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951.
C. Strazielle 《European Polymer Journal》1979,15(1):55-59
This paper presents the results of a study of the thermodynamic properties of a ternary system viz. solvent (ethylacetate or benzene)-polydimethylsiloxane-polystyrene. The interaction parameter between the two polymers χ23, determined both from light scattering and studies of the critical conditions of phase separation, has been studied as a function of the molecular weights of the two polymers. Using a polystyrene of fixed molecular weight, we observe a large decrease in χ23 for increasing molecular weight of polydimethylsiloxane. When the molecular weights of the two polymers are very high, the parameter χ23 becomes very small (of the order of 0.01). The values of χ23 obtained for these two polymers are compared to those found for comparable systems, viz. polystyrene-polyisobutene and polydimethylsiloxane-polyisobutene. 相似文献
952.
D. H. Beebe C. E. Gordon R. N. Thudium M. C. Throckmorton T. L. Hanlon 《Journal of polymer science. Part A, Polymer chemistry》1978,16(9):2285-2301
A quantitative procedure has been developed for characterizing the complete microstructure of polymers of 1,3-pentadiene, including the tacticity of any crystalline component. This can be accomplished by a combination of infrared spectroscopy, X-ray crystallinity, and 300-MHz NMR spectroscopy. A series of high structural purity polymers were synthesized with a series of previously unreported mixed microstructures. These samples were characterized by using the three techniques mentioned, including the previously unreported 300-MHz NMR data. With those results a 60-MHz NMR/IR method of spectroscopy was developed to determine the composition of poly(1,3-pentadiene)s in terms of percent cis-1,2-, cis-1,4-, trans-1,4-, and 3,4-pentadiene units. 相似文献
953.
The coulometric determination of thioacetamide (TAA) with electrogenerated silver is described. The titration is done in a solution 0.1M in both ammonia and sodium hydroxide, and the end-point is detected potentiometncally with a silver-silver sulphide electrode. On repeat analyses of approx. 2-mg samples of TAA an average error of -04% (relative standard deviation 0.25%) was obtained. Important steps in the procedure include cleaning the silver generating electrode in nitric acid before each titration, purging well with nitrogen to remove oxygen, and not using too large a sample. 相似文献
954.
This work reports the experimental results of the uniaxial pressure dependence at various temperatures of the spin-lattice relaxation time, T1, in paradichlorobenzene single crystals.The directionality of the pressure dependence, together the temperature dependence ot T1 near room temperature, give us some information about the dependence of the molecular torsional frequencies and lifetimes of the oscillations ground levels with the intermolecular crystalline potential. 相似文献
955.
D. Bagatti M. C. Cantone A. Giussani S. Ridone C. Birattari M. L. Bonardi F. Groppi A. Martinotti S. Morzenti M. Gallorini E. Rizzio 《Journal of Radioanalytical and Nuclear Chemistry》2005,263(2):515-520
Summary The nuclear properties of 186gRe make it a useful agent for radionuclide therapy and imaging. The coordination compound [186gRe]Re-HEDP has proved to be a successful bone seeking agent for palliation of metastatic bone pain. Chemical, radiochemical and radionuclidic purity of commercial radiopharmaceutical [186gRe]Re-HEDP have been checked by means by γ- and β-spectrometries, INAA and paper radio-chromatography. The results indicate a good radionuclidic purity, with levels of contamination from the short-lived 188Re well below the required specifications. After injection of the radiopharmaceutical, the radiochemical measurements conducted in vivo, on biological matrices, blood, plasma and urine, have shown that, entering the systemic circulation, 186gRe dissociates from the bis-phosphonate complex as hydrosoluble [186gRe]ReO4-, and the two chemical species follow different biokinetics. 相似文献
956.
Wuest JD 《Chemical communications (Cambridge, England)》2005,(47):5830-5837
Detailed structures of molecular crystals cannot yet be predicted with consistent accuracy, but the strategy of molecular tectonics offers crystal engineers a powerful tool for designing molecules that are predisposed to form crystals with particular structural features and properties. 相似文献
957.
The structures and energetics of Li(6) (+), Li(6) (-) and three isomers of Li(6) are investigated using the coupled-cluster singles, doubles and perturbative triples [CCSD(T)] method with valence and core-valence correlation consistent basis sets of double- to quadruple-zeta quality (cc-pVXZ and cc-pCVXZ, where X=D-Q). These results are compared with qualitatively different predictions by less reliable methods. Our results conclusively show that the D(4h) isomer is the global minimum structure for Li(6). It is energetically favored over the C(5v) and D(3h) structures by about 5.1 and 7.1 kcal mol(-1), respectively, after the inclusion of the zero-point vibrational energy (ZPVE) correction. Our most accurate total atomization energies are 123.2, 117.6, and 115.7 kcal mol(-1) for the D(4h), C(5v), and D(3h) isomers, respectively. Comparison of experimental optical absorption spectra with our computed electronic spectra also indicate that the D(4h) isomer is indeed the most stable structure. The cation, anion, and some higher spin states are investigated using the less expensive cc-pCVDZ basis set. Adiabatic ionization energies and electron affinities are reported and compared with experimental values. Predictions of molecular properties are found to be sensitive to the basis set used and to the treatment of electron correlation. 相似文献
958.
D.G. Aksenov O.V. Klimov G.V. Echevskii E.A. Paukshtis A.A Budneva 《Reaction Kinetics and Catalysis Letters》2004,83(1):187-194
Catalytic conversion of an oil distillate with the added extra amounts of thiophene over a zeolite catalyst was studied. The
rate of the catalyst deactivation was found to increase with the increase in the thiophene concentration in the feed. A possible
pathway of the thiophene conversion is discussed. 相似文献
959.
Electronically excited NF in both the a1Δ and b 1Σ+ states hasbeen observed from the reaction of fluorine atoms with HN3. The results suggest that fluorine atoms first abstract the hydrogen atom from HN3, then react with the remaining N3 to form NF≠(a1Δ). NF*(b1Σ+) is produced by a subsequent energy pooling reaction between NF≠(a1Δ) and vibrationally excited HF. The rate of the F + N3 reaction is estimated to be ≈ 1012 and 3 mole?1 s?1. 相似文献
960.
The synthesis of N-acyl derivatives of γ - keto - α - amino acids (3, 4, 5) by the amidoalkylation of 1,3-dicarbonyl compounds with glyoxylic acid-amide adducts (1, 2) is described. The γ - keto - α - amino acid derivatives (4, 5) were further converted to the corresponding butenolides (6, 7) and to pyrazolylglycine (12). 相似文献