Evaluation and optimisation of a splitter injector for capillary chromatography

Summary The repeatability and discrimination of a home-made splitter injector, operated under various conditions, towards a C-6 to C-24 test sample were investigated. Other different test samples were analysed to prove the integrity of the injector. Presented at the 15th International Symposium on Chromatography, Nürnberg, October 1984     

The geometry of African art II. A catalog of Benin patterns

This paper investigates the repeated patterns found in the art of Benin, classifying them on the basis of the 24 plane crystallographic groups. Although the patterns are less varied than in Bakuba art, studied in an earlier paper [1971], the same number, 19, of types occurs. Drawings of each are given, including many examples of each of the seven “one-dimensional” types.     

Electron wind-induced muon drift in metals

A preliminary experiment was carried out by the present authors in collaboration with R. Keitel to search for electron wind-induced muon drift in copper at liquid helium temperatures. Drift was not observed, which is taken as support of Kondo's theory of nonadiabatic damping of light interstitials in metals. The present paper discusses the possibility of increased current and thinner foils and concludes that it should be possible with a carefully optimized experiment to detect muon drift. Weak longitudinal fields do not appear to offer any advantage over the transverse fields in which the original experiment was performed. It is proposed to look for wind-induced drift through muon trapping. Aluminum with manganese trapping centers offers a favorable opportunity for observing drift in this way.     

Creating responsive surfaces with tailored wettability switching kinetics and reconstruction reversibility

We report on the formation of responsive surfaces with tailorable surface reconstruction kinetics and switching hysteresis by thiolene radical addition of mercaptoalkanols with variable lengths to poly(vinylmethylsiloxane) networks. Exposing these elastomer surfaces to water results in rearrangement of the hydrophilic alkanes at the surface. The rearrangement kinetics decreases with increasing number of the methylene spacers (n) in the mercaptoalkanol. The response kinetics is found to be very fast for n = 2 and 6. For instance, upon exposing to water, the water contact angle on 3-mercaptopropanol-based surfaces decreases by approximately 35 degrees at the rate of 2 degrees /s. The high flexibility of the siloxane backbone endows these materials with switching longevity; the materials were able to switch their wettability over 10 cycles with minimum hysteresis. Increasing the number of methylene spacers to n = 11 decreases the surface reorganization dramatically. Formation of semicrystalline regions in such materials (detected via IR) is responsible for initial "sluggish" kinetics and eventual surface "freezing".     

Investigation of GaAs Schottky barrier diodes in the THz range

The properties of GaAs Schottky barrier diodes as video detectors and mixing elements were investigated in the frequency range from 0.8–2.5 THz. For the most sensitive diode, the video responsivity and system noise temperature were measured as a function of incident laser power. The highest video responsivity was 2,000 V/W at 214m and 60 V/W at 118m. For five diodes differing in doping, capacitance, series resistance and anode diameter, the system noise temperature was measured at 214m and 118m. The best single sideband (SSB) values are 12,300 K and 24,200 K at 214m and 118m, respectively. The system noise temperature versus frequency is given over the range from 0.5–3 THz for two specific diodes demonstrating that the sharpness of the I–V characteristics is only of secondary importance for mixer perfomance at such high frequencies.     

Triple differential cross sections in the vicinity of the (2s 2)1 S state of helium

Triple differential cross sections have been measured in the vicinity of the (2s ²)¹ S autoionising state of helium, following impact by 200 eV electrons. The scattered electron detector was set at an angle of ?12° (anti-clockwise) and the forward and backward ejected electron angular ranges scanned. The direct ionisation cross section at an ejected electron energy of 33.5 eV has been obtained and the results for the resonant ionisation of the¹ S state are presented in the Shore/Balashov parametrisation. These measurements are compared with previous experimental data and emphasise the need for new detailed theoretical calculations on the autoionisation process.     

A 250 GHz planar low noise Schottky receiver

A planar quasi-optical Schottky receiver based on the quasi-integrated horn antenna has been developed and tested over the 230–280GHz bandwidth. The receiver consists of a planar GaAs Schottky diode placed at the feed of a dipole-probe suspended on a thin dielectric membrane in an etched-pyramidal horn cavity. The diode has a 1.2m anode diameter and a low parasitic capacitance due to the use of an etched surface channel. The antenna-mixer results in a measured DSB conversion loss and noise temperature at 258GHz of 7.2dB±0.5dB and 1310K±70K, respectively, at room temperature. The design is compatible with SIS mixers, and the low cost of fabrication and simplicity makes it ideal for submillimeter-wave imaging arrays requiring a 10–20% bandwidth.     

μ + Residual polarization in water,CS2, C6F6 and hydrocarbons under strong decoupling fields

The ⁺ decay asymmetry was measured as a function of longitudinal magnetic field (LF) between zero and 10 kG in spin decoupling experiments on muons in water, c-hexane, CS₂, C₆F₆, C₆H₆ etc. The results were compared both with the diamagnetic polarization,P _D, measured by transverse-field (TF) experiments ⁺SR, and with the asymmetry observed in ⁺ spin resonance experiments under longitudinal field. These results have been interpreted in terms of spin conversion and chemical reactions of muonium (Mu) with paramagnetic species such as free radicals in the muon track or spur. It is argued that spin-conversion reactions are responsible for the so-called missing fraction of ⁺ polarization in various media.