利用浅海声场干涉条纹反演海底参数方法研究

浅海频散特性导致声场在距离-频率平面形成干涉条纹,该干涉条纹蕴含着声源以及海底信息。本文通过降噪、滤波等方法,提取船舶辐射噪声干涉条纹中距离域干涉准周期、波导不变量以及去扩展衰减系数(不考虑扩展损失后接收到噪声级随距离的衰减程度)三种特征量的观测值,基于无限均匀沉积层海底模型,采用简正波计算程序理论计算上述三种特征量作为拷贝,提出一种以模拟退火法作为搜索寻优策略的新的匹配反演海底参数的方法。海试数据处理结果表明,该方法反演估计所得海底密度、声速、衰减系数三参数用于浅海负跃层条件下的声场预报效果比较良好。     

Cs4Sn5S12的溶剂热合成与表征

利用溶剂热法合成了硫代锡酸铯Cs4Sn5S12,单晶X-射线衍射结果表明Cs4Sn5S12属正交晶系,Pbca空间群,a=1.4232(4)nm,b=1.3161(4)nm,c=1.6372(5)nm,α=90°,Z=4。化合物Cs4Sn5S12中含有由八面体Sn S6和三角双锥Sn S5连接形成的层状阴离子[Sn5S12]4-∞。[Sn5S12]4-∞结构中有两种类型硫原子:连接六配位锡原子和五配位锡原子的硫原子以及只与两个五配位锡原子相连的硫原子。紫外-可见漫反射光谱表明Cs4Sn5S12为半导体,禁带宽度为2.3 e V。     

Bilayer structures in cholesteric, cyclic-siloxane liquid crystals

X-ray diffraction has been used to investigate a series of commercially available liquid crystals based on a cyclic penta(methylsiloxane) with combinations of cholesteryl-4'-allyloxybenzoate and biphenyl-4'-allyloxybenzoate mesogens pendant on the siloxane ring. A lamellar, (smectic-like) structure is indicated in the mesophase and quenched glassy solid state. Extended molecular dimensions of the mesogens generally account for the observed d spacings. The mesogens may interdigitate within lamellae but the packing and extent of interdigitation is dependent on the ratio of cholesteryl to biphenyl mesogens. There is probably also a structural contribution from the nano-aggregated (nano-phase separated), immiscible, siloxane-rich layer delineating the lamellae interfaces as this mesophase shows unusually good definition; diffraction patterns exhibit high order reflections (up to 6th order). The lamellae have a macroscopic helicoidal twist about an axis lying in the plane of the lamellae, a cholesteric supramolecular structure, which derives from the chiral, steroid mesogenic component. Surprisingly, this mesophase composed of low molar mass cyclic siloxanes may be drawn into fibres tens of metres in length, to give a morphology having the lamellae normal to the fibre axis.     

Super Riemann surfaces: Uniformization and Teichmüller theory

Teichmüller theory for super Riemann surfaces is rigorously developed using the supermanifold theory of Rogers. In the case of trivial topology in the soul directions, relevant for superstring applications, the following results are proven. The super Teichmüller space is a complex super-orbifold whose body is the ordinary Teichmüller space of the associated Riemann surfaces with spin structure. For genusg>1 it has 3g-3 complex even and 2g-2 complex odd dimensions. The super modular group which reduces super Teichmüller space to super moduli space is the ordinary modular group; there are no new discrete modular transformations in the odd directions. The boundary of super Teichmüller space contains not only super Riemann surfaces with pinched bodies, but Rogers supermanifolds having nontrivial topology in the odd dimensions as well. We also prove the uniformization theorem for super Riemann surfaces and discuss their representation by discrete supergroups of Fuchsian and Schottky type and by Beltrami differentials. Finally we present partial results for the more difficult problem of classifying super Riemann surfaces of arbitrary topology.Enrico Fermi Fellow. Research supported by the NSF (PHY 83-01221) and DOE (DE-AC02-82-ER-40073).     

Numerical studies of laminar flow in ducts and pipes

In part I a method is introduced for the numerical solution of swirling axisymmetric laminar flow situations. Consideration is given to finite difference formulation, boundary condition implementation, iterative solution strategies and pressure calculation. Part II is devoted to the application of the method to non-swirling flow problems. Some of these problems are well covered in the literature whilst others are new. Swirling flows are considered in Part III. In particular, details of separation and vortex breakdown induced by swirl are discussed. All results are supplemented by a selection of contour plots to indicate the nature of the flows predicted.     

Exploring structural effects of ketone catalysts on asymmetric epoxidation of olefins

Several ketone catalysts containing spiro ethers and lactones have been investigated for the asymmetric epoxidation of olefins. The results showed that substituents on the spiro ring of the ketone catalysts have profound effects on enantioselectivity. Results also suggested that the high enantioselectivities previously observed for conjugated cis-olefins with oxazolidinone containing ketones could be partially due to attractive interactions between the R_π group of the olefin and the carbonyl group of the oxazolidinone. In addition, nonbonding interactions such as van der Waals forces and/or hydrophobic interactions between the olefin substituents and the nitrogen substituents of the oxazolidinone may also be involved in stereodifferentiation. The information gained provides additional understanding of factors important for ketone catalyzed epoxidations.     

Phase behavior of cyclic siloxane-based liquid crystalline compounds

A series of 24 cyclic siloxane-based liquid crystalline compounds was synthesized using conventional hydrosilation chemistry. Variables examined included ring size, spacer group length, and type and composition of pendant mesogeric groups. Both pentamethylhydro- and tetramethylhydrosiloxane rings were reacted with mesogens based on cholesterol, biphenyl, or equimolar mixtures of both. Four different length spacer groups containing terminal vinyl groups were used to attach the mesogens to the cyclic siloxane core. The thermotropic liquid crystalline phase behavior was studied using differential scanning calorimetry (DSC) and polarized optical microscopy (POM). A lengthening of spacer groups resulted in lower crystallization temperatures for the biphenyl-based compounds and lower glass transition temperatures for the cholesterol- and mixed mesogen-based compounds. The tetramethyl ring derivatives exhibited higher glass transition or crystallization temperatures than their pentamethyl counterparts. Biphenyl-based compounds exhibited low temperature crystalline phases while the cholesterol-based compounds exhibited low temperature glassy phases. © 1994 John Wiley & Sons, Inc.     

聚呲咯的研究

本文研究了不同电化学氧化聚合条件下所得聚吡咯的红外光谱,X射线光电子能谱、元素分析、X射线衍射图及扫描电子显微镜图等。对聚吡咯的电导性、电导率的依赖性、化学结构及结晶性等进行了讨论。     

INVESTIGATION OF LIGHT-INDUCED CONFORMATION CHANGES IN SPIROPYRAN-MODIFIED SUCCINYLATED POLY(l-LYSINE)

Abstract— To determine the maximum range of coupling between side-chain photochromism and polypeptide conformation change, we modified the carboxylate side chains of succinylated poly(l -lysine) with a spiropyran to form polypeptide I. The extent of modification was determined to be 35.5%. The spacer group length between the polypeptide a-carbon and the dye was 12 atoms, providing minimum polypeptide-dye interaction. Conformation changes were monitored by circular dichroism as a function of light adaptation and solvent composition (hexafluoroisopropanol [HFIP] vs trifluoroethanol [TFE]). Under all solvent compositions, the dark-adapted dye was in the merocyanine form. Light adaptation by visible light converted the dye to the spiropyran form. When dissolved in TFE, I adopted a helical conformation insensitive to light adaptation. With increasing percentage HFIP, a solvent-induced helix-to-coil transition was observed around 80% (vol/vol) HFIP. At 100% HFIP, both light- and dark-adapted forms of I were in the coil state. Near the midpoint of the solvent-induced helix-to-coil transition, light adaptation caused conformation changes. Applying helix-to-coil transition theory, we measured a statistically significant difference in coil segment-HFIP binding constant for light- v.v dark-adapted solutions (6.38 ± 0.03 M^-1vs 6.56 ± 0.03 M^-1), but not for the nucleation parameter σ (1.2 ± 0.4 10^-3 v.v 1.3 ± 0.3 × 10^-3). The small binding constant difference translated to a light-induced binding energy difference of 17 cal/mol/monomer. Near the midpoint of the helix-to-coil transition, collective interactions between monomer units made possible the translation of a small energy difference (less than RT) into large macromolecular conformation changes. This work parallels similar behavior observed in poly(isocyanate) (Green, M. M. et al. J. Am. Chem. Soc. 115 , 4941–4942, 1993). The subtle differences in dye-backbone interaction in I suggested a maximum coupling distance (12 atoms) beyond which polypeptide conformation and dye state are uncoupled.     

高效液相色谱二氮杂冠醚键合相的合成及性能研究

本文报道在硅胶表面进行固－液相反应，合成硅胶键合二氮杂冠醚高效液相色谱固定相。采用有机元素分析、热分析、红外光谱、金属离子的络合容量测定等对键合材料进行鉴定和表征，并对其色谱性能进行了研究。