Synthesis and characterization of new porphyrin/4-quinolone conjugates

New porphyrin/4-quinolone conjugates were synthesized from the Suzuki-Miyaura coupling reaction of a β-borylated porphyrin with bromo-4-quinolones containing N-ethyl and N-d-ribofuranosyl substituents. The use of electrospray ionization tandem mass spectrometry showed important information about the fragmentation pathways of the new compounds. It was possible to distinguish between those compounds with the porphyrin moiety linked at the 6-position of the quinolone unit from their 7-substituted isomers. The new compounds showed to be good singlet oxygen generators.     

A class of primal affine scaling algorithms

We obtain a class of primal affine scaling algorithms which generalize some known algorithms. This class, depending on a r-parameter, is constructed through a family of metrics generated by −r power, r ? 1, of the diagonal iterate vector matrix. We prove the so-called weak convergence of the primal class for nondegenerate linearly constrained convex programming. We observe the computational performance of the class of primal affine scaling algorithms, accomplishing tests with linear programs from the NETLIB library and with some quadratic programming problems described in the Maros and Mészáros repository.     

Effect of 300 and 500 MPa pressure treatments on starch–water adsorption/desorption isotherms and hysteresis

Pressure treatments of 300 and 500?MPa during 15?min were found to change starch–water sorption (adsorption and desorption) isotherms and the hysteresis effect, particularly the 500?MPa. This last treatment shifted the adsorption/desorption isotherms downward, compared with non-treated starch and starch treated at 300?MPa. The observed hysteresis effect decreased with the increase in pressure level in the whole a_w range, indicating that adsorption and desorption isotherms became closer. Guggenheim–Anderson–De Boer and Brunauer–Emmett–Teller model parameters Cb, Cg, K and Mm also showed changes caused by pressure, the latter being lower in the pressure-processed samples, thus indicating possible changes on microbial and (bio)chemical stabilities of pressure-processed food products containing starch.     

Solvent extraction studies using tetracycline as complexing agent

The behaviour of tetracycline as an extracting agent for strontium, iodine, barium, molybdenum, technetium, zirconium, niobium, cesium, ruthenium, tellurium and uranium has been studied and the influence of the acidity of the aqueous phase upon extraction of the elements mentioned has been examined. Experiments have been made to determine whether or not the species extracted into the organic phase is the complex formed between tetracycline and the elements considered as well as to determine the time of shaking necessary so that the equilibrium between the phases is attained. As a practical application, the possibility of using the tetracycline-benzyl alcohol system for separating the fission products¹³⁷Cs,¹⁴⁰Ba,¹⁴⁰La,¹⁴¹Ce,¹⁰³Ru,⁹⁵Zr and⁹⁵Nb from each other and from uranium is presented. The same study has been made for¹³¹I,^99mTc,⁹⁹Mo,¹³²Te,²³⁹Np and uranium and the steps necessary for the separation of these elements are proposed.From a thesis submitted by I. I. L. CUNHA to the Instituto de Pesquisas Energéticas e Nucleares-University of São Paulo in partial fulfillment of the requirements for a Doctor of Science's Degree. Work supported by Comissão Nacional de Energia Nuclear.     

Effect of radiofrequency on the sheath-plasma resonance in a low-density plasma

Summary Bohm's theory on plasma probes has been modified, by taking into account the effect of the applied RF voltage on the ion saturation current, for explaining the experimentally detected behaviour of the plasma sheath resonance frequency in a low-temperature and low-density plasma

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Riassunto La teoria di Bohm sulle sonde nei plasmi è stata modificata, tenendo conto dell'effetto dovuto alla tensione RF applicata sulla corrente ionica di saturazione. Si spiega cosi l'andamento della frequenza di risonanza plasma-guaina ionica, rilevato sperimentalmente, in un plasma a bassa temperatura e bassa densità.

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Резюме Предлагается модификация теории Бома для плазменных зондов, которая учитывает влияние приложенного радиочастотного напряжения на ионный ток насыщения. Предложенная модификация позволяет объяснить экспериментально обнаруженное поведение резонансной частоты плазменной оболочки при низкой температуре и при низкой плотности плазмы.

     

First-order Kondo-frustated antiferromagnetic ordering in the heavy electron compound YbAs

¹⁷⁰Yb Mössbauer measurements show that the heavy electron compound YbAs undergoes a first order paramagnetic-antiferromagnetic transition centered at T_N=0.58K. The saturated 4f-shell magnetic moments are reduced by 47% relative to the value predicted by a crystal field model. A study of the line shapes below T_N in the presence of an external field shows that the RKKY exchange energy is about 20 times bigger than k_B T_N. These results show that YbAs presents a magnetic order frustrated by the Kondo effect.supported by CNPq     

57Fe Mössbauer study in the ternary hydrides of ErFe3

The ternary hydride phases ErFe₃Hx (with x=1.5 and 2.7) has been studied by⁵⁷Fe Mössbauer effect. The spectra show that the spin reorientation temperature is increased by the presence of hydrogen in the ErFe₃ lattice and is independent of hydrogen concentration for the two hydrides investigated. A preferential filling of the interstitial sites in the RFe₃ structure is indicated by the data.Work supported in part by Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) and Financiadora de Estudos e Projetos (FINEP).