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941.
Alexandru C. Razus Liviu Birzan Mihaela Cristea Victorita Tecuceanu Anamaria Hanganu Cristian Enache 《Journal of heterocyclic chemistry》2011,48(5):1019-1027
Pyranylium perchlorates with azulen‐1‐yl moiety in 4‐position and thiophen‐2‐yl or furan‐2‐yl in 2 and 6‐positions were obtained by the substitution of 4‐chloro corresponding salts with azulenes. The pyranylium salts are used as starting materials for the synthesis of pyridine and pyridinium salts. The products were characterized and for pyridines pKa was spectroscopically determined. Several attempts were made for pyridine complexation with metal cations as Hg2+ or Ag+. J. Heterocyclic Chem., (2011). 相似文献
942.
943.
Ilie A Raţ CI Scheutzow S Kiske C Lux K Klapötke TM Silvestru C Karaghiosoff K 《Inorganic chemistry》2011,50(6):2675-2684
Gold(I) and silver(I) complexes of 1-methyl-5-thio-tetrazole (1) have been prepared and the coordination chemistry of this ligand toward metal-phosphine frameworks has been explored. As indicated by IR and Raman data, ligand 1 is deprotonated and the resulted anion acts as a bidentate (S,N)-tetrazole-5-thiolato unit in the new gold(I) complexes, [Au(SCN(4)Me)(PPh(3))] (2), [{Au(SCN(4)Me)}(2)(μ-dppm)] (3), and [{Au(SCN(4)Me)}(2)(μ-dppe)] (4), while it is coordinated only through the sulfur atom as its neutral tetrazole-5-thione form in the silver(I) derivative, [Ag(HSCN(4)Me)(PPh(3))](2)(OTf)(2) (5). Further characterization of the new compounds was performed using multinuclear ((1)H, (13)C, (31)P, (19)F) NMR spectroscopy, mass spectrometry, and DSC measurements. Single-crystal X-ray diffraction studies revealed basically linear P-M-S arrangements in complexes 3-5. The bidentate (S,N) coordination pattern results in a T-shaped (S,N)PAu core in 3 and 4, whereas, in 5, a similar coordination geometry is achieved in the dimer association based on S-bridging ligand 1. Herein, weak (C)H···Au and (C)H···Ag agostic interactions were observed. An intramolecular Au···Au contact occurs in 3, while in 4 intermolecular aurophilic bonds lead to formation of a chain polymer. An intermolecular Ag···Ag contact is also present in the dimer unit of 5. Low-temperature (31)P NMR data for 5 evidenced the presence of monomer and dimer units in solution. Theoretical calculations on model of the complexes 2 and 4 are consistent with the geometries found by X-ray diffraction studies. 相似文献
944.
Adriana Cecilia Csakvari Cristian Moisa Dana G. Radu Leonard M. Olariu Andreea I. Lupitu Anca Ofelia Panda Georgeta Pop Dorina Chambre Vlad Socoliuc Lucian Copolovici Dana Maria Copolovici 《Molecules (Basel, Switzerland)》2021,26(13)
Cannabis sativa L. (hemp) is a plant used in the textile industry and green building material industry, as well as for the phytoremediation of soil, medical treatments, and supplementary food products. The synergistic effect of terpenes, flavonoids, and cannabinoids in hemp extracts may mediate the biogenic synthesis of metal nanoparticles. In this study, the chemical composition of aqueous leaf extracts of three varieties of Romanian hemp (two monoecious, and one dioecious) have been determined by Fourier-Transformed Infrared spectroscopy (FT-IR), high-performance liquid chromatography, and mass spectrometry (UHPLC-DAD-MS). Then, their capability to mediate the green synthesis of silver nanoparticles (AgNPs) and their pottential antibacterial applications were evaluated. The average antioxidant capacity of the extracts had 18.4 ± 3.9% inhibition determined by 2,2-diphenyl-1-picrylhydrazyl (DPPH•) and 78.2 ± 4.1% determined by 2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS™) assays. The total polyphenolic content of the extracts was 1642 ± 32 mg gallic acid equivalent (GAE) L−1. After this, these extracts were reacted with an aqueous solution of AgNO3 resulting in AgNPs, which were characterized by UV−VIS spectroscopy, FT-IR, scanning electron microscopy (SEM-EDX), and dynamic light scattering (DLS). The results demonstrated obtaining spherical, stable AgNPs with a diameter of less than 69 nm and an absorbance peak at 435 nm. The mixture of extracts and AgNPs showed a superior antioxidant capacity of 2.3 ± 0.4% inhibition determined by the DPPH• assay, 88.5 ± 0.9% inhibition as determined by the ABTS•+ assay, and a good antibacterial activity against several human pathogens: Escherichia coli, Klebsiella pneumoniae, Pseudomonas fluorescens, and Staphylococcus aureus. 相似文献
945.
Chiara Franceschini Cristian Giardinà Wolter Groenevelt 《Mathematical Physics, Analysis and Geometry》2018,21(4):29
We present a theorem which elucidates the connection between self-duality of Markov processes and representation theory of Lie algebras. In particular, we identify sufficient conditions such that the intertwining function between two representations of a certain Lie algebra is the self-duality function of a (Markov) operator. In concrete terms, the two representations are associated to two operators in interwining relation. The self-dual operator, which arise from an appropriate symmetric linear combination of them, is the generator of a Markov process. The theorem is applied to a series of examples, including Markov processes with a discrete state space (e.g. interacting particle systems) and Markov processes with continuous state space (e.g. diffusion processes). In the examples we use explicit representations of Lie algebras that are unitarily equivalent. As a consequence, in the discrete setting self-duality functions are given by orthogonal polynomials whereas in the continuous context they are Bessel functions. 相似文献
946.
Giliandro Farias Cristian A. M. Salla Murat Aydemir Ludmilla Sturm Pierre Dechambenoit Fabien Durola Bernardo de Souza Harald Bock Andrew P. Monkman Ivan H. Bechtold 《Chemical science》2021,12(45):15116
Halogenation of a twisted three-fold symmetric hydrocarbon with F, Cl or Br leads to strong modulation of triplet–triplet annihilation and dual phosphorescence, one thermally activated and the other very persistent and visible by eye, with different relative contributions depending on the halide. The room temperature phosphorescence is highly unusual given the absence of lone-pair-contributing heteroatoms. The interplay between the spin–orbit coupling matrix elements and the spatial configuration of the triplet state induces efficient intersystem crossing and thus room temperature phosphorescence even without relying on heteroatomic electron lone pairs. A ninefold increase of the ISC rate after introduction of three bromine atoms is accompanied by a much higher 34-fold increase of phosphorescence rate.Twisted π-systems investigation showed a very unusual HAE, influencing independently the ISC and the dual phosphorescence emission, one being very persistent at room temperature and visible by eye in powder. 相似文献
947.
Cristian A. Coclici Gheorghe Moroanu Wolfgang L. Wendland 《Mathematical Methods in the Applied Sciences》2000,23(5):401-440
We consider a one‐dimensional coupled problem for elliptic second‐order ODEs with natural transmission conditions. In one subinterval, the coefficient ϵ>0 of the second derivative tends to zero. Then the equation becomes there hyperbolic and the natural transmission conditions are not fulfilled anymore. The solution of the degenerate coupled problem with a flux transmission condition is corrected by an internal boundary layer term taking into account the viscosity ϵ. By using singular perturbation techniques, we show that the remainders in our first‐order asymptotic expansion converge to zero uniformly. Our analysis provides an a posteriori correction procedure for the numerical treatment of exterior viscous compressible flow problems with coupled Navier–Stokes/Euler models. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献
948.
949.
Beatrice Bartolomei Maria Sbacchi Dr. Cristian Rosso Ayse Günay-Gürer Dr. Lukáš Zdražil Dr. Alejandro Cadranel Dr. Slavko Kralj Prof. Dirk M. Guldi Prof. Maurizio Prato 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2024,136(5):e202316915
The surface of Carbon Nanodots (CNDs) stands as a rich chemical platform, able to regulate the interactions between particles and external species. Performing selective functionalization of these nanoscale entities is of practical importance, however, it still represents a considerable challenge. In this work, we exploited the organic chemistry toolbox to install target functionalities on the CND surface, while monitoring the chemical changes on the material's outer shell through nuclear magnetic resonance spectroscopy. Following this, we investigated the use of click chemistry to covalently connect CNDs of different nature en-route towards covalent suprastructures with unprecedent molecular control. The different photophysical properties of the connected particles allowed their optical communication in the excited state. This work paves the way for the development of selective and addressable CND building blocks which can act as modular nanoscale synthons that mirror the long-established reactivity of molecular organic synthesis. 相似文献
950.
Marta Igual Adriana Pucean Dan Cristian Vodnar Purificacin García-Segovia Javier Martínez-Monz Maria Simona Chi 《Molecules (Basel, Switzerland)》2022,27(6)
The rosehip (Rosa canina L.) fruit has gained researchers′ attention due to its rich chemical composition in vitamin C, phenols, carotenoids, and high antioxidant activity; meanwhile, polymers such as pea protein are generally recognized as exhibiting a protection role against the extrusion process. Corn snacks extrudates obtained by replacing corn flour with 10% R. canina powder (R) and 10% R. canina with pea protein (RPP) were evaluated for the physicochemical, textural, optical, and nutritional characteristics. A sample manufactured without R. canina powder was used as a control. Hardness, crispiness, chewiness, and solubility index (WSI) of the final extrudates were improved by addition of R. canina and pea protein powder (PP); meanwhile, b* (yellow/blue coordinate), C (chroma), and h* (tone) optical parameters were significantly different from the control sample (p < 0.05). Extrusion highlighted a negative impact on total phenols, carotenoids, vitamin C, and antioxidant activity extrudates, while PP exhibited a good protection against the extrusion process. In vitro digestion increased the bioaccessibility of vitamin C, folate, antioxidant activity, total phenols, and total carotenoids mainly on RPP extrudates. 相似文献