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111.
Robert D.?Carr Harvey J.?GreenbergEmail author William E.?Hart Goran?Konjevod Erik? Lauer Henry?Lin Tod?Morrison Cynthia A.?Phillips 《Mathematical Programming》2006,107(1-2):337-356
We present a series of related robust optimization models for placing sensors in municipal water networks to detect contaminants
that are maliciously or accidentally injected. We formulate sensor placement problems as mixed-integer programs, for which
the objective coefficients are not known with certainty. We consider a restricted absolute robustness criteria that is motivated
by natural restrictions on the uncertain data, and we define three robust optimization models that differ in how the coefficients
in the objective vary. Under one set of assumptions there exists a sensor placement that is optimal for all admissible realizations
of the coefficients. Under other assumptions, we can apply sorting to solve each worst-case realization efficiently, or we
can apply duality to integrate the worst-case outcome and have one integer program. The most difficult case is where the objective
parameters are bilinear, and we prove its complexity is NP-hard even under simplifying assumptions. We consider a relaxation
that provides an approximation, giving an overall guarantee of near-optimality when used with branch-and-bound search. We
present preliminary computational experiments that illustrate the computational complexity of solving these robust formulations
on sensor placement applications. 相似文献
112.
Eight bromoalkynes were prepared from substituted benzoic acids and treated with n-Bu3SnH to provide trans-fused perhydroindans or cis- and trans-fused perhydronaphthalenes. Atom-transfer reactions that accompany the free radical reactions resulted in several tandem radical cyclizations with formation of up to three carbon-carbon bonds in a single reaction. The relationship between these reactions and an approach to the quassinoid family of natural products is also described. 相似文献
113.
Varun Natu James L. Hart Maxim Sokol Helen Chiang Mitra L. Taheri Michel W. Barsoum 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(36):12785-12790
MXenes have shown promise in myriad applications, such as energy storage, catalysis, EMI shielding, among many others. However, MXene oxidation in aqueous colloidal suspensions when stored in water at ambient conditions remains a challenge. It is now shown that by simply capping the edges of individual MXene flakes, Ti3C2Tz and V2CTz, by polyanions such as polyphosphates, polysilicates or polyborates, it is possible to quite significantly reduce their propensity for oxidation even when held in aerated water for weeks. This breakthrough resulted from the realization that the edges of MXene sheets are positively charged. It is thus an example of selectively functionalizing the edges differently from the MXene sheet surfaces. 相似文献
114.
Dr. Zhao Liu Prof. Dr. Charles C. Sorrell Dr. Pramod Koshy Dr. Judy N. Hart 《Chemphyschem》2019,20(16):2074-2081
Methanol decomposition is a promising method for hydrogen production. However, the performance of current catalysts for this process is not sufficient for commercial applications. In this work, methanol adsorption on the CeO2 low-index surfaces is studied by density functional theory (DFT). The results show that methanol always dissociates spontaneously on the (100) surface, whereas dissociation on the (110) surface is site-selective; dissociation does not occur at all on the (111) surface, where only weak physisorption is found. The results confirm that surfaces with higher energies are more catalytically active. Analysis of the surface geometries shows that the dominant factors for the dissociation of methanol are the degree of undercoordination and the charges of the surface ions. The adsorption energy of each methanol molecule decreases with increasing coverage and there is a transition threshold between dissociative and associative adsorption. The present work indicates that a strategy to design catalysts with high activity is to maximize exposure of surfaces on which the ions have a high degree of undercoordination and a strong tendency to donate/accept electrons. The results demonstrate the importance of appropriately selecting and controlling exposed facets and particle morphology for optimizing catalyst performance. 相似文献
115.
116.
E. B. Hart 《Fresenius' Journal of Analytical Chemistry》1912,51(5):320-321
Ohne Zusammenfassung 相似文献
117.
This paper reports on the development of a novel electrochemical assay for Zn2+ in human sweat, which involves the use of disposable screen-printed carbon electrodes (SPCEs). Initially, SPCEs were used in conjunction with cyclic voltammetry to study the redox characteristics of Zn2+ in a selection of supporting electrolytes. The best defined cathodic and anodic peaks were obtained with 0.1 M NaCl/0.1 M acetate buffer pH 6.0. The anodic peak was sharp and symmetrical which is typical for the oxidation of a thin metal film on the electrode surface. This behaviour was exploited in the development of a differential pulse anodic stripping voltammetric (DPASV) assay for zinc. It was shown that a deposition potential of −1.6 V versus Ag/AgCl and deposition time of 60 s with stirring (10 s equilibration) produced a well-defined stripping peak with Epa = −1.2 V versus Ag/AgCl. Using these conditions, the calibration plot was linear over the range 1 × 10−8 to 5 × 10−6 M Zn2+. The precision was examined by carrying out six replicate measurements at a concentration of 2 × 10−6 M; the coefficient of variation was calculated to be 5.6%. The method was applied to the determination of the analyte in sweat from 10 human volunteers. The concentrations were between 0.39 and 1.56 μg/mL, which agrees well with previously reported values. This simple, low-cost sensitive assay should have application in biomedical studies and for stress and fatigue in sports studies. 相似文献
118.
William B. Hart 《The Ramanujan Journal》2008,15(3):435-468
Sets of appropriately normalized eta quotients, that we call level n Weber functions, are defined, and certain identities generalizing Weber function identities are proved for these functions. Schläfli type modular equations are explicitly obtained for Generalized Weber Functions associated with a Fricke group Γ0(n)+, for n=2,3,5,7,11,13 and 17. 相似文献
119.
Chemical vapor discrimination using a compact and low-power array of piezoresistive microcantilevers
A compact and low-power microcantilever-based sensor array has been developed and used to detect various chemical vapor analytes. In contrast to earlier micro-electro-mechanical systems (MEMS) array sensors, this device uses the static deflection of piezoresistive cantilevers due to the swelling of glassy polyolefin coatings during sorption of chemical vapors. To maximize the sensor response to a variety of chemical analytes, the polymers are selected based on their Hildebrand solubility parameters to span a wide range of chemical properties. We utilize a novel microcontact spotting method to reproducibly coat a single side of each cantilever in the array with the polymers. To demonstrate the utility of the sensor array we have reproducibly detected 11 chemical vapors, representing a breadth of chemical properties, in real time and over a wide range of vapor concentrations. We also report the detection of the chemical warfare agents (CWAs) VX and sulfur mustard (HD), representing the first published report of CWA vapor detection by a polymer-based, cantilever sensor array. Comparisons of the theoretical polymer/vapor partition coefficient to the experimental cantilever deflection responses show that, while general trends can be reasonably predicted, a simple linear relationship does not exist. 相似文献
120.
Stone N Hart Prieto MC Crow P Uff J Ritchie AW 《Analytical and bioanalytical chemistry》2007,387(5):1657-1668
Near-infrared Raman spectroscopy, an optical technique that is able to interrogate biological tissues, has been used to study
bladder and prostate tissues, with the objective being to provide a first approximation of gross biochemical changes associated
with the process of carcinogenesis. Prostate samples for this study were obtained by taking a chip at TURP, and bladder samples
from a biopsy taken at TURBT and TURP, following ethical approval. Spectra were taken from purchased biochemical constituents
and different pathologies within the bladder and the prostate. We were then able to determine the biochemical basis for these
pathologies by utilising an ordinary least-squares fit. We have shown for the first time that we are able to utilise Raman
spectroscopy in determining the biochemical basis for the different pathologies within the bladder and prostate gland. In
this way we can achieve a better understanding of disease processes such as carcinogenesis. This could have major implications
in the future of the diagnosis of disease within the bladder and the prostate gland. 相似文献