Phonon driven proton transfer in crystals with short strong hydrogen bonds

Recent work on understanding why protons migrate with increasing temperature in short, strong hydrogen bonds is extended here to three more organic, crystalline systems. Inelastic neutron scattering and density functional theory based simulations are used to investigate structure, vibrations, and dynamics of these systems as functions of temperature. The mechanism determined in a previous work on urea phosphoric acid of low frequency vibrations stabilizing average crystal structures, in which the potential energy well of the hydrogen bond has its minimum shifted towards the center of the bond, is found to be valid here. The new feature of the N-H...O hydrogen bonds studied in this work is that the proton is transferred from the donor atom to the acceptor atom. Molecular dynamics simulations show that in an intermediate temperature regime, in which the proton is not completely transferred, the proton is bistable, jumping from one side of the hydrogen bond to the other. In the case of 3,5-pyridine dicarboxylic acid, which has been studied in most detail, specific phonons are identified, which influence the potential energy surface of the proton in the short, strong hydrogen bond.     

A comparison of adaptive procedures for rapid and reliable threshold assessment and training in naive listeners

In psychoacoustic studies there is often a need to assess performance indices quickly and reliably. The aim of this study was to establish a quick and reliable procedure for evaluating thresholds in backward masking and frequency discrimination tasks. Based on simulations, four procedures likely to produce the best results were selected, and data collected from 20 naive adult listeners on each. Each procedure used one of two adaptive methods (staircase or maximum-likelihood estimation, each targeting the 79% correct point on the psychometric function) and two response paradigms (3-interval, 2-alternative forced-choice AXB or 3-interval; 3-alternative forced-choice oddball). All procedures yielded statistically equivalent threshold estimates in both backward masking and frequency discrimination, with a trend to lower thresholds for oddball procedures in frequency discrimination. Oddball procedures were both more efficient and more reliable (test-retest) in backward masking, but all four procedures were equally efficient and reliable in frequency discrimination. Fitted psychometric functions yielded similar thresholds to averaging over reversals in staircase procedures. Learning was observed across threshold-assessment blocks and experimental sessions. In four additional groups, each of ten listeners, trained on the different procedures, no differences in performance improvement or rate of learning were observed, suggesting that learning is independent of procedure.     

Stages of homogeneous nucleation in solid isotopic helium mixtures

We have made pressure and NMR measurements during the evolution of phase separation in solid helium isotopic mixtures. Our observations indicate clearly all three stages of the homogeneous nucleation-growth process: (1) creation of nucleation sites; (2) growth of the new-phase component at these nucleation sites; and (3) coarsening: the dissolution of subcritical droplets with the consequent further late-stage growth of the supercritical droplets. The time exponent for the coarsening, a=1/3, is consistent with the conserved order parameter Lifshitz-Slezov evaporation-condensation mechanism.     

Perception of multiple electrode stimulus patterns: implications for design of an electrotactile speech processor

Identification of multiple-electrode stimulus patterns was evaluated in nine adult subjects, to assess the feasibility of providing additional speech information through the tactual display of an electrotactile speech processor. Absolute identification scores decreased from 97.8% for single electrodes, to 61.9% for electrode pairs, and, to 31.8% for electrode triplets. Although input information increased with paired-and triple-electrode stimuli, information transmission scores were not significantly increased for either electrode pairs (2.99 bits) or triplets (2.84 bits) as compared with single electrodes (2.84 bits). These results suggest that speech coding strategies using stimulus patterns of electrode pairs or triplets would provide little improvement beyond that found for the present single-electrode scheme. However, higher absolute identification scores (73.6%), and an increase in information transmission to 3.88 bits, were recorded for test stimuli containing all combinations of paired and single electrodes. Based on this finding, two stimulus sets using a restricted number of combinations of paired and single electrodes were evaluated. The two stimulus sets simulated the spatial patterns of paired and single electrodes arising from use of alternative speech coding schemes to increase consonant voicing information. Results for the two stimulus sets showed higher electrode identification scores (79.7% and 90.4%), as compared with paired-electrode stimuli. Although electrode identification score was not as high as for single electrodes, information transmission was increased to 3.31 bits for the VF2 stimulus set. Analysis of the responses also showed that scores for identification of simulated voicing information conveyed by the two stimulus sets were 99.4 and 90.4% correct.(ABSTRACT TRUNCATED AT 250 WORDS)     

Perception of amplitude envelope variations of pulsatile electrotactile stimuli

Gross variations of the speech amplitude envelope, such as the duration of different segments and the gaps between them, carry information about prosody and some segmental features of vowels and consonants. The amplitude envelope is one parameter encoded by the Tickle Talker, an electrotactile speech processor for the hearing impaired which stimulates the digital nerve bundles with a pulsatile electric current. Psychophysical experiments measuring the duration discrimination and identification, gap detection, and integration times for pulsatile electrical stimulation are described and compared with similar auditory measures for normal and impaired hearing and electrical stimulation via a cochlear implant. The tactile duration limen of 15% for a 300-ms standard was similar to auditory measures. Tactile gap detection thresholds of 9 to 20 ms were larger than for normal-hearing but shorter than for some hearing-impaired listeners and cochlear implant users. The electrotactile integration time of about 250 ms was shorter than previously measured tactile values but longer than auditory integration times. The results indicate that the gross amplitude envelope variations should be conveyed well by the Tickle Talker. Short bursts of low amplitude are the features most likely to be poorly perceived.     

Apparent giant conductivity peaks in an anisotropic medium: TTF-TCNQ

Measurements are presented of electrical potential values on single crystals of TTF-TCNQ which show an extraordinary apparent conductivity maximum near 70 K. The observed voltages in these anisotropic crystals are shown to be unusually sensitive to the points at which electrical contact is made. Our anomalous apparent conductivities can be understood in terms of the strong temperature dependence of the electrical anisotropy which is found, through measurements on several samples, to peak near 70 K.     

Measurement of differential cross sections for elastic K+p scattering in the momentum range 0.7 to 1.9 GeV/c

Differential cross sections for elastic K⁺p scattering have been measured at nineteen momenta between 0.7 and 1.9 GeV/c. The data represent between 10 thousand and 20 thousand elastic events at each momentum and cover a wide range of scattering angles ($\text{?0.98 ?}\text{cos}\text{θ}{}^1\text{? 0.95}$). A computer controlled system of scintillation counters and acoustic spark chambers was used to detect the elastic events. Various internal consistency checks indicate that the absolute normalization of the data is accurate to within 2–3%. The cross sections show a smooth transition from an isotropic angular distribution to a dominant forward peak over the range covered by the experiment. Phase-shift analyses including these results show little evidence for a direct-channel resonance, and fitting the results by t- and u-channel exchange processes alone gives a good fit.     

Direct observation of surface diffusion and atomic interactions on metal surfaces

The unique attributes of the field ion microscope permit the direct observation of surface diffusion of single atoms and simple atomic clusters on perfect crystal planes. A brief review of the principles and techniques of such studies is presented along with a collection of much of the existing experimental data. Emphasis is placed on more recent work such as the diffusion of adatoms under the influence of a driving force, the kinetics of cluster formation and dissociation, and how the interatomic force between two atoms on a surface is related to the diffusion parameters and the pair distribution function.     

SO3 symmetry breaking mechanism for orientation and spatial frequency tuning in the visual cortex

A dynamical model of orientation and spatial frequency tuning in a cortical hypercolumn is presented. The network topology is taken to be a sphere whose poles correspond to orientation pinwheels associated with high and low spatial frequency domains, respectively. Recurrent interactions within the sphere generate a tuned response via an SO3 symmetry breaking mechanism.     

Ultrasound tunneling through 3D phononic crystals

We report the study of ultrasound tunneling in 3D phononic crystals, consisting of fcc arrays of close-packed tungsten carbide beads in water. The transmission coefficient, phase velocity, and group velocity were measured along the [111] direction, allowing us to systematically investigate the tunneling of ultrasound at frequencies in the lowest band gap. Our experimental data are interpreted using multiple scattering theory, which provides a good explanation of our results. The effect of absorption and the difference between the tunneling of classical waves and quantum waves are discussed.