全文获取类型
收费全文 | 854篇 |
免费 | 73篇 |
国内免费 | 7篇 |
专业分类
化学 | 678篇 |
晶体学 | 7篇 |
力学 | 43篇 |
数学 | 82篇 |
物理学 | 124篇 |
出版年
2023年 | 4篇 |
2022年 | 5篇 |
2021年 | 8篇 |
2020年 | 16篇 |
2019年 | 24篇 |
2018年 | 10篇 |
2017年 | 9篇 |
2016年 | 33篇 |
2015年 | 34篇 |
2014年 | 46篇 |
2013年 | 58篇 |
2012年 | 49篇 |
2011年 | 55篇 |
2010年 | 55篇 |
2009年 | 61篇 |
2008年 | 52篇 |
2007年 | 48篇 |
2006年 | 39篇 |
2005年 | 37篇 |
2004年 | 47篇 |
2003年 | 35篇 |
2002年 | 36篇 |
2001年 | 19篇 |
2000年 | 26篇 |
1999年 | 13篇 |
1998年 | 9篇 |
1997年 | 5篇 |
1996年 | 4篇 |
1995年 | 8篇 |
1994年 | 8篇 |
1993年 | 16篇 |
1992年 | 11篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1966年 | 1篇 |
1965年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有934条查询结果,搜索用时 15 毫秒
51.
Ya‐Ching Shen Yuan‐Bin Cheng Yu‐Hui Chen Ashraf Taha Khalil Chin‐Lien Ko 《中国化学会会志》2005,52(6):1263-1268
Three new clerodane diterpene derivatives were isolated from the leaves of Casearia membranacea Hance collected in Taiwan. The isolated metabolites were identified as caseamembrins P (1), Q (2), and R (3). Identification of the structures was based on detailed analysis of the spectral data, especially 2D NMR. 相似文献
52.
Chun Chieh Huang Ching Hsuan Lin Shenghong A. Dai 《Journal of polymer science. Part A, Polymer chemistry》2016,54(6):802-808
4‐Isopropenyl phenol ( 4‐IPP ) is a versatile dual functional intermediate that can be prepared readily from bisphenol‐A ( BPA ). Through etherification with epichlorohydrin to the phenolic group of 4‐IPP , it can be converted into 4‐isopropenyl phenyl glycidyl ether ( IPGE ). On further reaction with carbon dioxide in the presence of tetra‐n‐butyl ammonium bromide ( TBAB ) as the catalyst, IPGE was transformed into 4‐isopropenylphenoxy propylene carbonate ( IPPC ) in 90% yield. Cationic polymerization of IPPC with strong acid such as trifluoromethanesulfonic acid or boron trifluoride diethyl etherate as the catalyst at ?40 °C gave a linear poly(isopropenylphenoxy propylene carbonate), poly( IPPC ), with multicyclic carbonate groups substituted uniformly at the side‐chains of the polymer. The cyclic carbonate groups of poly( IPPC ) were further reacted with different aliphatic amines and diamines resulting in formation of polymers with hydroxy‐polyurethane on side‐chains. Syntheses, characterizations of poly( IPPC ) and its conversion into hydroxy‐polyurethane crosslinked polymers were presented. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 802–808 相似文献
53.
54.
Zi-Wei Zhao Hung-Chi Chang Hui Ching Jin-Cherng Lien Hui-Chi Huang Chi-Rei Wu 《Molecules (Basel, Switzerland)》2021,26(13)
In the present investigation, we compared the radical-scavenging activities and phenolic contents of seven Taiwanese Cirsium species with a spectrophotometric method. We further analyzed their phytochemical profiles with high-performance liquid chromatography–photodiode array detection (HPLC–DAD). We found that the flower part of Cirsium japonicum var. australe (CJF) showed the best radical-scavenging activities against 1,1-diphenyl-2-picrylhydrazyl (DPPH), 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), and the hypochlorite ion, for which the equivalents were 6.44 ± 0.17 mg catechin/g, 54.85 ± 0.66 mmol Trolox/g and 418.69 ± 10.52 mmol Trolox/g respectively. CJF also had the highest contents of total phenolics (5.23 ± 0.20 mg catechin/g) and phenylpropanoids (29.73 ± 0.72 mg verbascoside/g). According to the Pearson’s correlation coefficient, there was a positive correlation between the total phenylpropanoid content and ABTS radical-scavenging activities (r = 0.979). The radical-scavenging activities of the phenylpropanoids are closely related to their reducing power (r = 0.986). HPLC chromatograms obtained in validated HPLC conditions confirm that they have different phytochemical profiles by which they can be distinguished. Only CJF contained silicristin (0.66 ± 0.03 mg/g) and silydianin (9.13 ± 0.30 mg/g). CJF contained the highest contents of apigenin (5.56 ± 0.09 mg/g) and diosmetin (2.82 ± 0.10 mg/g). Among the major constituents, silicristin had the best radical-scavenging activities against DPPH (71.68 ± 0.66 mg catechin/g) and ABTS (3.01 ± 0.01 mmol Trolox/g). However, diosmetin had the best reducing power and radical-scavenging activity against the hypochlorite anion (41.57 ± 1.14 mg mmol Trolox/g). Finally, we found that flavonolignans (especial silicristin and silydianin) and diosmetin acted synergistically in scavenging radicals. 相似文献
55.
Lee Chee Ching Omar Fatin Saiha Numan Arshid Duraisamy Navaneethan Ramesh K. Ramesh S. 《Journal of Solid State Electrochemistry》2017,21(11):3205-3213
Journal of Solid State Electrochemistry - Manganese phosphate (Mn3(PO4)2) particles decorated polyaniline (PANI) have been proposed as a promising electrode material for supercapacitors. Mn3(PO4)2... 相似文献
56.
In this paper two new architectures for optical image verification are proposed. Both architectures are based on conventional joint transform correlators (JTCs) adopting a Fourier hologram and can significantly improve the recovered image quality. First, an input phase-only function is Fourier transformed and then interferes with a reference wave that is diffracted from a plane wave incident on another random phase mask. Second, two phase-only functions are placed at the two input sides of a beamsplitter such that the interference pattern of their Fourier transforms can be detected. To obtain a predefined target image in the output plane, one of the input phase functions is iteratively retrieved by the use of the projection onto constraint sets algorithm. Simulation results show that the less mean squared error and better image quality are obtained for both the binary and grayscale images. 相似文献
57.
This work describes a novel method for the accurate determination of lysergic acid diethylamide (LSD) in tablets. A technique involving sweeping-micellar electrokinetic chromatography (MEKC) was used for the initial on-line concentration and separation, after which a cryogenic molecular fluorescence experiment was performed at 77 K. Using this approach, not only the separation of LSD from the tablet extract was achieved, but on-line spectra were readily distinguishable and could be unambiguously assigned. The results are in agreement with analyses by gas chromatography-mass spectrometry (GC-MS). Thus, this method, which was found to be accurate, sensitive and rapid, has the potential for use as a reliable complementary method to GC-MS in such analyses. 相似文献
58.
59.
A series of 4‐[2‐(alicyclic‐[1,2,4]oxadiazol‐3‐yl)phenoxy]‐butyric acids were synthesized from N‐hydroxy‐2‐isopropoxy benzamidine in 4 steps with good yields. These [1,2,4]oxadiazoles are novel platelet aggregation inhibitors preventing human platelet aggregation induced by thromboxane derivative U44,619 and adenosine diphosphate. A structure‐activity‐relationship study revealed that the potency for these 5‐oxadiazoles increases with the increase in the ring size of the alicylic rings. Derivative 8f may be useful as a template for the design of more potent anti‐platelet agents. 相似文献
60.
Shao Hui Teo Ching Yern Chee Mochamad Zakki Fahmi Satya Candra Wibawa Sakti Hwei Voon Lee 《Molecules (Basel, Switzerland)》2022,27(21)
In the past few years, the research on particle-stabilized emulsion (Pickering emulsion) has mainly focused on the usage of inorganic particles with well-defined shapes, narrow size distributions, and chemical tunability of the surfaces such as silica, alumina, and clay. However, the presence of incompatibility of some inorganic particles that are non-safe to humans and the ecosystem and their poor sustainability has led to a shift towards the development of materials of biological origin. For this reason, nano-dimensional cellulose (nanocellulose) derived from natural plants is suitable for use as a Pickering material for liquid interface stabilization for various non-toxic product formulations (e.g., the food and beverage, cosmetic, personal care, hygiene, pharmaceutical, and biomedical fields). However, the current understanding of nanocellulose-stabilized Pickering emulsion still lacks consistency in terms of the structural, self-assembly, and physio-chemical properties of nanocellulose towards the stabilization between liquid and oil interfaces. Thus, this review aims to provide a comprehensive study of the behavior of nanocellulose-based particles and their ability as a Pickering functionality to stabilize emulsion droplets. Extensive discussion on the characteristics of nanocelluloses, morphology, and preparation methods that can potentially be applied as Pickering emulsifiers in a different range of emulsions is provided. Nanocellulose’s surface modification for the purpose of altering its characteristics and provoking multifunctional roles for high-grade non-toxic applications is discussed. Subsequently, the water–oil stabilization mechanism and the criteria for effective emulsion stabilization are summarized in this review. Lastly, we discuss the toxicity profile and risk assessment guidelines for the whole life cycle of nanocellulose from the fresh feedstock to the end-life of the product. 相似文献