Linear polyethylene in a glassy phase: The value of the glass-transition temperature

Raman spectroscopy, x-ray diffraction, and thermal analysis are used to investigate the structure of linear high-density polyethylene rapidly quenched from the melt to cryogenic temperatures. All the results point to the production of a glassy phase which crystallizes when heated above 170 K.     

The hall effect in liquid semiconductors

The proper interpretation of the Hall coefficient R_H of liquid semiconductors is still an unsolved problem, and it is a particularly interesting one in view of the frequently observed discrepancy in sign with the Seebeck coefficient. We present some new data which include measurements of the Hall mobility μ_H in liquid thallium-tellurium through the composition range where the Seebeck coefficient S changes sign, and in the range where S is negative. An abrupt change in magnitude of μ_H occurs at the intrinsic composition (Tl₂Te, where S changes sign), and μ_H is observed to have an appreciable dependence on temperature only at this composition. This is consistent with transport by carriers in two bands. μ_H is lower on the Tl-rich side of Tl₂Te, and the formula n_H = 1/R_He yields a value for n_H which is ten times larger than the electron concentration inferred from the composition, assuming that electrons are derived from the Tl in excess of Tl₂Te. We review the various suggested interpretations of the Hall effect in liquid semiconductors from several points of view, and conclude that the conventional formula n = ± 1/R_He is unreliable for inferring either the sign or concentration of the carriers.     

First-language phonotactics in second-language listening

Highly proficient German users of English as a second language, and native speakers of American English, listened to nonsense sequences and responded whenever they detected an embedded English word. The responses of both groups were equivalently facilitated by preceding context that both by English and by German phonotactic constraints forced a boundary at word onset (e.g., lecture was easier to detect in moinlecture than in gorklecture, and wish in yarlwish than in plookwish). The American L1 speakers' responses were strongly facilitated, and the German listeners' responses almost as strongly facilitated, by contexts that forced a boundary in English but not in German (thrarshlecture, glarshwish). The German listeners' responses were significantly facilitated also by contexts that forced a boundary in German but not in English (moycelecture, loitwish), while L1 listeners were sensitive to acoustic boundary cues in these materials but not to the phonotactic sequences. The pattern of results suggests that proficient L2 listeners can acquire the phonotactic probabilities of an L2 and use them to good effect in segmenting continuous speech, but at the same time they may not be able to prevent interference from L1 constraints in their L2 listening.     

Frequency and form as determinants of functor sensitivity in English-acquiring infants

High-frequency functors are arguably among the earliest perceived word forms and may assist extraction of initial vocabulary items. Canadian 11- and 8-month-olds were familiarized to pseudo-nouns following either a high-frequency functor the or a low-frequency functor her versus phonetically similar mispronunciations of each, kuh and ler, and then tested for recognition of the pseudo-nouns. A preceding the (but not kuh, her, ler) facilitated extraction of the pseudo-nouns for 11-month-olds; the is thus well-specified in form for these infants. However, both the and kuh (but not her-ler) facilitated segmentation for 8-month-olds, suggesting an initial underspecified representation of high-frequency functors.     

Formant transitions in fricative identification: the role of native fricative inventory

The distribution of energy across the noise spectrum provides the primary cues for the identification of a fricative. Formant transitions have been reported to play a role in identification of some fricatives, but the combined results so far are conflicting. We report five experiments testing the hypothesis that listeners differ in their use of formant transitions as a function of the presence of spectrally similar fricatives in their native language. Dutch, English, German, Polish, and Spanish native listeners performed phoneme monitoring experiments with pseudowords containing either coherent or misleading formant transitions for the fricatives /s/ and /f/. Listeners of German and Dutch, both languages without spectrally similar fricatives, were not affected by the misleading formant transitions. Listeners of the remaining languages were misled by incorrect formant transitions. In an untimed labeling experiment both Dutch and Spanish listeners provided goodness ratings that revealed sensitivity to the acoustic manipulation. We conclude that all listeners may be sensitive to mismatching information at a low auditory level, but that they do not necessarily take full advantage of all available systematic acoustic variation when identifying phonemes. Formant transitions may be most useful for listeners of languages with spectrally similar fricatives.     

Unavoidable subgraphs of colored graphs

A natural generalization of graph Ramsey theory is the study of unavoidable sub-graphs in large colored graphs. In this paper, we find a minimal family of unavoidable graphs in two-edge-colored graphs. Namely, for a positive even integer k, let S_k be the family of two-edge-colored graphs on k vertices such that one of the colors forms either two disjoint K_k/2's or simply one K_k/2. Bollobás conjectured that for all k and ε>0, there exists an n(k,ε) such that if n?n(k,ε) then every two-edge-coloring of K_n, in which the density of each color is at least ε, contains a member of this family. We solve this conjecture and present a series of results bounding n(k,ε) for different ranges of ε. In particular, if ε is sufficiently close to , the gap between our upper and lower bounds for n(k,ε) is smaller than those for the classical Ramsey number R(k,k).     

Champion data comparison in nuclear research institutes in Europe,the U. S., and Japan

Bibliometric analysis was carried out for champion data comparisons among prestigious nuclear research institutes (PNRI) existed in Japan, the U. S., France, and Germany. The analysis was relied on database INIS (IAEA), ECD (DOE), WOS (Thomson), and SCOPUS (Elsevier). INIS is advanced, key ex-post evaluating tool for determining general research paper-based champion. Over the 30-year time span of research paper publication, the world champion among 11 PNRI is JAERI confirmed by INIS but ORNL confirmed by ECD, WOS, and SCOPUS, the latter two collected journal submitted research paper. Five years ago JAERI is the 3rd ranked institutes following ORNL and ANL. INIS database results revealed that CEA/Grenoble is the French domestic champion regarding research paper publication. Five years ago it was CEA/Saclay. Results from analytical tools used in bibliometric studies should be viewed with careful consideration to learn of any influencing factors because different characteristics exhibited by individual databases can sometimes generate conflicting bibliometric results. This was true among INIS, ECD, WOS, and SCOPUS when looking at trends especially between 5-year periods.     

Strong vortex/boundary layer interactions

This is the second of two papers on the interaction between a longitudinal vortex pair, produced by a delta-wing at angle of attack, and a turbulent boundary layer developing on a flat plate. In the first paper only the outer parts of the vortices entered the boundary layer whereas in this paper the vortices merge with it. In the resultant interaction, the boundary layer between the vortices is kept thin by lateral divergence and a three-dimensional separation line is formed outboard of each vortex. Turbulent, momentum-deficient fluid containing longitudinal vorticity is entrained from the boundary layer along these lines and wrapped around the vortices. As a consequence, the turbulent region of the vortices increases in size and the circulation slowly decreases. It is shown that the flow near the separation line and in the vortices is complicated, and this interaction is expected to be more difficult to calculate than the first. Detailed mean flow and turbulence measurements are reported.     

Comment on the validity of first-order paraxial theory for electron and ion sources with needle-type or pointed geometry

An essential feature of first-order paraxial theory is the assumption that if the potential along the axis of an axially symmetric system is known, then the potential (fields) near the axis can be obtained by a power-series expansion about points lying on axis. However, in traditional first-order theory, which commonly assumes systems with cylindrical symmetry, only terms up to second-order in the coordinate transverse to the beam axis are retained. In this letter we argue that a consequence of this restriction is that traditional first-order paraxial theory should not be applicable to electron and ion sources with pointed or needle-type geometries. In order to treat non-parallel trajectories which occur in the pointed geometries present, say, in field emission liquid metal ion sources, a modified paraxial theory is suggested which describes two-dimensional particle dynamics.This work has been supported in part by the Division of Materials Research, National Science Foundation, Grant No. DMR-81008829