上的一类问题具有很大优势. 相似文献
137.
138.
Synthesis and Self‐Assembly of Thermoresponsive Amphiphilic Biodegradable Polypeptide/Poly(ethyl ethylene phosphate) Block Copolymers
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Qiuhua Wu Dan Zhou Renyu Kang Xiuping Tang Qi Yang Ximing Song Guolin Zhang 《化学:亚洲杂志》2014,9(10):2850-2858
We report the design and synthesis of new fully biodegradable thermoresponsive amphiphilic poly(γ‐benzyl L ‐glutamate)/poly(ethyl ethylene phosphate) (PBLG‐b‐PEEP) block copolymers by ring‐opening polymerization of N‐carboxy‐γ‐benzyl L ‐glutamate anhydride (BLG? NCA) with amine‐terminated poly(ethyl ethylene phosphate) (H2N? PEEP) as a macroinitiator. The fluorescence technique demonstrated that the block copolymers could form micelles composed of a hydrophobic core and a hydrophilic shell in aqueous solution. The morphology of the micelles as determined by transmission electron microscopy (TEM) was spherical. The size and critical micelle concentration (CMC) values of the micelles showed a decreasing trend as the PBLG segment increased. However, UV/Vis measurements showed that these block copolymers exhibited a reproducible temperature‐responsive behavior with a lower critical solution temperature (LCST) that could be tuned by the block composition and the concentration. 相似文献
139.
140.
Meihui Li Jianping Xu Ximing Chen Xiaosong Zhang Yanyu Wu Ping Li Xiping Niu Chengyuan Luo Lan Li 《Superlattices and Microstructures》2012
Zn1−xCoxO nanocrystals with nominal Co doping concentrations of x = 0–0.1 were synthesized through a simple solution route followed by a calcining process. The doping effects on the structural, morphological and optical properties were investigated by means of X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Raman, absorption and luminescence spectroscopy. The results indicated that a small amount of Co ions were incorporated into ZnO lattice structure, whereas the secondary phase of Co3O4 was segregated and precipitated at high Co doping concentrations, the solid solubility of Co ions in ZnO nanocrystals could be lower than 0.05. The spectra related to transitions within the tetrahedral Co2+ ions in the ZnO host crystal were observed in absorption and luminescence spectra. 相似文献