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941.
942.
O. A. Alekseeva N. I. Sorokina I. A. Verin T. Yu. Losevskaya V. I. Voronkova V. K. Yanovskii V. I. Simonov 《Crystallography Reports》2003,48(2):205-211
This study is a continuation of research into the atomic structure and physical properties of niobium-doped potassium titanyl phosphate crystals, KTiOPO4 (KTP: Nb). Crystals containing 7 and 11 at. % of niobium were grown and studied. With an increase in niobium content, the number of vacancies and additional potassium positions in the structure also increase. This fact accounts for an increase in both the intensities of relaxation peaks and the conductivity of KTP: Nb crystals. 相似文献
943.
I. P. Kuranova K. M. Polyakov E. A. Smirnova W. E. Höhne V. S. Lamzin R. Meijer 《Crystallography Reports》2003,48(6):953-958
Crystals of Saccharomyces cerevisiae inorganic pyrophosphatase suitable for X-ray diffraction study were grown by cocrystallization of the enzyme with cobalt chloride and imidodiphosphate. Saccharomyces cerevisiae is a metal-dependent enzyme which catalyzes hydrolysis of inorganic pyrophosphate to orthophosphate. The three-dimensional structure of this enzyme was solved by the molecular-replacement method and refined at 1.8 Å resolution to an R factor of 19.5%. Cobalt and phosphate ions were revealed in the active centers of both identical subunits (A and B) of the pyrophosphatase molecule. In subunit B, a water molecule was found between two cobalt ions. It is believed that this water molecule acts as an attacking nucleophile in the enzymatic cleavage of the pyrophosphate bond. It was demonstrated that cobalt ions and a phosphate group occupy only part of the potential binding sites (two chemically identical and crystallographically independent subunits have different binding sites). The arrangement of ligands and the structure of the nucleophile-binding site are discussed in relation to the mechanism of action of the enzyme and the nature of the metal activator. 相似文献
944.
G.D. Manolis 《Journal of sound and vibration》2003,266(2):281-305
This work examines elastic wave scattering around cavities embedded in a continuum with depth-dependent shear modulus and under conditions of plane strain. A restricted case of inhomogeneity is considered, where the Poisson ratio is fixed at 0.25 and where the density profile also varies, but proportionally to the shear modulus. For this specific case, the wave speeds remain macroscopically constant and it becomes possible to recover the exact Green functions by using an algebraic transformation method. These functions are subsequently used as kernels in a standard 2D boundary element formulation defined in the Laplace transform domain. The final step involves an inverse Laplace transformation, whereby the transient behavior of cavities in the aforementioned inhomogeneous continuum can be recovered. Two basic examples are solved, namely the circular cylindrical cavity under sudden internal explosion and under a pressure wave sweep. In the latter case, it is possible to investigate the effect that the angle of wave incidence has on the displacement and stress that develop along the cavity's perimeter, given the fact that the shear modulus is changing along the vertical direction. These examples serve to illustrate the present approach and to reveal some interesting differences that are observed in transient wave scattering phenomena between homogeneous and continuously inhomogeneous models, where the latter models yield a more realistic representation of geological formations. 相似文献
945.
H. Yonemura S. Moribe K. Hayashi M. Noda H. Tokudome S. Yamada H. Nakamura 《Applied magnetic resonance》2003,23(3-4):289-307
Photoinduced intramolecular electron-transfer reactions in carbazole (Cz)-fullerene (C60) (Cz(8)C60) and phenothiazine (Ph)-C60 (Ph(n)C60 (n=8, 10, 12)) linked compounds have been investigated in benzene and benzonitrile by fluorescence, transient absorption, and time-resolved electron paramagnetic resonance measurements, and by magnetic field effects on the decay rate constants of the photogenerated biradicals. In benzonitrile, photoinduced intramolecular electron transfer from Cz to the singlet excited state of C60 (1C60 *) occurred in Cz(8)C60, but not to the triplet excited state (3C60 *), while the intramolecular electron-transfer to both1C60 * and3C60 * occurred in Ph(n)C60 (n=8, 10, 12). In benzene, on the other hand, no electron transfer to both1C60 * and3C60 * took place in all linked compounds. These results were interpreted in terms of the different Gibbs free energy changes in the two solvents. 相似文献
946.
Timoshenko's theory of vibrating beams requires a shear correction factor to correctly take into account the effects of shear deformation for different beam cross-sections. This correction is crucial for a precise determination of the shear modulus from the resonant frequencies. Hutchinson's beam theory is used to derive a new shear correction coefficient for anisotropic materials. A comparison is made with other shear coefficients for anisotropic materials published in the literature. Computer-simulated spectra are used to validate the new anisotropic shear correction coefficient. 相似文献
947.
V. I. Tsoy 《Optics and Spectroscopy》2003,94(4):607-612
In the framework of the matrix formulation of the coupled plane wave approach, a method is proposed for increasing the stability of the numerical analysis of vector electromagnetic fields in periodic structures, including dielectric and metallic anisotropic layers and relief boundaries. 相似文献
948.
The operating principles, design, and characteristics of an ion source with a cold magnetron cathode and magnetic plasma compression are described. The source is intended for the injector of a linear proton accelerator. 相似文献
949.
The local vibrational spectra of copper crystals containing vacancies are calculated using the pair atomic potential derived in the framework of the resonance pseudopotential theory. The calculations are performed by a recursive method with due regard for the symmetry of the defect region. The frequencies of the vacancy-induced resonance vibrations of different symmetries are determined. 相似文献
950.
Yu. M. Pechatnikov 《Technical Physics》2003,48(12):1522-1526
Transition (molecular-viscous) isothermal channel flow of rarefied gases is considered. Present-day engineering physical models of transition gas flow and methods of simulation are analyzed and verified in terms of the kinetic theory on the micro-and macrolevels. 相似文献