SnS Nanosheets for 105th Harmonic Soliton Molecule Generation

As a member of the 2D group IV monochalcogenides (MX; M = Sn, Ge; X = S, Se), SnS has attracted great interest due to its outstanding optical, electrical, and optoelectronic properties. Especially, SnS nanosheets material have a large absorption coefficient and high photoelectric conversion efficiency, it can be potentially used in optical modulators, saturable absorbers, solar cells, supercapacitors, and other optical devices. However, the nonlinear optical properties of SnS nanosheets and their applications in ultrafast photonics are seldom studied. In this paper, the nonlinear optical properties of SnS nanosheets have been characterized through a dual‐balance detection system, whose modulation depth is 5.8%. More importantly, 105th harmonic soliton molecule based on SnS saturable absorbers has been realized for the first time to the authors’ knowledge. A compact mode‐locked fiber laser with a pulse duration of 1.02 ps and a repetition rate of 459 MHz is realized near 1.5 µm. It is demonstrated that SnS nanosheets have outstanding nonlinear properties and play an extremely important role in the field of ultrafast photonics.     

氢离子与里德伯原子碰撞中的电荷转移过程

应用双中心原子轨道强耦合方法研究了H⁺与里德伯态原子Li（5d）碰撞的电荷转移过程,计算了电子转移到氢原子各个n,l壳层（这里n为主量子数,l为角量子数）的态选择截面.结果发现,电荷转移的末态主要分布在与初态电子能量5d接近的n=4—7能级,该分布随碰撞能量的变化不大;但俘获末态的l分布对入射离子能量很敏感：在1 keV左右的低能时主要分布在高l的末态,随着碰撞能量增加峰值逐渐向低l方向移动,并在l= 关键词： 电子俘获过程 双中心原子轨道强耦合方法 态选择截面     

Reflection-Absorption Infrared Spectroscopy Study of Polyacrylonitrile on Copper at Elevated Temperature

Reflection-absorption infrared spectroscopy (RAIR) has been used to investigate the chemical structural changes in Polyacrylonitrile (PAN) film adsorbed on copper at 200°C for different time. The formation of an almost fully conjugated C-C=C backbone occurs after heating for only 2 h due to the catalytic effect of copper. The freely dangling cyano groups in PAN molecules initially coordinate to copper surface through the triple bond in π-bonded orientation, then convert to [sgrave]-bonding through the donation of the lone pair of electrons of nitrogen. It is suggested that this transition of the types of coordination would relate to the different geometries of PAN on copper during heating. Since the nitrile complexing and cyclization occur at the same time, the reaction process for the pyrolysis of PAN on copper surface is different from that in the bulk.     

基于虚拟仪器技术和网络的综合实验控制系统设计

为实现大型物理实验现场复杂多样的仪器控制,分析了物理实验的特点、过程、环境及仪器控制功能需求,利用虚拟仪器技术、计算机网络技术和数据库技术,建立了一套集成硬件和软件的综合控制管理信息系统,实现记录系统中示波器状态远程批量设置及波形数据自动采集、控制探测系统的高压电源并发加压或退压、保障各测试项目间测试仪器之间时间关联、监控UPS电量和远端现场图片或视频状态。给出了系统的关键的设计思路,列举了某型示波器控制的通用控制代码。结果表明,系统达到了一人总控或多人分权控制实验过程中多种多台仪器的目标,方便快捷地实现不同品牌不同类型示波器的相同功能。     

Influence of oxalate anions on manganese electrodeposition in sulfate solution

The influences of oxalate anions on manganese electrodeposition in sulfate solution were investigated on the basis of cathode current efficiency, characterization of SEM-EDX and XRD, solution chemistry calculation, thermodynamics and electrochemical test. The experimental results show that the range of (NH₄)₂C₂O₄ was adjusted from 0 mol/L to 4.8?×?10^?3 mol/L. And 1.5?×?10^?3 mol/L (NH₄) ₂C₂O₄ was suitably used with initial pH 7.0. The characterization of SEM indicates that oxalate anions can improve the morphology of electrodeposited films. The electrodeposited films containing manganese were characterized and determined by EDX and XRD. The solution chemistry calculation of catholyte and oxalate anions shows that the main active species are MnSO₄, Mn(SO₄)2? 2, Mn²⁺, Mn(SO₄)C₂O2? 4, MnC₂O 4, Mn(NH₃)²⁺, and C₂O2? 4. The reaction trend between C₂O2? 4 and Mn²⁺ ions is confirmed by computation of reaction energy. Electrochemical test analysis indicates oxalate anions increase the overpotentials of hydrogen evolution reaction and manganese electrodeposition.     

Research on Optical Transmitter and Receiver Module Used for High-Speed Interconnection between CPU and Memory

With the development of the multicore processor, the bandwidth and capacity of the memory, rather than the memory area, are the key factors in server performance. At present, however, the new architectures, such as fully buffered DIMM (FBDIMM), hybrid memory cube (HMC), and high bandwidth memory (HBM), cannot be commercially applied in the server. Therefore, a new architecture for the server is proposed. CPU and memory are separated onto different boards, and optical interconnection is used for the communication between them. Each optical module corresponds to each dual inline memory module (DIMM) with 64 channels. Compared to the previous technology, not only can the architecture realize high-capacity and wide-bandwidth memory, it also can reduce power consumption and cost, and be compatible with the existing dynamic random access memory (DRAM). In this article, the proposed module with system-in-package (SiP) integration is demonstrated. In the optical module, the silicon photonic chip is included, which is a promising technology to be applied in the next-generation data exchanging centers. And due to the bandwidth–distance performance of the optical interconnection, SerDes chips are introduced to convert the 64-bit data at 800 Mbps from/to 4-channel data at 12.8 Gbps after/before they are transmitted though optical fiber. All the devices are packaged on cheap organic substrates. To ensure the performance of the whole system, several optimization efforts have been performed on the two modules. High-speed interconnection traces have been designed and simulated with electromagnetic simulation software. Steady-state thermal characteristics of the transceiver module have been evaluated by ANSYS APLD based on finite-element methodology (FEM). Heat sinks are placed at the hotspot area to ensure the reliability of all working chips. Finally, this transceiver system based on silicon photonics is measured, and the eye diagrams of data and clock signals are verified.     

脉冲偏压电弧离子镀CNx薄膜研究

用脉冲偏压电弧离子镀通过控制不同的氮流量在(100)单晶Si基片上制备了不同成分的CNx薄膜.用光学显微镜,XPS,XRD,激光Raman和Nanoindenter等方法研究了薄膜的形貌、成分、结构和性能.结果表明,薄膜表面平整致密、氮含量随着氮流量的降低而降低、结构为非晶且为类金刚石薄膜;随着氮含量从18.9%降低到5.3%(摩尔百分比,全文同),薄膜的硬度和弹性模量单调增加而且增幅较大,其中硬度从15.0 GPa成倍增加到30.0 GPa;通过氮流量的调整能够敏感地改变薄膜中的sp3键的含量,是CNx薄膜的硬度和弹性模量获得大幅度凋整的本质原因.     

Polarization beam splitter based on dielectric periodic structure with different EFCs for two polarizations

A dielectric multi-layered structure is studied in this letter. It is found that at some frequency ranges, the equal-frequency contours (EFCs) are almost flat for one polarization but still curve for the other. Based on this property, we propose a novel polarization beam splitter.     

Inactivation of bovine immunodeficiency virus by photodynamic therapy with HMME

To investigate the effect of photodynamic therapy (PDT) with hematoporphrin monomethyl ether (HMME) on bovine immunodeficiency virus (BIV) can provide the basis theory for photoinactivation of human immunodeficiency virus (HIV). To assess the protection of HMME-PDT on the cell line Cf2Th infected with BIVR29 by 3-(4,5)-dimethylthiahiazol-2-yl-3,5-di-phenytetrazolium bromide (MTT) with power density of 5 and 25 mW/cm2 and energy density from 0.6 to 3 J/cm<'2>. To observe the inhibition of membrane fusion using a new reporter cell line BIVE by fluorescence microscope. HMME-PDT has significant protectant effects on Cf2Th-BIVR29 with both power densities, especially in the group of high power density. Fluorescent microscope shows that there is no significant difference between the group of PDT and control, which means PDT could not inhibit the BIV-mediated membrane fusion.