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91.
92.
A fluorocarbon-modified poly(N-isopropylacrylamide) has been synthesized by copolymerization of N-isopropyl acrylamide with a small amount of acrylate or methacrylate containing a perfluoroalkyl group. It was found that the hydrophilicity of macromolecular backbone is an important factor to the solution properties of the copolymers and that hydrophobic association between fluorocarbon groups is stronger than that between the corresponding hydrocarbon analogies. The viscosity of some of the copolymer solutions was very sensitive to temperature. It was dilatant at higher fluorocarbon comonomer content ( > 0.20-1.0 mol%) and was Newtonian at very low fluorocarbon comonomer content (0.03-0.2 mol% ) . Evidence for hydrophobic association of the fluorocarbon groups was obtained from the effects of adding Nad and surfactants on the solution viscosity. The LC-ST properties of these copolymers were studied by DSC method and this was also found to be consistent with hydrophobic association between the fluorocarbo 相似文献
93.
M. B. Belonenko S. Yu. Glazov N. G. Lebedev N. E. Meshcheryakova 《Physics of the Solid State》2009,51(8):1758-1764
Physics of the Solid State - The interaction of electromagnetic waves with carbon nanotubes has been investigated theoretically. The dynamics of nonlinear electromagnetic waves is considered in... 相似文献
94.
Interest in zirconia as a chromatography support has increased considerably recently because of its chemical inertness and its promise as a useful support. We have reported the preparation of spherical zirconia and characterization of its chromatographic behavior. However, the zirconia was found unsatisfactory for its chromatographic efficiency, probably owing to the poor pore structure of it. In this paper, we for the first time report the preparation of alkylphosphonic acid modified zirconia-magnesia stationary phase, and characterization of its structure and chromatographic behavior. 相似文献
95.
研究了碱基在十二胺-N,N-二亚甲基膦酸(DDPA)改性氧化锆固定相(DPZ)上的色谱保留行为,考察了流动相中甲醇含量、流动相pH值、缓冲溶液中离子类型和离子强度对碱基保留的影响,对DDPA在氧化锆表面的吸附方式进行了研究。研究结果表明,DDPA仅以一个膦酸基与氧化锆结合,因而DPZ固定相表面上除了有长链的疏水烷基外,还有酸性的膦酸基和碱性的氨基。碱基分子中也存在氨基和酰胺基等极性基团,因此碱基在DPZ固定相上除了有疏水作用外,还具有电荷排斥作用、离子交换作用等多种保留机理。由于多种保留机理的存在,使得碱基在DPZ固定相上具有较好的分离选择性,在酸性条件下对碱基混合样品的分离取得了满意的结果。 相似文献
96.
WANG Rui DA Chao-Shan LIU Da-Xue YANG Xiao-wu XIN Zhuo-Qun DONG Shou-Liang ShEN Jan-Heng SU Wu WANG Heng-shan WANG Quan ZHANG Li-Chen CHAN Albert S.C 《高等学校化学研究》2001,17(3)
Catalytic asymmetric carbon-carbon bond formation is one of the most important reactions and have attracted much attention to develop more efficient enantioselective C-C formation methods in organic synthesis. In this field, asymmetric addition of diethylzinc to aldehydes[1] and conjugate addition to enones[2] have drawn special interests and have been greatly developed. Regardless of it, much spaces in these areas still exist, so it needs more extensive and intensive researches for the purpose of as follows: (1) attaching ligands to a polymer for the easy separation of the catalysts so as to be able to allow very efficient recovery and reuse of the catalysts, and the possibility of carrying out the desired transfomation in continuous mode in a flow reactor, etc., (2) searching for novel chiral catalysts with such features as more suitable for more extensive substrates varieties, and more convenient and economical as well as possessing applicable prospect, and so on. Here we report some works in these areas done in our laboratory. 相似文献
97.
Photoacoustic microscopy is applied to observe the surface structure of Cu-Al-Ni shape-memory single crystals in both the loaded and unloaded state. Visualizing the early stages of the loading-induced martensitic transformation is demonstrated to be feasible. The photoacoustic images are distinguished to advantage from the corresponding CCD images by a higher contrast between different phases of the shape memory alloy. 相似文献
98.
M.V. Glazov M.V. Braginsky L.A. Lalli O. Richmond 《Applied Physics A: Materials Science & Processing》1998,67(5):571-578
Received: 23 June 1998/Accepted: 15 July 1998 相似文献
99.
甘氨酸衍生化β-环糊精键合硅胶液相色谱固定相的合成与评价 总被引:1,自引:0,他引:1
β-环糊精键合硅胶经对甲苯磺酰化后,与甘氨酸反应得到甘氨酸衍生化β-环糊精键合硅胶固定相(GCDS)。考察了GCDS对位置异构体、丹磺酰化氨基酸异构体、苯丙酸类药物等的分离性能,研究了流动相中甲醇浓度、pH以及柱温对色谱保留行为的影响。 相似文献
100.
A microscopic theory of spin fluctuations in an ensemble of electrons localized on donors in a bulk semiconductor has been developed. Both the hyperfine interaction of the electron spin with spins of host lattice nuclei and the exchange interaction between the electrons have been taken into account. A model of clusters to calculate spin noise spectra of the ensemble of localized charge carriers has been proposed. It has been shown that the electron-electron exchange interaction leads to an effective averaging of random nuclear fields and a shift of the peak in the spin-fluctuation spectrum towards lower frequencies. 相似文献