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81.
Eldrup AB Christensen C Haaima G Nielsen PE 《Journal of the American Chemical Society》2002,124(13):3254-3262
The synthesis and evaluation of a series of novel nucleobases based on substituted 1,8-naphthyridin-2(1H)-ones are reported. The nucleobases were designed to meet the requirements for incorporation into peptide nucleic acids (PNAs) and were evaluated as part of PNA duplex and triplex nucleic acid recognition systems. Of the various nucleobases tested, only the 7-chloro-1,8-naphthyridin-2(1H)-one (7-Cl-bT) nucleobase led to consistently increased affinity in all recognition systems, duplex (Watson-Crick) as well as triplex (Hoogsteen). For multiply modified systems, the increase in thermal stability per modification was dependent on the sequence context, ranging from 2.0 degrees C (in separate positions) to 3.5 degrees C (in adjacent positions) in PNA-DNA duplexes and from 1.2 degrees C (in separate positions) to 3.2 degrees C (in adjacent positions) in PNA-RNA duplexes. Singly mismatched oligonucleotide targets were employed to demonstrate uncompromised sequence discrimination. When part of multiply modified triplex (Hoogsteen) recognition systems, the 7-Cl-bT unit gave rise to increases in the thermal stability ranging from 2.7 to 3.5 degrees C when incorporated into separated and adjacent positions, respectively. Our results furthermore indicate that the duplex stabilization is predominantly enthalpic and therefore most likely not a consequence of single-strand preorganization. Finally, and most surprisingly, we find no direct correlation between the end-stacking efficiency of this type of nucleobase and its helix stabilization when involved in Watson-Crick base pairing within a helix. 相似文献
82.
Bearden IG Beavis D Besliu C Blyakhman Y Budick B Bøggild H Chasman C Christensen CH Christiansen P Cibor J Debbe R Enger E Gaardhøje JJ Hagel K Hansen O Holm A Holme AK Ito H Jakobsen E Jipa A Jørdre JI Jundt F Jørgensen CE Karabowicz R Keutgen T Kim EJ Kozik T Larsen TM Lee JH Lee YK Løvhøiden G Majka Z Makeev A McBreen B Mikelsen M Murray M Natowitz J Nielsen BS Norris J Olchanski K Olness J Ouerdane D Płaneta R Rami F Ristea C Röhrich D Samset BH Sandberg D Sanders SJ Sheetz RA Staszel P 《Physical review letters》2002,88(20):202301
We present charged-particle multiplicities as a function of pseudorapidity and collision centrality for the 197Au+197Au reaction at square root[s(NN)] = 200 GeV. For the 5% most central events we obtain dN(ch)/deta/(eta = 0) = 625+/-55 and N(ch)/(-4.7< or =eta < or =4.7) = 4630 +/- 370, i.e., 14% and 21% increases, respectively, relative to square root[s(NN)] = 130 GeV collisions. Charged-particle production per pair of participant nucleons is found to increase from peripheral to central collisions around midrapidity. These results constrain current models of particle production at the highest RHIC energy. 相似文献
83.
The splitting of the spin degeneracy of the lowest conduction band of GaAs for along [110] is calculated by · perturbation theory as well as by means of the self-consistent LMTO method. The magnitude and the sign of the calculated splitting agree with recent measurements of the spin precession in spin- polarized photoemission from GaAs [110] surfaces. 相似文献
84.
85.
R. Nieva G. S. Christensen M. E. El-Hawary 《Journal of Optimization Theory and Applications》1981,35(2):261-275
This paper considers the problem of short-term optimal operation of nuclear-hydro-thermal electric power systems. The solution is obtained by use of a functional analytic optimization technique that employs the minimum norm formulation.A power system with an arbitrary number of generating stations is considered. The limited flexibility exhibited by the thermal nuclear reactors, when operating in a load-following mode, is accounted for by means of a model of the xenon concentration in their cores. The nonlinear effects induced by trapezoidal water reservoirs and the time delay of the water flow between upstream and downstream hydroplants is taken into consideration as well.A two-level iterative scheme of the feasible type is proposed for implementing the optimal solution.This work was supported in part by the National Research Council of Canada, Grant No. A-4146. 相似文献
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87.
S.Brøgger Christensen Ulla Rasmussen Carsten Christophersen 《Tetrahedron letters》1980,21(39):3829-3830
The major skin irritating constituent of the root of Thapsia garganica L. has been shown to be a hexaoxygenated-C6-guaianolide esterificated with four carboxylic acids. 相似文献
88.
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90.
R.M. Christensen 《International Journal of Solids and Structures》1976,12(7):537-544
Asymptotic methods are used to obtain simple formulas for use in predicting the effective modulus properties of composite materials containing randomly oriented fibers. Both cases of two and three dimensional random orientation are treated. The theoretical predictions are compared with experimental results in the two-dimensional case. The results extend and simplify an earlier approach to the problem. 相似文献