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951.
Lee KI Joo SJ Lee JH Rhie K Kim TS Lee WY Shin KH Lee BC LeClair P Lee JS Park JH 《Physical review letters》2007,98(10):107202
Tunneling magnetoresistance was found to be suppressed with decreasing temperature for magnetic tunnel junctions (MTJs) oxidized under high plasma power. A strong temperature dependence of the junction resistance was observed, along with zero-bias anomalies of dynamic resistance at low temperatures. Resistance shows a logarithmic dependence on temperature, and resistance versus temperature exhibits a scaling behavior. Our experimental data can be explained in a consistent way by the Kondo effect in the MTJs with the Kondo temperature TK=20-30 K. 相似文献
952.
Omar Alkhazragi Hang Lu Wenbo Yan Nawal Almaymoni Tae-Yong Park Yue Wang Tien Khee Ng Boon S. Ooi 《Annalen der Physik》2023,535(9):2300289
Random number generation (RNG) is needed for a myriad of applications ranging from secure communication encryption to numerical simulations to sports and games. However, generating truly random numbers can be elusive. Pseudorandom bit generation using computer algorithms provides a high random bit generation rate. Nevertheless, the reliance on predefined algorithms makes it deterministic and predictable once initial conditions are known. Relying on physical phenomena (such as measuring electrical noise or even rolling dice) can achieve a less predictable sequence of bits. Furthermore, if the physical phenomena originate from quantum effects, they can be truly random and completely unpredictable due to quantum indeterminacy. Traditionally, physical RNG is significantly slower than pseudorandom techniques. To meet the demand for high-speed RNG with perfect unpredictability, semiconductor light sources are adopted as parts of the sources of randomness, i.e., entropy sources, in quantum RNG (QRNG) systems. The high speed of their noise, the high efficiency, and the small scale of these devices make them ideal for chip-scale QRNG. Here, the applications and recent advances of QRNG are reviewed using semiconductor emitters. Finally, the performance of these emitters is compared and discuss their potential in future technologies. 相似文献
953.
Oscillatory flows of a choked underexpanded supersonic impinging jet issuing from a convergent nozzle have been computed using
the axisymmetric unsteady Navier--Stokes system. This paper focuses on the oscillatory flow features associated with the variation
of the nozzle-to-plate distance and nozzle pressure ratio. Frequencies of the surface pressure oscillation and flow structural
changes from computational results have been analyzed. Staging behavior of the oscillation frequency has been observed for
both cases of nozzle-to-plate distance variation and pressure ratio variation. However, the staging behavior for each case
exhibits different features. These two distinct staging behaviors of the oscillation frequency are found to correlate well
if the frequency and the distance are normalized by the length of the shock cell. It is further found that the staging behavior
is strongly correlated with the change of the pressure wave pattern in the jet shear layer, but not with the shock cell structure.
Communicated by K. Takayama
PACS 02.60.Cb; 47.40.−x; 47.40.Nm; 47.35.+I; 47.15.−x 相似文献
954.
The onset of convective instability in an initially quiescent, stably stratified fluid layer between two horizontal plates
is analyzed with linear theory. The bottom boundary is heated suddenly from below, subjected to a step change in surface temperature.
The critical time t
c to mark the onset of Rayleigh-Bénard convection is predicted by propagation theory. This theory uses the length scaled by
, where α denotes thermal diffusivity. Under the normal mode analysis the dimensionless disturbance equations are obtained
as a function of τ(=αt/d
2) and ζ(=Z/), where d is the fluid layer depth and Z is the vertical distance. The resulting equations are transformed to self-similar ones by using scaling and finally fixing
τ as τc under the frame of coordinates τ and ζ. For a given γ, Pr and τc, the minimum value of Ra is obtained from the marginal stability curve. Here γ denotes the temperature ratio to represent the degree of stabilizing
effect, Pr is the Prandtl number and Ra is the Rayleigh number. With γ=0, the minimum Ra value approaches the well-known value of 1708 as τc increases. However, it is inversely proportional to τc
3/2 as τc decreases. With increasing γ, the system becomes more stable. It is interesting that in the present system, propagation theory
produces the stability criteria to bound the available experimental data over the whole domain of time.
Received 5 November 2001 and accepted 29 March 2002 Published online: 2 October 2002
RID="*"
ID="*" This work has been supported by both SK Chemicals Co. Ltd. and LG Chemical Ltd., Seoul under the Brain Korea 21 Project
of the Ministry of Education.
Communicated by H.J.S. Fernando 相似文献
955.
Ki Byung Sunwoo Seung Joon Park Seong Jae Lee Kyung Hyun Ahn Seung Jong Lee 《Rheologica Acta》2002,41(1-2):144-153
Three-dimensional numerical simulation of viscoelastic coextrusion process has been performed and numerical results were
compared with the experimental data of Karagiannis et al. (1990). By varying the magnitude of the second normal stress difference
and its ratio of Fluid I and Fluid II, we were able to control the interface profile and the degree of encapsulation along
the downstream direction. By increasing the parameter α (αFluid I=αFluid II) from 0.1 to 0.4 in the Giesekus model and increasing the α ratio (αFluid IαFluid II) between Fluid I and Fluid II from 2.0 to 4.0 in the permissible range of realistic polymeric systems, the interface profile
and the degree of encapsulation along the downstream direction were fitted with the experimental results. There was little
difference between the numerical results and the experimental data in the interface profile and the degree of encapsulation
along the downstream direction when the α ratio was set to 3.0 (0.3:0.1). Fluid I with larger magnitude of the second normal
stress difference protrudes into Fluid II with smaller magnitude of the second normal stress difference around the symmetric
plane, while Fluid II wraps around Fluid I near the side walls. As the ξ
1
ratio (ξ
1
,Fluid Iξ
1
,Fluid II) increases from 1.0 to 3.0 for the two-mode Phan-Thien and Tanner model, it was found that the curvature of the interface
profile increased, and the difference between the numerical results and the experimental data in the interface profile and
the degree of encapsulation along the downstream direction was almost negligible when the ξ
1
ratio was set to 3.0 (0.54:0.18). Although the parameters of viscoelastic models were fitted by using the shear viscosity
data only, quantitative agreements between the numerical results and the experimental coextrusion data were quite satisfactory.
Received: 24 April 2001 Accepted: 5 June 2001 相似文献
956.
An experimental study was performed to investigate the macroscopic behavior and atomization characteristics of a high-speed diesel spray impinged on the wall at various injection and impinging conditions. The development processes of sprays impinged on the wall were visualized using the spray visualization system composed of a Nd:YAG laser and an intensified charge-coupled device (ICCD) camera. The atomization characteristics of the impinged spray on the wall were also explored in terms of mean droplet diameter and velocity distributions by using a phase Doppler particle analyzer (PDPA) system. The results provide the effects of injection parameters, wall conditions, and the other various experimental conditions on the macroscopic behavior and atomization characteristics of the impinged sprays on the wall. 相似文献
957.
Formation of a Syndiotactic Organic Polymer Inside a MOF by a [2+2] Photo‐Polymerization Reaction
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Dr. In‐Hyeok Park Dr. Raghavender Medishetty Hyeong‐Hwan Lee Caroline Evania Mulijanto Hong Sheng Quah Prof. Shim Sung Lee Prof. Jagadese J. Vittal 《Angewandte Chemie (International ed. in English)》2015,54(25):7313-7317
Getting suitable crystals for single‐crystal X‐ray crystallographic analysis still remains an art. Obtaining single crystals of metal–organic frameworks (MOFs) containing organic polymers poses even greater challenges. Here we demonstrate the formation of a syndiotactic organic polymer ligand inside a MOF by quantitative [2+2] photopolymerization reaction in a single‐crystal‐to‐single‐crystal manner. The spacer ligands with trans,trans,trans‐conformation in the pillared‐layer MOF with guest water molecules in the channels, undergo pedal motion to trans,cis,trans‐conformation prior to [2+2] photo‐cycloaddition reaction and yield single crystals of MOF containing two‐dimensional coordination polymers fused with the organic polymer ligands. We also show that the organic polymer in the single crystals can be depolymerized reversibly by cleaving the cyclobutane rings upon heating. These MOFs also show interesting photoluminescent properties and sensing of small organic molecules. 相似文献
958.
Chemoselective Silylative Reduction of Conjugated Nitriles under Metal‐Free Catalytic Conditions: β‐Silyl Amines and Enamines
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Dr. Narasimhulu Gandhamsetty Juhyeon Park Jinseong Jeong Dr. Sung‐Woo Park Dr. Sehoon Park Prof. Dr. Sukbok Chang 《Angewandte Chemie (International ed. in English)》2015,54(23):6832-6836
The B(C6F5)3‐catalyzed silylative reduction of conjugated nitriles has been developed to afford synthetically valuable β‐silyl amines. The reaction is chemoselective and proceeds under mild conditions. Mechanistic elucidation indicates that it proceeds by rapid double hydrosilylation of the conjugated nitrile to an enamine intermediate which is subsequently reduced to the β‐silyl amine, thus forming a new C(sp3)? Si bond. Based on this mechanistic understanding, a preparative route to enamines was also established using bulky silanes. 相似文献
959.
Integrating NiCo Alloys with Their Oxides as Efficient Bifunctional Cathode Catalysts for Rechargeable Zinc–Air Batteries
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Dr. Xien Liu Minjoon Park Dr. Min Gyu Kim Shiva Gupta Prof. Gang Wu Prof. Jaephil Cho 《Angewandte Chemie (International ed. in English)》2015,54(33):9654-9658
The lack of high‐efficient, low‐cost, and durable bifunctional electrocatalysts that act simultaneously for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) is currently one of the major obstacles to commercializing the electrical rechargeability of zinc–air batteries. A nanocomposite CoO‐NiO‐NiCo bifunctional electrocatalyst supported by nitrogen‐doped multiwall carbon nanotubes (NCNT/CoO‐NiO‐NiCo) exhibits excellent activity and stability for the ORR/OER in alkaline media. More importantly, real air cathodes made from the bifunctional NCNT/CoO‐NiO‐NiCo catalysts further demonstrated superior performance to state‐of‐the‐art Pt/C or Pt/C+IrO2 catalysts in primary and rechargeable zinc–air batteries. 相似文献
960.
A Family of Molecular Sieves Containing Framework‐Bound Organic Structure‐Directing Agents
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Jun Kyu Lee Dr. Jiho Shin Nak Ho Ahn Alessandro Turrina Dr. Min Bum Park Dr. Youngchul Byun Prof. Sung June Cho Prof. Paul A. Wright Prof. Suk Bong Hong 《Angewandte Chemie (International ed. in English)》2015,54(38):11097-11101
Organic structure‐directing agents (OSDAs), such as quaternary ammonium cations and amines, used in the synthesis of zeolites and related crystalline microporous oxides usually end up entrapped inside the void spaces of the crystallized inorganic host lattice. But none of them is known to form direct chemical bonds to the framework of these industrially important catalysts and adsorbents. We demonstrate that ECR‐40, currently regarded as a typical silicoaluminophosphate molecular sieve, constitutes instead a new family of inorganic‐organic hybrid networks in which the OSDAs are covalently bonded to the inorganic framework. ECR‐40 crystallization begins with the formation of an Al–OSDA complex in the liquid phase in which the Al is octahedrally coordinated. This unit is incorporated in the crystallizing ECR‐40. Subsequent removal of framework‐bound OSDAs generates Al‐O‐Al linkages in a fully tetrahedrally coordinated framework. 相似文献