全文获取类型
收费全文 | 392篇 |
免费 | 8篇 |
国内免费 | 1篇 |
专业分类
化学 | 265篇 |
晶体学 | 10篇 |
力学 | 18篇 |
数学 | 80篇 |
物理学 | 28篇 |
出版年
2022年 | 3篇 |
2021年 | 6篇 |
2017年 | 3篇 |
2016年 | 8篇 |
2015年 | 8篇 |
2014年 | 5篇 |
2013年 | 21篇 |
2012年 | 10篇 |
2011年 | 19篇 |
2010年 | 11篇 |
2009年 | 15篇 |
2008年 | 17篇 |
2007年 | 23篇 |
2006年 | 13篇 |
2005年 | 12篇 |
2004年 | 10篇 |
2003年 | 10篇 |
2002年 | 14篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 8篇 |
1998年 | 3篇 |
1997年 | 8篇 |
1996年 | 11篇 |
1995年 | 9篇 |
1994年 | 9篇 |
1993年 | 9篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 9篇 |
1989年 | 12篇 |
1988年 | 8篇 |
1987年 | 5篇 |
1986年 | 5篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1982年 | 3篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1970年 | 3篇 |
1969年 | 2篇 |
1967年 | 3篇 |
1948年 | 2篇 |
1918年 | 2篇 |
1910年 | 2篇 |
1887年 | 2篇 |
1884年 | 4篇 |
排序方式: 共有401条查询结果,搜索用时 656 毫秒
31.
Paolo Domiano Amos Musatti Mario Nardelli Corrado Pelizzi Giovanni Predieri 《Transition Metal Chemistry》1980,5(1):172-175
Summary The synthesis, i.r. spectrum and x-ray crystal structure of the title, complex are described, Crystals are monoclinic space groupP 21/n, witha = 19.901(7),b = 13.163(8),c = 7.273(6) A, = 90.58(5)° Z = 4, The structure was solved from diffractometer data by direct methods and refined by least-squares techniques toR = 0.053 for 923 independent reflections. The complex has a distortedmer-octahedral geometry [Mo-O = 1,70(1), 2.15(1), Mo-Cl = 2.340(7), 1.352(7), 2.280(7), Mo-N = 2.19(2) A], The starting ligand Hsip, which is in theE configuration when free and in a number of metal complexes where it is terdentate, assumes here theZ configuration and is hiclentate. 相似文献
32.
Rita Menicagli Corrado Malanga Luciano Lardicci Laura Tinucci 《Tetrahedron letters》1980,21(47):4525-4528
2-Ethoxy-5-alkyl-3,4-dihydro-2H-pyrans react with Albui3 and through a regioselective hydride addition provide substituted cyclobutylmethanols in very good yields. 相似文献
33.
Anna Laura Segre Fulvio Andruzzi Corrado Barone Massimo Paci Pier Luigi Magagnini 《Journal of Polymer Science.Polymer Physics》1985,23(12):2611-2621
The 13C NMR spectra of aromatic comblike polyesters obtained from 1,2-icosanediol and isomeric phthalic acids are reported and discussed. The analysis shows that the most informative spectral regions are those of the carbonyl and quaternary carbon resonances, whose peak multiplicities have been interpreted in terms of dyad and triad sequences. The results indicate that the extent of structural characterization possible for the polymers examined is dependent on the type of isomerism of the aromatic acid involved. 相似文献
34.
Xu W Dutta D Xiong F Anderson B Auberbach L Averett T Bertozzi W Black T Calarco J Cardman L Cates GD Chai ZW Chen JP Choi S Chudakov E Churchwell S Corrado GS Crawford C Dale D Deur A Djawotho P Filippone BW Finn JM Gao H Gilman R Glamazdin AV Glashausser C Glöckle W Golak J Gomez J Gorbenko VG Hansen JO Hersman FW Higinbotham DW Holmes R Howell CR Hughes E Humensky B Incerti S de Jager CW Jensen JS Jiang X Jones CE Jones M Kahl R Kamada H Kievsky A Kominis I Korsch W Kramer K Kumbartzki G 《Physical review letters》2000,85(14):2900-2904
We have measured the transverse asymmetry A(T') in 3He(e,e(')) quasielastic scattering in Hall A at Jefferson Laboratory with high precision for Q2 values from 0.1 to 0.6 (GeV/c)(2). The neutron magnetic form factor G(n)(M) was extracted based on Faddeev calculations for Q2 = 0.1 and 0.2 (GeV/c)(2) with an experimental uncertainty of less than 2%. 相似文献
35.
Salvatore Giuffrida Guglielmo G. Condorelli Lucia L. Costanzo Giorgio Ventimiglia Raffaella Lo Nigro Maria Favazza Enrico Votrico Corrado Bongiorno Ignazio L. Fragalà 《Journal of nanoparticle research》2007,9(4):611-619
Liquid Phase Photo-Deposition (LPPD) technique has been used to obtain both colloidal particles and thin films of metallic
and chloride nickel from solutions of only precursor Ni(acac)2 (acac=2,4-pentandionato). Metallic nickel was obtained from ethanol solutions by direct nickel(II) photoreduction at 254 nm
and by acetone sensitised reaction at 300 nm. In this latter process the rate was higher than in the first one. NiCl2 was formed from CCl4 solution by a solvent-initiated reaction. TEM analysis, performed on colloidal particles of nickel, showed that their dimensions
are in the range 2–4 nm. The films did not present carbon contamination and were characterized by AFM, XPS and GIXRD. Metallic
films consisted of particles of 20–40 nm that are the result of the aggregation of smaller crystallites (4–5 nm). Larger agglomerations
(around 200 nm) have been observed for NiCl2 films. 相似文献
36.
37.
38.
Minardi Giovannina Mura Emanuela Pistuddi Angelo M. Solinas Costantino Bacchi Alessia Pelizzi Corrado Pelizzi Giancarlo Chelucci Giorgio 《Transition Metal Chemistry》1999,24(4):481-485
Chelating properties of C2-symmetric chiral bipyridine ligands are discussed. In particular we report the syntheses of the cobalt(II), nickel(II), zinc(II) and copper(II) complexes of (4S,5S)-2,2-dimethyl-4,5-bis(2-pyridyl)-1,3-dioxolane. All compounds have been characterized by IR spectroscopy, and an X-ray diffraction analysis has been carried out on one of them: Co(L)(NO3)2. The ligand coordinates the cobalt atom by the two nitrogen donors N(1) and N(2). A seven-membered chelation ring is formed, presenting a remarkable non-crystallographic twofold pseudosymmetry around the axis connecting Co and the midpoint of the C(6)–C(7) bond. The metal also binds two monodentate nitrates, thus completing a distorted coordination tetrahedron. 相似文献
39.
40.
Corrado Tanasi 《Monatshefte für Mathematik》1986,101(4):327-336
Borelian sections for measured foliations have been defined. A sufficient condition for the existence of borelian sections in the measured foliations is given and it is also proved that the measure on the set of equivalence classes obtained via Whitehead's relation is a dense probability measure.
Lavoro eseguito con il contributo del Ministero Pubblica Instruzione per la ricerca scientifica. 相似文献
Lavoro eseguito con il contributo del Ministero Pubblica Instruzione per la ricerca scientifica. 相似文献