全文获取类型
收费全文 | 5214篇 |
免费 | 209篇 |
国内免费 | 985篇 |
专业分类
化学 | 2679篇 |
晶体学 | 6篇 |
力学 | 363篇 |
综合类 | 48篇 |
数学 | 1043篇 |
物理学 | 2269篇 |
出版年
2022年 | 10篇 |
2021年 | 11篇 |
2020年 | 10篇 |
2019年 | 6篇 |
2018年 | 9篇 |
2017年 | 12篇 |
2016年 | 33篇 |
2015年 | 16篇 |
2014年 | 32篇 |
2013年 | 69篇 |
2012年 | 75篇 |
2011年 | 1094篇 |
2010年 | 560篇 |
2009年 | 576篇 |
2008年 | 92篇 |
2007年 | 98篇 |
2006年 | 166篇 |
2005年 | 245篇 |
2004年 | 995篇 |
2003年 | 637篇 |
2002年 | 448篇 |
2001年 | 250篇 |
2000年 | 111篇 |
1999年 | 97篇 |
1998年 | 100篇 |
1997年 | 66篇 |
1996年 | 43篇 |
1995年 | 38篇 |
1994年 | 39篇 |
1993年 | 124篇 |
1992年 | 88篇 |
1991年 | 42篇 |
1990年 | 49篇 |
1989年 | 51篇 |
1988年 | 38篇 |
1987年 | 3篇 |
1986年 | 7篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1977年 | 3篇 |
1935年 | 2篇 |
1932年 | 2篇 |
1928年 | 2篇 |
1919年 | 3篇 |
1917年 | 2篇 |
1916年 | 2篇 |
1911年 | 4篇 |
1910年 | 3篇 |
1909年 | 3篇 |
1907年 | 3篇 |
排序方式: 共有6408条查询结果,搜索用时 0 毫秒
81.
Synthesis of porphyrin nitrogen mustards with potential anti-tumor activities in chemotheraphy and photodynamic therapy 总被引:3,自引:0,他引:3
2,7,12,18-Tetramethyl-13,17-di[3'-N,N'-di(2"-chloroethyl)aminopropyl]porphin and it's 3,8-di(1'-alkyloxyethyl)-analogous or porphyrin-nitrogen mustards were synthesized for the first time Their structures were determined by spectroscopics and elemental analyses.Most of the compounds possess both the chemotherapeutic and photodynamic effects on tumor and deserve further investigation. 相似文献
82.
Study of Tea Digitized Chromatographic Fingerprint Spectra Using Micellar Electrokinetic Chromatography 总被引:1,自引:0,他引:1
IntroductionTeaisthemostwidelyconsumedbeverageinpeople’slife .Theheightenedpopularityofthisbeveragethroughouttheworldinrecentyearsmaybedueinparttotheevidenceofarelationshipbetweenteaconsumptionandpreventionofcertainformsofhumandisease .Themaincomponentsofteaarepolyphenoliccompounds ,commonlyknownascatechins ,whichrepresentagroupofcom poundsbelongingtotheflavonoidfamily .Thesecom poundsarewidelydistributedinthetealeavesandconsti tuteupto 30 %ofthedryleafweight.1Muchinteresthasbeenfocusedoncat… 相似文献
83.
The herbicidal activities of a series of 1,2,4-triazolo[1,5-a]pyrimidine-2-sulfonanilides containing various substituents on the benzene ring were quantitatively analyzed with physicochemi-cal parameters by using Hansch-Fujita method.Variations in the activity were parabolically related to electronic parameters with the optimum pKavalue being about 6.93.The hydrophobic factor in addition to the electronic property seemed to have important effect on the activity. 相似文献
84.
85.
Introduction As an important type of fungicides, triazole compounds are highly efficient, low poisonous and inward absorbent.1-3 At present, the studies on triazole derivatives are mainly concentrated on compounds with triazole as the only active group. The report of triazole compounds that contain both triazole group and other active group in a single molecule has rarely been found. Dialkyl-substituted dithiocarbamate salts have also shown interesting biological effects.4 N,N-Dialkyldithio-… 相似文献
86.
报道了一种快速、简便的同时测定食用香料麦芽酚、乙基麦芽酚光度法,方法基于在pH2.87的B R缓冲溶液中对麦芽酚和乙基麦芽酚两组分混合溶液进行光度测定,所得的重叠波谱数据用主成分回归法(PCR)、经典最小二乘法(CLS)和偏最小二乘法(PLS)等化学计量学方法进行处理,结果表明主成分回归法(PCR)的预报误差最小。对样品进行测定,获得了较好的定量分析结果。麦芽酚和乙基麦芽酚的线性范围均为1.0~20.0mg·L-1;检出限分别为0.4347和0 5589mg·L-1。 相似文献
87.
88.
张雨文 《广东微量元素科学》2003,10(7):61-63
老年人由于组织器官的老化和功能减退,影响药物的吸收、分布、代谢和排泄。为确保老年患者的用药安全,应提高老年人的合理用药水平。 相似文献
89.
Nian Yun YANG Shi Hui QIAN Jin Ao DUAN Ping LI Li Juan TIAN Jiangsu Academy of Traditional Chinese Medicine Nanjing China Pharmaceutical University Nanjing Jinling Pharmaceutical Company Limited Nanjing 《中国化学快报》2005,16(9)
Various germacrane sesquiterpenes have been isolated from many species of the Eupatorium.In recent years these compounds have been increasing interest due to their insecticidal,cytotoxic,antitumor-promoting and insect-antifeedant activities1.In our present study,we have investigated the chemical constituents of Eupatorium lindleyanum DC.,which is a geo-authentic medicine of Jiangsu province.It is used as a antipyretic drug.Two novel germacrane sesquiterpenes(Figure1)were found by us from th… 相似文献
90.
Mg-based hydrogen storage alloys Mg0.9Ti0.1-xZrxNi (x=0.02, 0.04, 0.06) were successfully prepared by means of mechanical alloying (MA). The effects of Zr addition on the discharge capacity and the cycle performance of the Mg-based electrodes were also studied. It was found that the discharge capacities were improved with addition of a small amount of Zr and the cycle performances of the alloy were stabilized with the addition of Ti. The effects of surface modification or coating on the properties of Mg0.9Ti0.06Zr0.04Ni were also studied. The results indicated that coating with graphite improved both the discharge capacity and cycle life of the amorphous Mg0.9Ti0.06Zr0.04Ni electrode. 相似文献