Carrier recombination dynamics in anatase TiO2 nanoparticles

We present an experimental study of the radiative recombination dynamics in size-controlled TiO₂ nanoparticles in the range 20–130 nm. Time-integrated photoluminescence spectra clearly show a dominance of self-trapped exciton (STE) emission, with main features not dependent on the nanoparticle size and on its environment. From picosecond time-resolved experiments as a function of the excitation density and the nanoparticle size we address the STE recombination dynamics as the result of two main processes related to the direct STE formation and to the indirect STE formation mediated by non-radiative surface states.     

Spatial and temporal plasma inhomogeneity effects on the luminescence of highly excited GaAs/AlGaAs multiple quantum well structures

Summary The effects on the luminescence lineshape of the spatial and temporal inhomogeneities of the electron-hole plasma generated by strong laser pulses in GaAs/AlGaAs multiple quantum well structures are experimentally investigated. It is found that inhomogeneities strongly affect the luminescence spectra and must be taken into account for a correct interpretation of the experimental data. The lineshape of the luminescence spectra is analysed using a statistical model that includes, in a simple way, the spatial and temporal inhomogeneities of the laser pulses used for excitation. A fair agreement is obtained with the experimental data; at the same time the values of the fit parameters turn out to be rather sensitive to the model assumed for describing the inhomogeneities. Therefore, caution has to be used when inferring plasma properties, such as the carrier density and temperature, from a lineshape analysis.

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Riassunto Si presenta, in questo lavoro, uno studio sperimentale degli effetti delle disomogeneità spaziali e temporali nei plasmi di elettroni e lacune generati da impulsi laser potenti in strutture a buche quantiche di GaAs/AlGaAs. Si trova che tali disomogeneità modificano fortemente gli spettri di fotoluminescenza e devono quindi essere considerate per una corretta interpretazione dei dati sperimentali. La forma di riga degli spettri di luminescenza viene analizzata mediante un modello statistico che include, in modo semplice, le disomogeneità spaziali e temporali degli impulsi laser usati per l’eccitazione. Si ottiene un accordo soddisfacente con i dati sperimentali e si trova che i valori dei parametri ottenuti dal fit dipendono in modo sensibile dal modello assunto per la descrizione delle disomogeneità. Grande cautela deve essere quindi usata nel dedurre le proprietà del plasma fotogenerato a partire da una analisi delle forme di riga.

     

Raman scattering by hot and thermal polaritons in crystal quartz

Summary Nonlinear mixing of IR and visible radiation,i.e. coherent Raman scattering by polaritons driven by a CO₂ laser, has been used to obtain the dispersion curve and its width inq-space of the polariton associated to theE-phonon at 1065 cm⁻¹ in crystal quartz. It is shown in this paper that a direct method to determine indipendently, with high precision, the refractive index and absorbance of a crystal can be obtained in this way. The results are compared with accurate data obtained from Raman scattering by polaritions in thermal equilibrium and very good agreement is found between the two measurements. It is finally shown that nonlinear-mixing techniques turn out to be completely consistent with the simple picture of scattering of light by hot polaritons. This work was supported by the Italian Consiglio Nazionale delle Ricerche del Ministero della Pubblica Istruzione.