全文获取类型
收费全文 | 1232篇 |
免费 | 41篇 |
国内免费 | 11篇 |
专业分类
化学 | 691篇 |
晶体学 | 8篇 |
力学 | 72篇 |
数学 | 116篇 |
物理学 | 397篇 |
出版年
2023年 | 9篇 |
2022年 | 7篇 |
2021年 | 7篇 |
2019年 | 19篇 |
2018年 | 7篇 |
2017年 | 6篇 |
2016年 | 23篇 |
2015年 | 25篇 |
2014年 | 35篇 |
2013年 | 45篇 |
2012年 | 84篇 |
2011年 | 94篇 |
2010年 | 57篇 |
2009年 | 61篇 |
2008年 | 68篇 |
2007年 | 76篇 |
2006年 | 67篇 |
2005年 | 58篇 |
2004年 | 40篇 |
2003年 | 39篇 |
2002年 | 31篇 |
2001年 | 28篇 |
2000年 | 28篇 |
1999年 | 12篇 |
1998年 | 10篇 |
1997年 | 16篇 |
1996年 | 18篇 |
1995年 | 9篇 |
1994年 | 15篇 |
1993年 | 29篇 |
1992年 | 19篇 |
1991年 | 24篇 |
1990年 | 20篇 |
1989年 | 11篇 |
1988年 | 11篇 |
1987年 | 13篇 |
1985年 | 9篇 |
1984年 | 10篇 |
1983年 | 7篇 |
1982年 | 13篇 |
1981年 | 11篇 |
1980年 | 12篇 |
1979年 | 15篇 |
1978年 | 11篇 |
1977年 | 9篇 |
1975年 | 7篇 |
1974年 | 6篇 |
1972年 | 5篇 |
1970年 | 7篇 |
1969年 | 8篇 |
排序方式: 共有1284条查询结果,搜索用时 15 毫秒
141.
A biosensor was fabricated to detect pesticides in food samples. Acetylcholinesterase was immobilized in a novel fenugreek hydrogel–agarose matrix with gold nanoparticles. Transparent thin films with superior mechanical strength and stability were obtained with 2% fenugreek hydrogel and 2% agarose. Immobilization of acetylcholinesterase on the membrane resulted in high enzyme retention efficiency (92%) and a significantly prolonged shelf life of the enzyme (half-life, 55 days). Transmission electron microscopy revealed that, gold nanoparticles (10–20 nm in diameter) were uniformly dispersed in the fenugreek hydrogel–agarose–acetylcholinesterase membrane. This immobilized enzyme-gold nanoparticle dip-strip system detected various carbamates, including carbofuran, oxamyl, methomyl, and carbaryl, with limits of detection of 2, 21, 113, and 236 nM (S/N = 3), respectively. Furthermore, the fabricated biosensor exhibited good testing capabilities when used to detect carbamates added to various fruit and vegetable samples. 相似文献
142.
[Cu32(H)20{S2P(OiPr)2}12]: The Largest Number of Hydrides Recorded in a Molecular Nanocluster by Neutron Diffraction 下载免费PDF全文
Dr. Rajendra S. Dhayal Jian‐Hong Liao Dr. Samia Kahlal Dr. Xiaoping Wang Dr. Yu‐Chiao Liu Dr. Ming‐Hsi Chiang Prof. Werner E. van Zyl Prof. Jean‐Yves Saillard Prof. C. W. Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(23):8369-8374
An air‐ and moisture‐stable nanoscale polyhydrido copper cluster [Cu32(H)20{S2P(OiPr)2}12] ( 1H ) was synthesized and structurally characterized. The molecular structure of 1H exhibits a hexacapped pseudo‐rhombohedral core of 14 Cu atoms sandwiched between two nestlike triangular cupola fragments of (2×9) Cu atoms in an elongated triangular gyrobicupola polyhedron. The discrete Cu32 cluster is stabilized by 12 dithiophosphate ligands and a record number of 20 hydride ligands, which were found by high‐resolution neutron diffraction to exhibit tri‐, tetra‐, and pentacoordinated hydrides in capping and interstitial modes. This result was further supported by a density functional theory investigation on the simplified model [Cu32(H)20(S2PH2)12]. 相似文献
143.
Inside Back Cover: A Reversible Proton Relay Process Mediated by Hydrogen‐Bonding Interactions in [FeFe]Hydrogenase Modeling (Chem. Eur. J. 31/2015) 下载免费PDF全文
144.
Mixed convection boundary layer flows of non-Newtonian fluids over the wavy surfaces are studied by the coordinate transformation and the cubic spline collocation numerical method. The effects of the wavy geometry, the buoyancy parameter and the generalized Prandtl number for pseudoplastic fluids, Newtonian fluids and dilatant fluids on the skin-friction coefficient, local and mean Nusselt numbers have been graphically studied. Results show that both higher generalized Prandtl numbers and buoyancy parameters are seen to enhance the influence of wavy surfaces on the local Nusselt number, irrespective of whether the fluids are Newtonian fluids or non-Newtonian fluids. Moreover, the irregular surfaces have higher total heat flux than that of corresponding flats plate for any fluid. 相似文献
145.
Experimental and theoretical studies of edge effects in rectangular composite strips under tension are discussed. The objective of the study was to investigate the effect of various parameters, including reinforcement material, fiber orientation and the structure of the reinforcement, on the various quantities which are observed in the vicinity of free edges in multidirectionally reinforced laminates. Of particular interest was the confirmation of theoretical results related to differences in response of graphite- and boron-reinforced laminates. Experiments consisted of moiré measurements of surface-displacement patterns which were compared with theoretical predictions, and examination of failure levels. The experiments were carried out on AVCO 5505 boron and Whitaker 5206 MODMOR II graphite-reinforced angle-ply laminates in which both stacking sequence and fiber orientation were varied parametrically. Moiré techniques were developed which allowed observation of displacements on both the wide surface and along the narrow edge of 1 in.-wide × 16-ply-thick (.085 in.-.105 in.) laminates. 相似文献
146.
A validated computer simulation model has been developed for the analysis of colinear spheres in a heated gas stream. Using the Galerkin finite element method, the steady-state Navier-Stokes and heat transfer equations have been solved describing laminar axisymmetric thermal flow past closely-spaced monodisperse spheres with fluid injection. Of interest are the coupled nonlinear interaction effects on the temperature fields and ultimately on the Nusselt number of each sphere for different free stream Reynolds numbers (20 ≤Re ≤ 200) and intersphere distances (1.5 ≤d ij ≤ 6.0) in the presence of surface blowing (0 ≤v b < 0.1). Fluid injection (i.e. blowing) and associated wake effects generate lower average heat transfer coefficients for each interacting sphere when the Reynolds number increases (Re>100). Heat transfer is also reduced at small spacings especially for the second and third sphere. A Nusselt number correlation for each interacting (porous) sphere has been developed based on computer experiments. 相似文献
147.
Lee Y Liu D Seoung D Liu Z Kao CC Vogt T 《Journal of the American Chemical Society》2011,133(6):1674-1677
When the small-pore zeolite natrolite is compressed at ca. 1.5 GPa and heated to ca. 110 °C in the presence of CO(2), the unit cell volume of natrolite expands by 6.8% and ca. 12 wt % of CO(2) is contained in the expanded elliptical channels. This CO(2) insertion into natrolite is found to be reversible upon pressure release. 相似文献
148.
Zi-Cai Li Ming-Gong LeeJohn Y. Chiang Ya Ping Liu 《Journal of Computational and Applied Mathematics》2011,235(15):4350-4367
In this paper, the Trefftz method of fundamental solution (FS), called the method of fundamental solution (MFS), is used for biharmonic equations. The bounds of errors are derived for the MFS with Almansi’s fundamental solutions (denoted as the MAFS) in bounded simply connected domains. The exponential and polynomial convergence rates are obtained from highly and finitely smooth solutions, respectively. The stability analysis of the MAFS is also made for circular domains. Numerical experiments are carried out for both smooth and singularity problems. The numerical results coincide with the theoretical analysis made. When the particular solutions satisfying the biharmonic equation can be found, the method of particular solutions (MPS) is always superior to the MFS and the MAFS, based on numerical examples. However, if such singular particular solutions near the singular points do not exist, the local refinement of collocation nodes and the greedy adaptive techniques can be used for seeking better source points. Based on the computed results, the MFS using the greedy adaptive techniques may provide more accurate solutions for singularity problems. Moreover, the numerical solutions by the MAFS with Almansi’s FS are slightly better in accuracy and stability than those by the traditional MFS. Hence, the MAFS with the AFS is recommended for biharmonic equations due to its simplicity. 相似文献
149.
Lin PC Chen HY Chen PY Chiang MH Chiang MY Kuo TS Hsu SC 《Inorganic chemistry》2011,50(21):10825-10834
The decarbonylation reaction of ferric carbonyl dicationic [Cp(2)Fe(2)(μ-SEt)(2)(CO)(2)](BF(4))(2) [1(BF(4))(2)] carried out in refluxing acetonitrile affords a binuclear iron-sulfur core complex [Cp(2)Fe(2)(μ-SEt)(2)(CH(3)CN)(2)](BF(4))(2) [2(BF(4))(2)] containing two acetonitrile coordinated ligands. The treatment of 2(BF(4))(2) with 2 equiv of the 1,4-diisocyanobenzene (1,4-CNC(6)H(4)NC) results in the formation of the diisocyanide complex [Cp(2)Fe(2)(μ-SEt)(2)(1,4-CNC(6)H(4)NC)(2)](BF(4))(2) [3(BF(4))(2)]. The rectangular tetranuclear iron thiolate aryldiisocyanide metallocyclophane complex [Cp(4)Fe(4)(μ-SEt)(4)(μ-1,4-CNC(6)H(4)NC)(2)](BF(4))(4) [4(BF(4))(4)] has been synthesized by a self-assembly reaction between equimolar amounts of 2(BF(4))(2) and 1,4-diisocyanobenzene or by a stepwise route involving mixing of a 1:1 molar ratio of complexes 2(BF(4))(2) and 3(BF(4))(2). Chemical reduction of 4(BF(4))(4) by KC(8) was observed to produce the reduction product 4(BF(4))(2). The spectroscopic and electrochemical properties of the iron-sulfur core complexes 1(PF(6))(2), 3(BF(4))(2), 4(BF(4))(4), and 4(BF(4))(2) were determined. Finally, differences between the redox control cavities of rectangular tetranuclear iron thiolate aryldiisocyanide complexes are revealed by a comparison of the X-ray crystallographically determined structures of complexes 4(BF(4))(4) and 4(BF(4))(2). 相似文献
150.
Ding S Luan D Boey FY Chen JS Lou XW 《Chemical communications (Cambridge, England)》2011,47(25):7155-7157
We demonstrate a new hydrothermal method to directly grow SnO(2) nanosheets on a graphene oxide support that is subsequently reduced to graphene. This unique SnO(2)/graphene hybrid structure exhibits enhanced lithium storage properties with high reversible capacities and good cycling performance. 相似文献