首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   53023篇
  免费   8850篇
  国内免费   5693篇
化学   37477篇
晶体学   643篇
力学   3096篇
综合类   330篇
数学   5967篇
物理学   20053篇
  2024年   182篇
  2023年   1122篇
  2022年   2082篇
  2021年   2158篇
  2020年   2273篇
  2019年   2147篇
  2018年   1833篇
  2017年   1780篇
  2016年   2621篇
  2015年   2647篇
  2014年   3109篇
  2013年   3965篇
  2012年   4858篇
  2011年   4796篇
  2010年   3334篇
  2009年   3132篇
  2008年   3349篇
  2007年   2963篇
  2006年   2656篇
  2005年   2285篇
  2004年   1746篇
  2003年   1398篇
  2002年   1282篇
  2001年   1022篇
  2000年   900篇
  1999年   1050篇
  1998年   863篇
  1997年   810篇
  1996年   798篇
  1995年   729篇
  1994年   613篇
  1993年   520篇
  1992年   432篇
  1991年   395篇
  1990年   332篇
  1989年   241篇
  1988年   178篇
  1987年   163篇
  1986年   159篇
  1985年   139篇
  1984年   87篇
  1983年   93篇
  1982年   55篇
  1981年   39篇
  1980年   29篇
  1979年   18篇
  1977年   18篇
  1976年   20篇
  1975年   21篇
  1972年   19篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
In this paper, both low order and high order extensions of the Iyengar type inequality are obtained. Such extensions are the best possible in the same sense as that of the Iyengar inequality. hzrthermore, the Chebyshev central algorithms of integrals for some function classes and some related problems are also considered and investigated.  相似文献   
52.
本文利用Banach压缩映射原理,讨论了中立型时滞脉冲微分方程正解的存在性。  相似文献   
53.
证明了当超越亚纯函数的级小于1时,其Norel例外值最多只有一个.由于存在任何级的整函数,因此一个例外值总可达到,故所得结果不能再改进。  相似文献   
54.
The synthesized 1-aryliminomethylenylnaphthalen-2-ol derivatives reacted with nickel chloride to form bis(1-aryliminomethylenylnaphthalen-2-oxy)nickel complexes. All resultant compounds were structurally characterized by elemental analyses, IR and H NMR, and the structures of the formed complexes were elucidated by X-ray crystal structure analysis. The complexes show high catalytic activities for the vinyl polymerization of norbornene in the presence of methylaluminoxane. The catalytic activity variations have been followed by gas chromatography through monitoring the conversion of norbornene.  相似文献   
55.
学生学习知识,一般来说,是从生动的具体的直观开始的,生动的直观能使学生获得关于事物生动而具体的感性认识。但是,感性认识并没有揭露事物的本质,人们对事物本质的认识要通过一系列的抽象来完成。  相似文献   
56.
Rhythmic growth of ring‐banded spherulites in blends of liquid crystalline methoxy‐poly(aryl ether ketone) (M‐PAEK) and poly(aryl ether ether ketone) (PEEK) has been investigated by means of differential scanning calorimetry (DSC), polarized light microscopy (PLM), and scanning electron microscopy (SEM) techniques. The measurements reveal that the formation of the rhythmically grown ring‐banded spherulites in the M‐PAEK/PEEK blends is strongly dependent on the blend composition. In the M‐PAEK‐rich blends, upon cooling, an unusual ring‐banded spherulite is formed, which is ascribed to structural discontinuity caused by a rhythmic radial growth. For the 50:50 M‐PAEK/PEEK blend, ring‐banded spherulites and individual PEEK spherulites coexist in the system. In the blends with PEEK as the predominant component, M‐PAEK is rejected into the boundary of PEEK spherulites. The cooling rate and crystallization temperature have great effect on the phase behavior, especially the ring‐banded spherulite formation in the blends. In addition, the effects of M‐PAEK phase transition rate and phase separation rate on banded spherulite formation is discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3011–3024, 2007  相似文献   
57.
To investigate the position and amount of the CF3 group affecting the coloration of polyimides (PIs), we prepared 2,2‐bis[4‐(4‐amino‐2‐trifluoromethylphenoxy)phenyl]hexafluoropropane ( 2 ) with four CF3 groups with 2‐chloro‐5‐nitrobenzotrifluoride and 2,2‐bis(4‐hydroxyphenol)hexafluoropropane. A series of soluble and light‐colored fluorinated PIs ( 5 ) were synthesized from 2 and various aromatic dianhydrides ( 3a – 3f ). 5a – 5f had inherent viscosities ranging from 0.80 to 1.19 dL/g and were soluble in amide polar solvents and even in less polar solvents. The glass‐transition temperatures of 5 were 221–265 °C, and the 10% weight‐loss temperatures were above 493 °C. Their films had cutoff wavelengths between 343 and 390 nm, b* values (a yellowness index) ranging from 5 to 41, dielectric constants of 2.68–3.01 (1 MHz), and moisture absorptions of 0.03–0.29 wt %. In a comparison of the PI series 6 – 8 based on 2,2‐bis[4‐(4‐aminophenoxy)phenyl]hexafluoropropane, 2,2‐bis[4‐(4‐amino‐2‐trifluoromethylphenoxy)phenyl]propane, and 2,2‐bis[4‐(4‐aminophenoxy)phenyl]propane, we found that the CF3 group close to the imide group was more effective in lowering the color; this means that CF3 of 5 , 7 , and 8f was more effective than that of 6c . The color intensity of the four PI series was lowered in the following order: 5 > 7 > 6 > 8 . The PI 5f , synthesized from diamine 2 and 4,4′‐hexafluoroisopropylidenediphthalic anhydride, had six CF3 groups in a repeated segment, so it exhibited the lightest color among the four series. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 922–938, 2003  相似文献   
58.
陆路德  汪信 《应用化学》1989,6(1):63-65
双金属催化剂是一类重要的多相催化剂。其中d电子在催化活性方面起着重要的作用.本文在Co_3[Fe(CN)_6]_2的工作基础上,进一步研究了该配合物在硅胶、氧化铝、以及氧化镁上的热性质,同时考察了CN~-在Co-Fe体系双端基配位的活化加氢,探讨了载体的影响.  相似文献   
59.
Based on a dipole-dipole interaction model, we discuss the levitation force and related vibration problems to understand the effects of flux pinning in type-II superconductors, and the applications of levitation in superconducting systems.  相似文献   
60.
A low cost, coolerless 980nm diode pumped, gain flattened L band EDFA with fast transient control, high pump efficiency and gain clamping effect was realized by using FBGs as C band seed generators.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号