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41.
We present light scattering results from two different fluid mixtures undergoing phase separation next to a glass interface. We observe a characteristic length scale L, which coarsens as a function of time L ∼ t3/2. This growth is faster than any observed previously in bulk samples. The physical process responsible for it is the formation of a wetting layer of one of the two coexisting phases next to the interface. We discuss recent theoretical attempts to explain the fast kinetic mode. 相似文献
42.
J. W. Cumming 《Journal of Thermal Analysis and Calorimetry》1995,45(5):1089-1098
A method has been developed using thermoanalytical techniques for the analysis of residues from coal-burning fluidised bed plant where limestone is used as a sulphur scavenger. This completely eliminates the need for lengthy wet chemical analyses and allows the derivation of parameters necessary for efficient plant operation, such as limestone addition rate, calcium utilisation efficiency and calcium to sulphur mole ratio. The method also gives values for the unburned carbon content and the ratio of coal ash to limestone derivatives in the sample. 相似文献
43.
Acoustic radiation force has been demonstrated as a method for manipulating micron-scale particles, but is frequently affected by unwanted streaming. In this paper the streaming in a multi-transducer quasi-standing wave acoustic particle manipulation device is assessed, and found to be dominated by a form of Eckart streaming. The experimentally observed streaming takes the form of two main vortices that have their highest velocity in the region where the standing wave is established. A finite element model is developed that agrees well with experimental results, and shows that the Reynolds stresses that give rise to the fluid motion are strongest in the high velocity region. A technical solution to reduce the streaming is explored that entails the introduction of a biocompatible agar gel layer at the bottom of the chamber so as to reduce the fluid depth and volume. By this means, we reduce the region of fluid that experiences the Reynolds stresses; the viscous drag per unit volume of fluid is also increased. Particle Image Velocimetry data is used to observe the streaming as a function of agar-modified cavity depth. It was found that, in an optimised structure, Eckart streaming could be reduced to negligible levels so that we could make a sonotweezers device with a large working area of up to 13 mm × 13 mm. 相似文献
44.
Benjamin P. Cumming Sukanta Debbarma Barry Luther-Davies Min Gu 《Applied physics. B, Lasers and optics》2012,109(2):227-232
We demonstrate compensation for the spherical aberration due to the refractive index mismatch that occurs when a laser beam is focused into a thick arsenic trisulfide (As $_2$ S $_3$ ) film with a high numerical aperture objective. The effects of the aberration at different focal depths on the point spread function have been calculated numerically and the axial response method shown to be a useful measure for compensating the spherical aberration. We show that with the addition of adaptive optics based on a spatial light modulator, the aberration can be significantly reduced, resulting in an increase in peak intensity by a factor of 2.4 and a decrease in axial elongation by a factor of 2.2. 相似文献
45.
Akiba Y Beavis D Beery P Britt HC Budick B Chasman C Chen Z Chi CY Chu YY Cianciolo V Cole BA Costales JB Crawford HJ Cumming JB Debbe R Engelage J Fung SY Gonin M Gushue S Hamagaki H Hansen O Hayano RS Hayashi S Homma S Kaneko H Kang J Kaufman S Kehoe WL Kurita K Ledoux RJ Levine MJ Miake Y Morrison DP Morse RJ Moskowitz B Nagamiya S Namboodiri MN Nayak TK Olness J Parsons CG Remsberg LP Roehrich D Rothschild P Sakurai H Sangster TC Seto R Soltz R Stankus P Steadman SG Stephans GS Sung T 《Physical review letters》1993,70(8):1057-1060
46.
We present a mass-conservative vertex-centred finite volume method for efficiently solving the mixed form of Richards’ equation
in heterogeneous porous media. The spatial discretisation is particularly well-suited to heterogeneous media because it produces
consistent flux approximations at quadrature points where material properties are continuous. Combined with the method of
lines, the spatial discretisation gives a set of differential algebraic equations amenable to solution using higher-order
implicit solvers. We investigate the solution of the mixed form using a Jacobian-free inexact Newton solver, which requires
the solution of an extra variable for each node in the mesh compared to the pressure-head form. By exploiting the structure
of the Jacobian for the mixed form, the size of the preconditioner is reduced to that for the pressure-head form, and there
is minimal computational overhead for solving the mixed form. 相似文献
47.
James Grant Ivonne Escorcia‐Carranza Chong Li Iain J. H. McCrindle John Gough David R. S. Cumming 《Laser u0026amp; Photonics Reviews》2013,7(6):1043-1048
In this article a monolithic resonant terahertz sensor element with a noise equivalent power superior to that of typical commercial room temperature single pixel terahertz detectors and capable of close to real time read‐out rates is presented. The detector is constructed via the integration of a metamaterial absorber and a micro‐bolometer sensor. An absorption magnitude of 57% at 2.5 THz, a minimum NEP of and a thermal time constant of 68 ms for the sensor are measured. As a demonstration of detector capability, it is employed in a practical Nipkow terahertz imaging system. The monolithic resonant terahertz detector is readily scaled to focal plane array formats by adding standard read‐out and addressing circuitry enabling compact, low‐cost terahertz imaging. 相似文献
48.
Iain James Hugh McCrindle James Paul Grant Luiz Carlos Paiva Gouveia David Robert Sime Cumming 《physica status solidi (a)》2015,212(8):1625-1633
49.
50.
Laura Quintana Gomez Amal K. Shehab Ali Al-Shathr William Ingram Mariia Konstantinova Denis Cumming James McGregor 《ChemSusChem》2020,13(3):647-658
The synthesis of oxygenate products, including cyclic ketones and phenol, from carbon dioxide and water in the absence of gas-phase hydrogen has been demonstrated. The reaction takes place in subcritical conditions at 300 °C and pressure at room temperature of 25 barg. This is the first observation of the production of cyclic ketones by this route and represents a step towards the synthesis of valuable intermediates and products, including methanol, without relying on fossil sources or hydrogen, which carries a high carbon footprint in its production by conventional methods. Inspiration for these studies was taken directly from natural processes occurring in hydrothermal environments around ocean vents. Bulk iron and iron oxides were investigated to provide a benchmark for further studies, whereas reactions over alumina and zeolite-based catalysts were employed to demonstrate, for the first time, the ability to use catalyst properties such as acidity and pore size to direct the reaction towards specific products. Bulk iron and iron oxides produced methanol as the major product in concentrations of approximately 2–3 mmol L−1. By limiting the hydrogen availability through increasing the initial CO2/H2O ratio the reaction could be directed to yield phenol. Alumina and zeolites were both observed to enhance the production of longer-chained species (up to C8), likely owing to the role of acid sites in catalysing rapid oligomerisation reactions. Notably, zeolite-based catalysts promoted the formation of cyclic ketones. These proof-of-concept studies show the potential of this process to contribute to sustainable development through either targeting methanol production as part of a “methanol economy” or longer-chained species including phenol and cyclic ketones. 相似文献