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991.
The collision dynamics between a droplet and a film has been studied with high-impact energy that can be grouped in a dimensionless
Weber number, We, as normalized by surface energy. To accomplish this, we have developed a technique based on cutting of a high-speed jet,
which can generate a single droplet with speed up to 23 m/s and We on the order of thousands. It was found that the boundaries indicating the occurrence of a central jet and that of a secondary
droplet disintegrated from the jet decreased monotonically with increased dimensionless film thickness, H, and remained constant when the film thickness was larger than the crater depth. However, the transition designating multiple
droplets that are originated from a central jet shows a non-monotonic trend with the variation of H, with a minimum We being at H ≈ 3, which is about the maximum crater depth, owing to a tuning behavior. The critical We for splashing that occurs at an early phase immediately after the impact is relatively sensitive to the film thickness only
when H is between 1 and 2, which increases with reduced H. At large We (≳2,570 for high H), the ejected crown is closed to form a bubble and the transition boundary reveals a similar dependence on H as that for creation of a central jet. 相似文献
992.
This paper discusses two series of experiments performed in a shear cell device with six different amounts of silicone oils and using 2-mm soda lime beads as the granular materials. The first series of experiments were mixing experiments, and the developments of mixing layer thicknesses were measured. The second series of experiments had the same experimental conditions as the first series but used different combinations of colored particles. In the second series of experiments, the motions of granular materials were recorded by a high-speed camera. Using the image processing technology and particle tracking method, the positions and velocities of particles were measured. The self-diffusion coefficient could be found from the history of the particle displacements. 相似文献
993.
We have recently developed a new type of chiral templates, dibenzosuberanes. Thess C2, symmetric diaryl modifiers have been successfully applied to the synthesis of chiral triarylcarbenium ions. They can serve as catalysts in the asymmetric Mukaiyama aldol reactions with moderate enantioselectivities of up to 50% [1]. We have subsequently found that one major side reaction between the catalyst and the substrate-silyl ketene acetal which releases extra silyl-X species is responsible for the erosion of asymmetric induction. The dibenzosuberane scaffold was found essential to prevent this type of side reaction. For the selection of carbenium counter ions, we have resorted to the chloride in order to completely suppress the undesired silyl catalysis [2]. 相似文献
994.
995.
996.
The intercalation of aluminosilicate clays proceeds via a critical conformation change. Ion exchange of the poly(oxypropylene)diamine salts allows widening of the clay layers from 12 Å to 20 Å and then a sharp increase to 58 Å. The data indicate a critical conformation change of the intercalated amines, thus providing a new way for manipulating nanomaterials and control of polymer conformations in layered silicate confinement.
997.
Qing Xia Deyuan Li Lanling Zhao Jun Wang Yuxin Long Xue Han Zhaorui Zhou Yao Liu Yiming Zhang Yebing Li Abulgasim Ahmed Abbaker Adam Shulei Chou 《Chemical science》2022,13(10):2841
Developing efficient energy storage and conversion applications is vital to address fossil energy depletion and global warming. Li–O2 batteries are one of the most promising devices because of their ultra-high energy density. To overcome their practical difficulties including low specific capacities, high overpotentials, limited rate capability and poor cycle stability, an intensive search for highly efficient electrocatalysts has been performed. Recently, it has been reported that heterostructured catalysts exhibit significantly enhanced activities toward the oxygen reduction reaction and oxygen evolution reaction, and their excellent performance is not only related to the catalyst materials themselves but also the special hetero-interfaces. Herein, an overview focused on the electrocatalytic functions of heterostructured catalysts for non-aqueous Li–O2 batteries is presented by summarizing recent research progress. Reduction mechanisms of Li–O2 batteries are first introduced, followed by a detailed discussion on the typical performance enhancement mechanisms of the heterostructured catalysts with different phases and heterointerfaces, and the various heterostructured catalysts applied in Li–O2 batteries are also intensively discussed. Finally, the existing problems and development perspectives on the heterostructure applications are presented.The structure–function relationships between heterostructures and their catalytic properties were discussed in detail, and the challenges and improvement strategies for heterostructure based cathodes towards Li–O2 catalysis were also summarized. 相似文献
998.
Chia-Ou Chang Guo-En Chang Chan-Shin Chou Wen-Tien Chang Chien Po-Chih Chen 《International Journal of Solids and Structures》2008,45(24):6114-6132
In this paper the natural frequencies and the associated mode shapes of in-plane free vibration of a single-crystal silicon ring are analyzed. It is found that the Si(1 1 1) ring is two-dimensionally isotropic in the (1 1 1) plane for elastic constants but three-dimensionally anisotropic, while the Si(1 0 0) ring is fully anisotropic. Hamilton’s principle is used to derive the equations of vibration, which is a set of partial differential equations with coefficients being periodic in polar variable. Expressing the radial and tangential displacements in sinusoidal form with non-predetermined amplitudes, and through the integration with respect to the circumferential variable, the original governing equations in partial differential form can be converted into the amplitude equations in ordinary differential form. The exact expressions for frequencies and mode shapes are obtained. It is found that for Si(1 0 0) rings the frequencies of a pair of modes, which are equal for an isotropic ring, split due to the anisotropic effect only for the second in-plane vibration mode. The phenomena of frequency splitting and degenerate modes can be proved either based on the conservation of averaged mechanical energy or by the concept of crystallographic symmetry groups. When the single-crystal silicon is replaced by the polycrystalline silicon, which is isotropic in elastic constants, the derived equations for frequencies correctly predict the vanishing of the phenomenon of frequency splitting. 相似文献
999.
The title compound 2 was readily prepared by MCPBA oxidation of the sulfide 1. Thermal desulfonylation of 2 gave the sulfoxide‐substituted diene 3. The Diels‐Alder reactions of 3 with various dienophiles gave the cyclized products 4‐9 in good yields. The regiochemistry was found to be dominated by the phenylsulfinyl group, but could be reversed by the presence of a Lewis acid. Deprotonation of 2 by BuLi, followed by the reaction with alkyl halides, gave the substituted 2‐sulfolenes 10. A synthetic application of 10 was demonstrated by converting 10e to the bicyclic product 11. 相似文献
1000.
In this research, an experimental short-range visible light communication link using red-, green-, and blue-based light-emitting diodes (LEDs) for portable micro-projector applications is presented. A Reconfigurable design of a post-equalizer aimed to improve the inherent narrow modulation bandwidth of red-, green-, and blue-based LEDs has been experimentally implemented, and its effectiveness with optical filters at the receiver is investigated. Reflective liquid-crystal-on-silicon-based micro-projection architecture, widely used in portable micro-projectors, was set up to evaluate the proposed visible light communication system. The measurement results demonstrated that a significant aggregative bandwidth improvement of 162 MHz as well as an aggregative data transmission rate of nearly 400 Mb/s can be achieved by using a non-return-to-zero–on-off keying (NRZ–OOK) modulation scheme based on only one polarization state of incident light without any offline signal processing. 相似文献