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排序方式: 共有418条查询结果,搜索用时 312 毫秒
131.
Sebastian Dochow Claudia Beleites Thomas Henkel Günter Mayer Jens Albert Joachim Clement Christoph Krafft Jürgen Popp 《Analytical and bioanalytical chemistry》2013,405(8):2743-2746
Three important technical innovations are reported here towards Raman-activated cell sorting. Firstly, a microfluidic chip made of quartz is introduced which integrates injection of single cells, trapping by laser fibres and sorting of cells. Secondly, a chip holder was designed to provide simple, accurate and stable adjustment of chips, microfluidic connections and the trapping laser fibres. The new setup enables to the collection of Raman spectra of single cells at 785 nm excitation with 10 s exposure time. Lastly, a new type of modelling the various background contributions is described, improving Raman-based cell identification by the classification algorithm linear discriminant analysis. Mean sensitivity and specificity determined by iterated 10-fold cross validation were 96 and 99 %, respectively, for the distinction of leucocytes extracted from blood, breast cancer cells BT-20 and MCF-7, and leukaemia cells OCI-AML3. 相似文献
132.
A synthetic route to p-amino-N,N′-dihydroxybenzamidine is established using a TBDMS protecting group strategy starting with p-nitrobenzhydroxamic acid chloride, which is transformed to O,O′-bis(tert-butyldimethylsilyl)-N,N′-dihydroxybenzamidine. Reduction with sodium dithionite occurs without degradation of the dihydroxyamidine functional group. Deprotection with ammonium fluoride is fast and efficient. This is important because no other possibility to synthesize this derivative has been found up to now. Furthermore, TBDMS protecting group strategy is proved to be adaptable to other substituted N,N′-dihydroxybenzamidines. 相似文献
133.
In therapeutic ultrasound, the presence of shock waves can be significant due to the use of high intensity beams, as well as due to shock formation during inertial cavitation. Although modeling of such strongly nonlinear waves can be carried out using spectral methods, such calculations are typically considered impractical, since accurate calculations often require hundreds or even thousands of harmonics to be considered, leading to prohibitive computational times. Instead, time-domain algorithms which generally utilize Godunov-type finite-difference schemes are commonly used. Although these time domain methods can accurately model steep shock wave fronts, unlike spectral methods they are inherently unsuitable for modeling realistic tissue dispersion relations. Motivated by the need for a more general model, the use of Gegenbauer reconstructions as a postprocess tool to resolve the band-limitations of the spectral methods are investigated. The present work focuses on eliminating the Gibbs phenomenon when representing a steep wave front using a limited number of harmonics. Both plane wave and axisymmetric 2D transducer problems will be presented to characterize the proposed method. 相似文献
134.
Lee Y Clement C Hellerstedt J Kinney J Kinnischtzke L Leng X Snyder SD Goldman AM 《Physical review letters》2011,106(13):136809
Electric double layer transistor configurations have been employed to electrostatically dope single crystals of insulating SrTiO(3). Here we report on the results of such doping over broad ranges of temperature and carrier concentration employing an ionic liquid as the gate dielectric. The surprising results are, with increasing carrier concentration, an apparent carrier-density dependent conductor-insulator transition, a regime of the anomalous Hall effect, suggesting magnetic ordering, and finally the appearance of superconductivity. The possible appearance of magnetic order near the boundary between the insulating and superconducting regimes is reminiscent of effects associated with quantum critical behavior in some complex compounds. 相似文献
135.
We study the internal dynamical processes taking place in a granular packing below yield stress. At all packing fractions and down to vanishingly low applied shear, a logarithmic creep is observed. The experiments are analyzed using a viscoelastic model which introduces an internal, time-dependent, fluidity variable. For all experiments, the creep dynamics can be rescaled onto a unique curve which displays jamming at the random-close-packing limit. At each packing fraction, we measure a stress corresponding to the onset of internal granular reorganization and a slowing down of the creep dynamics before the final yield. 相似文献
136.
Platinum(II) Olefin Hydroarylation Catalysts: Tuning Selectivity for the anti‐Markovnikov Product 下载免费PDF全文
Marie L. Clement Kyle A. Grice Avery T. Luedtke Werner Kaminsky Prof. Karen I. Goldberg 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(52):17287-17291
PtII complexes containing unsymmetrical (pyridyl)pyrrolide ligands are shown to catalyze the hydroarylation of unactivated alkenes with selectivity for the anti‐Markovnikov product. Substitution on the pyrrolide portion of the ligand allows effective tuning of the selectivity to anti‐Markovnikov alkylarene products, whereas substitution on the pyridyl portion can promote competitive alkenylarene production. 相似文献
137.
The purpose of this paper is to calculate shadow prices of hospital services and compare them to the reimbursement rates those hospitals receive. These shadow prices are calculated by estimating a multiple-output distance function and applying a dual Shephard's lemma, a technique suggested by Färe and Grosskopf [8]. In contrast to cost functions, distance functions require no price data and do not presume cost minimization. We apply this technique to a sample of California hospitals operating in 1986. We find that hospitals engaged in selective contracting for Medi-Cal patients exhibit closer agreement between relative shadow prices and relative reimbursement rates (Medi-Cal relative to private patients) than noncontracting hospitals.Contact author. 相似文献
138.
139.
A. C. G. Clement 《Archiv der Mathematik》1991,57(6):531-538
140.
S. Abd El-Samad R. Bilger K. -Th. Brinkmann H. Clement M. Dietrich E. Doroshkevich S. Dshemuchadse A. Erhardt W. Eyrich A. Filippi H. Freiesleben M. Fritsch R. Geyer A. Gillitzer J. Hauffe D. Hesselbarth R. Jaekel B. Jakob L. Karsch K. Kilian H. Koch J. Kress E. Kuhlmann S. Marcello S. Marwinski R. Meier K. Möller H. P. Morsch L. Naumann E. Roderburg P. Schönmeier M. Schulte-Wissermann W. Schroeder M. Steinke F. Stinzing G. Y. Sun J. Wächter G. J. Wagner M. Wagner U. Weidlich A. Wilms S. Wirth G. Zhang P. Zupranski 《The European Physical Journal A - Hadrons and Nuclei》2006,30(2):443-453
The single-pion production reactions pp → dπ+, pp → npπ+ and pp → ppπ0 were measured at a beam momentum of 0.95GeV/c ( T
p ≈ 400MeV) using the short version of the COSY-TOF spectrometer. The implementation of a central calorimeter provided particle
identification, energy determination and neutron detection in addition to time-of-flight and angle measurements. Thus, all
pion production channels were recorded with 1-4 overconstraints. The total and differential cross-sections obtained are compared
to previous data and theoretical calculations. Main emphasis is put on the discussion of the ppπ0 channel, where we obtain angular distributions different from previous experimental results, however, partly in good agreement
with recent phenomenological and theoretical predictions. In particular, we observe very large anisotropies for the π0 angular distributions in the kinematical region of small relative proton momenta revealing there a dominance of proton spinflip
transitions associated with π0
s and d partial waves and emphasizing the important role of π0
d-waves. 相似文献