Orthorhombic and monoclinic TNT: a nitrogen -14 NQR study

α-Trinitrotoluene can coexist at ambient temperatures in either a monoclinic or an orthorhombic phase. Nitrogen-14 NQR spectra were obtained for each phase at 77 K using Fourier transform multiple-pulse NQR methods. For each spectrum twelve resonance lines were detected. These were further paired up as six corresponding ν_? and ν₊ sets by a simple level crossing method. The six NQR inequivalent sites were further uniquely matched to the six crystallographic sites described by J.R.C. Duke, by considering the effect of the large twist angles of the C-nitro groups about the CN bond axis on the nitrogen p- π orbital occupation. Results are also presented in the two similar compounds, s-Trinitrobenzene and Trinitro-m-Xylene.     

Early phase process scale-up challenges for fungal and filamentous bacterial cultures

Culture pelleting and morphology has a strong influence on process productivity and success for fungal and filamentous bacterial cultures. This impact is particularly evident with early phase secondary metabolite processes with limited process definition. A compilation of factors affecting filamentous or pelleting morphology described in the literature indicates potential leads for developing process-specific control methodologies. An evaluation of the factors mediating citric acid production is one example of an industrially important application of these techniques. For five model fungal and filamentous bacterial processes in an industrial fermentation pilot plant, process development strategies were developed and effectively implemented with the goal of achieving reasonable fermentation titers early in the process development cycle. Examples of approaches included the use of additives to minimize pelleting in inoculum shake flasks, the use of large-volume frozen bagged inoculum obtained from agitated seed fermentors, and variations in production medium composition and fermentor operating conditions. Results were evaluated with respect to productivity of desired secondary metabolites as well as process scalability. On-line measurements were utilized to indirectly evaluate the cultivation impact of changes in medium and process development. Key laboratory to pilot plant scale-up issues also were identified and often addressed in subsequent cultivations.     

Fast iterative methods for symmetric sinc-Galerkin systems

The symmetric sinc-Galerkin method developed by Lund, when appliedto the second-order self-adjoint boundary value problem, givesrise to a symmetric coefficient matrix has a special structureso that it can be advantageously used in solving the discretesystem. In this paper, we employ the preconditioned conjugategradient method with banded matrices as preconditioners. Weprove that the condition number of the preconditioned matrixis uniformly bounded by a constant independent of the size ofthe matrix. In particular, we show that the solution of an n-by-ndiscrete symmetric sinc-Galerkin system can be obtained in O(nlog n) operations. We also extend our method to the self-adjointelliptic partial differential equation. Numerical results aregiven to illustrate the effectiveness of our fast iterativesolvers.     

(e, 3e) Differential cross section of He (21 S) and He (23 S)

The angular distribution of the five-fold differential cross section for the electron impact double ionization of He (2¹ S) and He (2³ S) has been studied. The kinematical conditions for maxima/minima in the angular distribution for the two cases have been compared. The two-step process for the double ionization is found to contribute very little in the triplet case.     

Pharmakolologisch active Polymere 13. Mitt. Aufk?rung der Tumor-Affinit?t von Poly(sulfadiazinacrylamid)

Ohne Zusammenfassung     

Strong coupling of nonlinear electronic and biological oscillators: reaching the "amplitude death" regime

Interaction between an electronic and a biological circuit has been investigated for a pair of electrically connected nonlinear oscillators, with a spontaneously oscillating olivary neuron as the single-cell biological element. By varying the coupling strength between the oscillators, we observe a range of behaviors predicted by model calculations, including a reversible low-energy dissipation "amplitude death" where the oscillations in the coupled system cease entirely.     

Using fuzzy cognitive mapping techniques to model situation awareness for army infantry platoon leaders

This paper describes work on the development of an actionable model of situation awareness for Army infantry platoon leaders using fuzzy cognitive mapping techniques. Developing this model based on the formal representation of the platoon leader provided by the Goal-Directed Task Analysis (GDTA) methodology advances current cognitive models because it provides valuable insight on how to effectively support human cognition within the decision-making process. We describe the modeling design approach and discuss validating the model using the VBS2 simulation environment.     

Measurements of higher order flow harmonics in Au+Au collisions at √s(NN)=200 GeV

Flow coefficients ν(n) for n=2, 3, 4, characterizing the anisotropic collective flow in Au+Au collisions at √s(NN)=200 GeV, are measured relative to event planes Ψ(n), determined at large rapidity. We report ν(n) as a function of transverse momentum and collision centrality, and study the correlations among the event planes of different order n. The ν(n) are well described by hydrodynamic models which employ a Glauber Monte Carlo initial state geometry with fluctuations, providing additional constraining power on the interplay between initial conditions and the effects of viscosity as the system evolves. This new constraint can serve to improve the precision of the extracted shear viscosity to entropy density ratio η/s.