Coherent Stokes and anti-Stokes Raman spectra of the ν1 (A1) and ν2 (E) bands of SF6 and UF6

Coherent Stokes and anti-Stokes Raman scattering are used to study the ν₁ and ν₂ spectral band profiles of UF₆ and SF₆. Most of the observed SF₆ “hot” bands are assigned, leading to evaluations of the anharmonicity constants X_ij: X₁₂ = ?(2.80 ± 0.30) cm^?1, X₁₄ = ?(1.00 ± 0.15) cm^?1, X₁₅ = ?(1.00 ± 0.15) cm^?1. For UF₆, a tentative assignment of the “hot” bands is made: X₁₂ = ?(1.80 ± 0.30) cm^?1, X₁₃ = ?(1.60 ± 0.30) cm^?1, X₁₄ = ?(0.20 ± 0.10) cm^?1, X₁₅ = ?(0.25 ± 0.10) cm^?1, and X₁₆ = ?(0.10 ± 0.05) cm^?1. Parameters such as the vibration-rotation coupling constants are determined. For SF₆: α = (7 ± 2) × 10^?5 cm^?1 for the ν₂ band and α = ?(1.02 ± 0.01) 10^?4 cm^?1 for the ν₁ band. The calculated spectral profiles of the coherent Stokes or anti-Stokes spectra, which are in good agreement with experimental results, give values for the resonant and nonresonant parts of the susceptibility in both molecules. They also show, in some cases, the influence of neighboring combination bands.     

Few-neutron removal from238U at relativistic energies

As part of a comprehensive study of uranium fragmentation at relativistic energies at the GSI projectile fragment separator, FRS, inclusive neutron-removal cross sections have been measured for severalxn channels at projectile energies of 600 and 950A MeV using targets of Al, Cu and Pb. The variation of the experimental cross sections with target nuclear charge is used to disentangle nuclear and electromagnetic contributions. The electromagnetic cross sections agree surprisingly well with a simple harmonic oscillator calculation of giant dipole resonances based on measured photonuclear cross sections and do not require an extra enhancement of the two-phonon giant dipole excitation as concluded from similar measurements with¹⁹⁷Au.     

Properties of electromagnetic transitions in C

Transitions to seven levels below 16 MeV excitation energy were studied by using low-energy scattering. For the T = 3/2 → 1/2, 15.11 MeV transition, which is of interest in connection with a possible isotensor electromagnetic interaction, the M1 and E2 radiative widths were measured with high precision. Electric monopole excitation of 1/2⁻ levels was found.     

Diffusion localisée de phosphore dans le silicium

Sans résumé     

Nuclear charge distribution of mass-separated isobars from thermal-neutron-induced fission of 235U

The nuclear charge distribution of fission products with mass numbers A = 90, 91, 94, 99, 100, 101 and 104 provided by the mass separator “Lohengrin” was measured. Adjacent elements in the group of the light fission products could be separated by their different energy loss in a carbon absorber. The Z-yields were found to be strongly dependent on the kinetic energy of the fission products. The widths of the nuclear charge distributions are very small, in general, and strongly dependent on A as well as on the kinetic energy. The influence of the neutron evaporation and odd-even effects are clearly detected. An asymmetric nuclear charge distribution was found for A = 104 indicating the suppression of fission fragments with Z = 43. The average nuclear charges of the fission products at their average kinetic energy are in good agreement with the results from measurements of the number of β-decays and K X-ray measurements. The average nuclear charge of the isobar A = 132 was measured at its average kinetic energy with a calibrated secondary electron detector to be Z = 51.14 ± 0.15 which is in very good agreement with the radiochemical results. Thus previous physical measurements indicating a large independent yield for the doubly magic nucleus ¹³²Sn could not be confirmed.     

Strukturaufklärung organischer Verbindungen durch computerunterstützten Vergleich spektraler Daten

A system for computer-aided identification of organic compounds by means of spectroscopic data is described. The binary coded spectral data of the unknown compounds are compared with a reference file containing NMR., IR. and Mass Spectra. A highly flexible software automatically selects the appropriate search strategy and directs the updating of the collection, thereby ensuring continuous adaption to varying needs.     

Determination of H o , G o , and S o of the interaction of ions with carrier antibiotics by computerized microcalorimetry

ΔH°, ΔG°, and ΔS° — and thereby the equilibrium constant of the interaction of carrier antibiotics with ions — are determined using a microcalorimeter on-line with a dedicated computer. Thermodynamic data of the interaction of monensin, macrotetrolides and valinomycin with sodium and potassium ions in methanol at 25°C are given.     

Investigation of the fusion of heavy nearly symmetric systems

Excitation functions in the vicinity of the Coulomb barrier have been measured for the formation of evaporation residues in¹⁰⁰Mo-induced fusion reactions with^{90, 92, 96}Zr,^{92, 96, 98, 100}Mo,¹⁰⁴Ru and¹¹⁰Pd as well as for the system⁹⁶Zr+⁹⁶Zr. From these data the fusion probability in central collisions was extracted covering a range of 4 orders of magnitude. At the fusion barriers expected from systematics we find that the fusion probability is suppressed by one to three orders of magnitude. It is rising very gradually at higher energies and reaches for the heaviest systems saturation only at energies as high as 30 MeV above the barrier. The observed hindrance of the fusion process increases roughly with the growing Coulomb repulsion between the collision partners, but there is also a distinct influence of their individual nuclear structure. The data are compared to the extra-push model, the surface-friction model and the diabatic fusion model. A parameterisation of the extra-push energy and its fluctuation in terms of a macroscopic quantity like the Coulomb repulsion combined with a microscopic quantity characterizing the nuclear structure is proposed. As a byproduct of this work a new alpha emitter,¹⁹¹Po, could be identified. Its half-life is (15.5 _–2.5 ⁺⁶ ) ms, the alpha energy is (7314±20) keV.