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941.
Kinetics and concentration profile associated with the regulated radiodegradation of bilirubin in an organic solvent were
assessed. The pure unconjugated specimen was prepared in chloroform (40.0 μM). The depletion of bilirubin was almost linear
with dose, and complete degradation was accomplished with doses in excess of 100 Gy. The method was also evaluated for the
explicit production of the long-wavelength isomer of biliverdin, which was characterized spectrometrically by an absorbance
band in the region 600–650 nm. Results including differences in air, N2 and O2 purged samples are presented to identify the atmospheric medium for optimum production of biliverdin. The process was regulated
by controlling the dose. The general rate constant of the depletion process was estimated at a dose rate of 5.67·10−2Gy·s−1. The method is a convenient substitute for light illumination studies of bilirubin.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
942.
F. Berthelin F. Bouchut 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2003,20(6):189-997
We consider isentropic gas dynamics equations with unilateral constraint on the density and mass loss. The γ and pressureless pressure laws are considered. We propose an entropy weak formulation of the system that incorporates the constraint and Lagrange multiplier, for which we prove weak stability and existence of solutions. The nonzero pressure model is approximated by a kinetic BGK relaxation model, while the pressureless model is approximated by a sticky-blocks dynamics with mass loss. 相似文献
943.
944.
945.
946.
The frequency or dispersion relation for the least‐squares mixed formulation of the shallow‐water equations is analysed. We consider the use of different approximation spaces corresponding to co‐located and staggered meshes, respectively. The study includes the effect of Coriolis, and the dispersion properties are compared analytically and graphically with those of the mixed Galerkin formulation. Numerical solutions of a test problem to simulate slow Rossby modes illustrate the theoretical results. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
947.
N. Fazeli F. Afshar Taromi 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):135-142
The basis of the two‐step in–in method is as follows: star polymers with poly(divinyl benzene) cores, synthesized by the arm‐first method, include many unreacted double bonds in their core, and these double bonds can be attacked by the carbanions of some monomers such as styrene and dienes. In this work, linear polyisoprene chains were used to attack the double bonds existing in the poly(divinyl benzene) cores of polystyrene star polymers, so that a heteroarm star polymer with polystyrene and polyisoprene arms was synthesized. It was later well characterized with size exclusion chromatography, light scattering, viscometry, UV spectroscopy, dynamic mechanical thermal analysis, and 1H NMR. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 135–142, 2003 相似文献
948.
Kurenkov V. F. Zhelonkina T. A. Ryabysheva N. A. Lobanov F. I. 《Russian Journal of Applied Chemistry》2003,76(8):1310-1314
The influence of single- and double-charged cations on degradation of metal 2-acrylamido-2-methylpropanesulfonate-N-vinylpyrrolidine copolymers in aqueous solutions in the presence of potassium peroxodisulfate, K2S2O8, at 50 and 70°C was studied by viscosimetry. 相似文献
949.
The features of anthracite oxidation as influenced by temperature and time were determined. Physicochemical and sorption characteristics of the resulting cation exchanger were studied. 相似文献
950.
J. M. P. Garcia H. F. M. Filho L. V. Zuquette 《Journal of Thermal Analysis and Calorimetry》2007,89(2):385-388
Angra dos Reis/Itaguai region of the state of Rio de Janeiro, Brazil, is a very problematic area due to the instability of
slope and landslides, due to geological and geomorphological conditions and to the significant and continuous human occupation
over favorable areas is prone to the triggering of landslides. The samples were analyzed by thermogravimetry (TG), derivative
thermogravimetry (DTG) and differential thermal analysis (DTA). This paper analyzes and characterizes the clay minerals and
presence of water, gravitational mass movements’ sites and compares it with sites where gravitational mass movements do not
occur. Indeed, this analysis also attempts to verify the presence of minerals. 相似文献