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101.
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Pons M Ahufinger V Wunderlich C Sanpera A Braungardt S Sen De A Sen U Lewenstein M 《Physical review letters》2007,98(2):023003
We demonstrate the possibility of realizing a neural network in a chain of trapped ions with induced long range interactions. Such models permit one to store information distributed over the whole system. The storage capacity of such a network, which depends on the phonon spectrum of the system, can be controlled by changing the external trapping potential. We analyze the implementation of error resistant universal quantum information processing in such systems. 相似文献
104.
Zacher D Yusenko K Bétard A Henke S Molon M Ladnorg T Shekhah O Schüpbach B de los Arcos T Krasnopolski M Meilikhov M Winter J Terfort A Wöll C Fischer RA 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(5):1448-1455
The progressive liquid-phase layer-by-layer (LbL) growth of anisotropic multicomponent layer-based porous coordination polymers (PCPs) of the general formula [M(L)(P)(0.5)] (M: Cu(2+), Zn(2+); L: dicarboxylate linker; P: dinitrogen pillar ligand) was investigated by using either pyridyl- or carboxyl-terminated self-assembled monolayers (SAMs) on gold substrates as templates. It was found that the deposition of smooth, highly crystalline, and oriented multilayer films of these PCPs depends on the conditions at the early growth cycles. In the case of a two-step process with an equimolar mixture of L and P, growth along the [001] direction is strongly preferred. However, employing a three-step scheme with full separation of all components allows deposition along the [100] direction on carboxyl-terminated SAMs. Interestingly, the growth of additional layers on top of previously grown oriented seeding layers proved to be insensitive to the particular growth scheme and full retention of the initial orientation, either along the [001] or [100] direction, was observed. This homo- and heteroepitaxial LbL growth allows full control over the orientation and the layer sequence, including introduction of functionalized linkers and pillars. 相似文献
105.
The detection of corticosteroids and sex steroids in samples with no content indication, which are confiscated for forensic
investigation, is a challenge in doping analysis. A screening method based on the identification of androgens, estrogens,
gestagens, and their esters by means of a mass spectral library, along with a fast ultra-performance liquid chromatography–mass
spectrometry (UPLC-MS) method, was recently developed in our lab for the analysis of dietary supplements. However, for forensic
investigations, it is important to extend the scope of the method to corticosteroids in various matrices. Therefore, 36 corticosteroids
were added to the mass spectral library, and the sample preparation step was modified so that androgens, gestagens, corticosteroids,
and their esters could be analyzed with only one injection with the UPLC-MS method. A complementary tool to the existing library
identification was found in the extraction of common fragment ions out of the full scan data obtained for the library search.
The fragment ion with m/z 147 was found to be a good marker for the detection of steroids. Extra confirmation was obtained from the fragment ions with
m/z 135 (for all steroids) and 237 (specific for corticosteroids) or from the fragment ions with m/z 77, 91, and 105. The effectiveness of this approach was evaluated on some samples previously screened for forensic investigation
with thin-layer chromatography and confirmed with a targeted gas chromatography–mass spectrometry method. This study shows
that the combination of the library identification and the common fragment ions approach can be a valuable tool in the detection
of steroids without defining any target at the start of the analysis. 相似文献
106.
Shekhah O Arslan HK Chen K Schmittel M Maul R Wenzel W Wöll C 《Chemical communications (Cambridge, England)》2011,47(40):11210-11212
Thin films of MOFs grown on solid substrates offer a huge potential with regard to tailoring the properties of a surface, in particular if used in connection with post-synthesis modification (PSM). Here, we report on the PSM of surface-supported crystalline MOFs, with target molecules using an amine-based coupling strategy. 相似文献
107.
Christof Külske 《Journal of statistical physics》2003,112(5-6):1079-1108
It is known that the joint measures on the product of spin-space and disorder space are very often non-Gibbsian measures, for lattice systems with quenched disorder, at low temperature. Are there reflections of this non-Gibbsianness in the corresponding mean-field models? We study the continuity properties of the conditional probabilities in finite volume of the following mean field models: (a) joint measures of random field Ising, (b) joint measures of dilute Ising, (c) decimation of ferromagnetic Ising. The conditional probabilities are functions of the empirical mean of the conditionings; so we look at the large volume behavior of these functions to discover non-trivial limiting objects. For (a) we find (1) discontinuous dependence for almost any realization and (2) dependence of the conditional probabilities on the phase. In contrast to that we see continuous behavior for (b) and (c), for almost any realization. This is in complete analogy to the behavior of the corresponding lattice models in high dimensions. It shows that non-Gibbsian behavior which seems a genuine lattice phenomenon can be partially understood already on the level of mean-field models. 相似文献
108.
109.
The Car-Parrinello method for ab-initio molecular dynamics avoids the explicit minimization of energy functionals given by
functional density theory in the context of the quantum adiabatic approximation (time-dependent Born-Oppenheimer approximation).
Instead, it introduces a fictitious classical dynamics for the electronic orbitals. For many realistic systems this concept
allowed first-principle computer simulations for the first time. In this paper we study the quantitative influence of the involved parameter , the fictitious electronic mass of the method. In particular, we prove by use of a carefully chosen two-time-scale asymptotics
that the deviation of the Car-Parrinello method from the adiabatic model is of order – provided one starts in the ground state of the electronic system and the electronic excitation spectrum satisfies a certain
non-degeneracy condition. Analyzing a two-level model problem we prove that our result cannot be improved in general.
Received June 14, 1996 相似文献
110.