全文获取类型
收费全文 | 697篇 |
免费 | 6篇 |
国内免费 | 9篇 |
专业分类
化学 | 394篇 |
晶体学 | 1篇 |
力学 | 16篇 |
数学 | 116篇 |
物理学 | 185篇 |
出版年
2022年 | 5篇 |
2019年 | 10篇 |
2018年 | 9篇 |
2017年 | 9篇 |
2016年 | 11篇 |
2014年 | 7篇 |
2013年 | 18篇 |
2012年 | 25篇 |
2011年 | 28篇 |
2010年 | 15篇 |
2009年 | 18篇 |
2008年 | 24篇 |
2007年 | 30篇 |
2006年 | 43篇 |
2005年 | 45篇 |
2004年 | 22篇 |
2003年 | 15篇 |
2002年 | 19篇 |
2001年 | 24篇 |
2000年 | 13篇 |
1999年 | 7篇 |
1998年 | 5篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 5篇 |
1992年 | 10篇 |
1991年 | 8篇 |
1990年 | 11篇 |
1989年 | 8篇 |
1988年 | 12篇 |
1987年 | 9篇 |
1986年 | 13篇 |
1985年 | 17篇 |
1984年 | 15篇 |
1982年 | 13篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1977年 | 10篇 |
1976年 | 7篇 |
1975年 | 12篇 |
1974年 | 9篇 |
1973年 | 11篇 |
1971年 | 5篇 |
1966年 | 6篇 |
1938年 | 10篇 |
1933年 | 4篇 |
1890年 | 4篇 |
排序方式: 共有712条查询结果,搜索用时 15 毫秒
41.
Trifluoroacetic acid efficiently catalyzes Prins cyclizations of enol ethers 8 to provide tetrahydropyrans 9 and 10. These tetrahydropyrans are isolated with combined yields of 42-85% and stereoselectivities at C(4) ranging from 95:5 to 50:50 depending on the nature of the substituent R. Unique byproducts of these cyclizations that reveal the presence of underlying equilibria have been isolated and identified. [reaction: see text] 相似文献
42.
Eisenstein BI Ernst J Gladding GE Gollin GD Hans RM Johnson E Karliner I Marsh MA Plager C Sedlack C Selen M Thaler JJ Williams J Edwards KW Sadoff AJ Ammar R Bean A Besson D Zhao X Anderson S Frolov VV Kubota Y Lee SJ Poling R Smith A Stepaniak CJ Urheim J Ahmed S Alam MS Athar SB Jian L Ling L Saleem M Timm S Wappler F Anastassov A Eckhart E Gan KK Gwon C Hart T Honscheid K Hufnagel D Kagan H Kass R Pedlar TK Thayer JB von Toerne E Zoeller MM Richichi SJ Severini H Skubic P Undrus A Savinov V 《Physical review letters》2001,87(6):061801
Using 12.7 fb(-1) of data collected with the CLEO detector at CESR, we observed two-photon production of the cc states chi(c0) and chi(c2) in their decay to pi(+)pi(-)pi(+)pi(-). We measured gamma(gammagamma)(chi(c))xB(chi(c)-->pi(+)pi(-)pi(+)pi(-)) to be 75+/-13(stat)+/-8(syst) eV for the chi(c0) and 6.4+/-1.8(stat)+/-0.8(syst) eV for the chi(c2), implying gamma(gammagamma)(chi(c0)) = 3.76+/-0.65(stat)+/-0.41(syst)+/-1.69(br) keV and gamma(gammagamma)(chi(c2)) = 0.53+/-0.15(stat)+/-0.06(syst)+/-0.22(br) keV. Also, cancellation of dominant experimental and theoretical uncertainties permits a precise comparison of gamma(gammagamma)(chi(c0))/gamma(gammagamma)(chi(c2)), evaluated to be 7.4+/-2.4(stat)+/-0.5(syst)+/-0.9(br), with QCD-based predictions. 相似文献
43.
Ammar R Bean A Besson D Davis R Kwak N Zhao X Anderson S Frolov VV Kubota Y Lee SJ Mahapatra R O'Neill JJ Poling R Riehle T Smith A Stepaniak CJ Urheim J Ahmed S Alam MS Athar SB Jian L Ling L Saleem M Timm S Wappler F Anastassov A Duboscq JE Eckhart E Gan KK Gwon C Hart T Honscheid K Hufnagel D Kagan H Kass R Pedlar TK Schwarthoff H Thayer JB von Toerne E Zoeller MM Richichi SJ Severini H Skubic P Undrus A Chen S Fast J Hinson JW Lee J Miller DH Shibata EI Shipsey IP Pavlunin V 《Physical review letters》2001,86(7):1167-1170
Using data recorded with the CLEO II and CLEO II.V detector configurations at the Cornell Electron Storage Rings, we report the first observation and mass measurement of the Sigma(*+)(c) charmed baryon, and an updated measurement of the mass of the Sigma(+)(c) baryon. We find M(Sigma(*+)(c))-M(Lambda(+)(c)) = (231.0+/-1.1+/-2.0) MeV, and M(Sigma(+)(c))-M(Lambda(+)(c)) = (166.4+/-0.2+/-0.3) MeV, where the errors are statistical and systematic, respectively. 相似文献
45.
We prove that when q is any odd prime power, the distance-2 graph on the set of vertices at maximal distance D from any fixed vertex of the Hemmeter graph HemD(q) is isomorphic to the graph QuadD-1(q) of quadratic forms on . 相似文献
46.
47.
Hugh Chaffey‐Millar Gene Hart‐Smith Christopher Barner‐Kowollik 《Journal of polymer science. Part A, Polymer chemistry》2008,46(5):1873-1892
A mass spectrometry analysis has been performed on complex architecture polymeric material produced during reversible addition fragmentation chain transfer (RAFT) polymerizations yielding star polymers. Para‐acetoxystyrene (AcOSty) has been polymerized at 60 °C, using azobisisobutyronitrile (AIBN) as the thermally decomposing initiator, in the presence of the R‐group approach tetrafunctional RAFT agent (1,2,4,5‐tetrakis‐(2‐phenyl‐thioacetyl‐sulfanylmethyl)‐benzene). In addition to ideal star material, a variety of products unique to this mode of polymerization have been identified. These include star–star couples, stars terminated with initiator fragments, star–star couples terminated with initiator fragments and linear polymers, supporting the notion that these species are responsible for the structured molecular‐weight distributions measured for these systems when analyzed via gel permeation chromatography. The analysis begins with a study of AcOSty polymerizing (i) in the absence of any mediating agent and (ii) in the presence of a monofunctional RAFT agent, revealing the mode of termination of propagating poly(AcOSty) radicals as combination and that some ionization biases exist among variants of poly (AcOSty). The interpretation of the mass spectrometry data has been aided by a novel kinetic model of star polymerizations, allowing the rationalization of experimental observations with theoretical expectations. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1873–1892, 2008 相似文献
48.
Edward Hart Charles O. Currier J. Habermann und U. Kreusler 《Fresenius' Journal of Analytical Chemistry》1885,24(1):78-80
Ohne Zusammenfassung 相似文献
49.
D. H. Brick A. M. Shapiro M. Widgoff E. D. Alyea Jr. T. Fuess E. S. Hafen P. Haridas R. I. Hulsizer C. Milstene I. A. Pless R. K. Yamamoto F. Grard R. Dolfini S. Ratti R. Di Marco M. Kalelkar R. J. Plano P. E. Stamer S. Dado J. Goldberg R. Heifetz A. Levy W. M. Bugg T. Handler E. L. Hart Y. Eisenberg U. Karshon 《Zeitschrift fur Physik C Particles and Fields》1986,32(1):59-63
The total hadron multiplicity and the multiplicity in the three-jet events ine + e ?-annihilation are considered. The formula for the total multiplicity (with account for the heavy quark contribution) agrees well with experiment. The value of the multiplicity for three-jet events is predicted. 相似文献
50.
Sergiu Hart 《International Journal of Game Theory》2008,36(3-4):441-460
A class of integer-valued allocation games—“General Lotto games”—is introduced and solved. The results are then applied to analyze the classical discrete “Colonel Blotto games”; in particular, optimal strategies are obtained for all symmetric Colonel Blotto games. 相似文献