Synthesis and optical and electrochemical properties of copolymers consisting of 9,9‐dihexylfluorene and aromatic triazole chromophores

Aromatic triazole chromophores were incorporated into polyfluorene in an attempt to increase electron affinity, to promote emission efficiency, and to diminish excimer formation. Poly(9,9‐dihexylfluorene) ( P1 ) and new copolymers with aromatic triazoles ( P2 – P4 ) were prepared by Suzuki coupling polymerization. In P2 , the aromatic triazole (3.8 mol %) was attached exclusively as terminal groups, whereas P3 and P4 were main‐chain copolymers containing 3.9 and 10.3 mol % aromatic triazole chromophores, respectively. The copolymers were soluble in common organic solvents and showed high decomposition temperatures (437–458 °C). The twisted structure between the triazole and fluorene increased the emission efficiency and effectively prevented excimer formation in P2 – P4 . After the introduction of the triazole units, the absorption spectra showed a blueshift (from 388 to 381 nm in chloroform) due to confined conjugation, but the photoluminescence spectra remained almost the same (417–418 nm); this was attributed to oligofluorene segments. No emission of triazole fluorophores was observed because of efficient energy transfer from the triazole to oligofluorene segments. However, incomplete energy transfer was observed in CH₃COOH. The optical stability upon thermal annealing was also improved by the incorporation of aromatic triazole segments. From cyclic voltammetry results, P2 – P4 , containing triazole groups, showed greater electron affinity (lowest unoccupied molecular orbital level = ?2.67 to ?2.71 eV) than P1 (?2.52 eV). Electroluminescence devices of P1 – P4 all exhibited excimer emissions (483–521 nm), which could also be diminished by the introduction of aromatic triazole chromophores. © 2006Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 136–146, 2007     

A real options approach for entering the Internet securities trading businesses with start‐up time

This paper uses a real options approach to establish a new evaluation model under uncertainty of both the volume of Internet securities transactions and the total transaction volume of a securities firm. The proposed approach can assist securities firms in evaluating the optimal thresholds for entering the Internet securities trading business and withdrawing from the conventional securities trading business. This paper assumes that the annual number of Internet securities transactions and the total annual number of securities transactions both follow a geometric Brownian motion. Besides, this model considers a start‐up time to complete the entry project's procedure. Accordingly, a decision model based on the real options approach is introduced, and the closed form solutions for the optimal threshold values of the entry or withdrawal models are determined. The conclusions provide some valuable references to help strategic managers of securities firms in making decisions on entering the Internet securities trading business or withdrawing from the conventional trading business. Copyright © 2003 John Wiley & Sons, Ltd.     

Ferromagnetic films with magnon bandgap periodic structures: Magnon crystals

A new type of photonic crystals is proposed. The new crystals have a forbidden gap in the microwave spectrum of magnetostatic spin waves, and, by analogy with photonic crystals, they are called magnon crystals. Specimens of such crystals were fabricated on the basis of yttrium iron garnet films. The surfaces of ferromagnetic films containing two-dimensional etched hole structures were studied by atomic force and magnetic force mag-netometry. The propagation of spin waves through the magnon crystals was investigated.     

Stochastic Dynamic Programming Formulation for a Wastewater Treatment Decision-Making Framework

In this paper, a decision-making framework (DMF) based on stochastic dynamic programming (SDP) is presented for a wastewater treatment system, consisting of a liquid treatment line with eleven levels and a solid treatment line with six levels (Chen and Beck, 1997). A continuous-state SDP solution approach based on the OA/MARS method (Chen, Ruppert, and Shoemaker, 1999) is employed, which provides an efficient method for representing a wide range of possible influent conditions. The DMF is used to evaluate current and emerging technologies for the multi-level liquid and solid lines of the wastewater treatment system. At each level, one technology unit is selected out of a set of options which includes the empty unit. The DMF provides a comparison on possible technologies for screening which types of technologies may best be further developed in order for an urban wastewater infrastructure to be judged progressively more sustainable. The results indicate that one or a pair of technologies are dominant in each level. The cheap, lower-technology unit processes receive a mixed review. Some of them are selected as the most promising technology units while the others are not considered as good candidates.     

Error analysis of the L2 least‐squares finite element method for incompressible inviscid rotational flows

In this article we analyze the L² least‐squares finite element approximations to the incompressible inviscid rotational flow problem, which is recast into the velocity‐vorticity‐pressure formulation. The least‐squares functional is defined in terms of the sum of the squared L² norms of the residual equations over a suitable product function space. We first derive a coercivity type a priori estimate for the first‐order system problem that will play the crucial role in the error analysis. We then show that the method exhibits an optimal rate of convergence in the H¹ norm for velocity and pressure and a suboptimal rate of convergence in the L² norm for vorticity. A numerical example in two dimensions is presented, which confirms the theoretical error estimates. © 2004 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2004     

Chemisorptive bonding of carbon monoxide on nickel (001): Formulation and application of a new pseudofunctional electron muffin tin approach

The nature of chemisorptive bonding of carbon monoxide on single-crystal transition metal surfaces, particularly Ni(001) and Fe(110) is reviewed in terms of valence-level shifts in photoemission, characteristic stretching frequencies, two-dimensional electron-band structure and adsorbate-site location. The experimentally determined data for many of these parameters are critically compared to a first-principle, total-energy slab-calculation approach developed by the writers called the pseudo-functional (PSF) method and conclusions made on the microscopic parameters for CO chemisorption and chemical-bond formation.Supported primarily by the National Science Foundation and the E.I. duPont de Nemours Company     

The method of fundamental solutions with eigenfunction expansion method for nonhomogeneous diffusion equation

In this article we describe a numerical method to solve a nonhomogeneous diffusion equation with arbitrary geometry by combining the method of fundamental solutions (MFS), the method of particular solutions (MPS), and the eigenfunction expansion method (EEM). This forms a meshless numerical scheme of the MFS‐MPS‐EEM model to solve nonhomogeneous diffusion equations with time‐independent source terms and boundary conditions for any time and any shape. Nonhomogeneous diffusion equation with complex domain can be separated into a Poisson equation and a homogeneous diffusion equation using this model. The Poisson equation is solved by the MFS‐MPS model, in which the compactly supported radial basis functions are adopted for the MPS. On the other hand, utilizing the EEM the diffusion equation is first translated to a Helmholtz equation, which is then solved by the MFS together with the technique of the singular value decomposition (SVD). Since the present meshless method does not need mesh generation, nodal connectivity, or numerical integration, the computational effort and memory storage required are minimal as compared with other numerical schemes. Test results for two 2D diffusion problems show good comparability with the analytical solutions. The proposed algorithm is then extended to solve a problem with irregular domain and the results compare very well with solutions of a finite element scheme. Therefore, the present scheme has been proved to be very promising as a meshfree numerical method to solve nonhomogeneous diffusion equations with time‐independent source terms of any time frame, and for any arbitrary geometry. © 2006 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2006     

Cheating in Visual Cryptography

A secret sharing scheme allows a secret to be shared among a set of participants, P, such that only authorized subsets of P can recover the secret, but any unauthorized subset cannot recover the secret. In 1995, Naor and Shamir proposed a variant of secret sharing, called visual cryptography, where the shares given to participants are xeroxed onto transparencies. If X is an authorized subset of P, then the participants in X can visually recover the secret image by stacking their transparencies together without performing any computation. In this paper, we address the issue of cheating by dishonest participants, called cheaters, in visual cryptography. The experimental results demonstrate that cheating is possible when the cheaters form a coalition in order to deceive honest participants. We also propose two simple cheating prevention visual cryptographic schemes.     

A bidirectional hybrid DWDM-PON employing optical injection locking technique and data comparators

A bidirectional hybrid dense-wavelength-division-multiplexing (DWDM)-passive optical network (PON) employing optical injection locking technique on vertical-cavity surface-emitting lasers (VCSELs) and data comparator, as well as optical injection locking technique on distributed feedback laser diodes (DFB LDs) and amplitude/phase compensator is proposed and demonstrated. Improved performances of bit error rate (BER) and carrier-to-noise ratio/composite second order/composite triple beat (CNR/CSO/CTB) were observed in our proposed bidirectional hybrid DWDM-PON. Bidirectional transmission in bidirectional hybrid DWDM-PON architecture is a very attractive option, the capacity of the optical network can be expanded relatively easily by bidirectional transmission technology.