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91.
We propose an extended Hubbard model on a 2D kagome lattice with an additional ring exchange term. The particles can be either bosons or spinless fermions. We analyze the model at the special filling fraction 1/6, where it is closely related to the quantum dimer model. We show how to arrive at an exactly soluble point whose ground state is the "d-isotopy" transition point into a stable phase with a certain type of non-Abelian topological order. Near the "special" values, d=2cos(pi/(k+2), this topological phase has anyonic excitations closely related to SU(2) Chern-Simons theory at level k. 相似文献
92.
We present the first numerical computation of the neutral fermion gap, Δ(F), in the ν=5/2 quantum Hall state, which is analogous to the energy gap for a Bogoliubov-de Gennes quasiparticle in a superconductor. We find Δ(F)≈0.027e(2)/ε?(0), comparable to the charge gap. We also deduce an effective Fermi velocity v(F) for neutral fermions from the low-energy spectra for odd numbers of electrons, and thereby obtain a correlation length ξ(F)=v(F)/Δ(F)≈1.3?(0). We comment on implications for experiments, topological quantum information processing, and electronic mechanisms of superconductivity. 相似文献
93.
We study the effects of dissipation on a disordered quantum phase transition with O(N) order-parameter symmetry by applying a strong-disorder renormalization group to the Landau-Ginzburg-Wilson field theory of the problem. We find that Ohmic dissipation results in a nonperturbative infinite-randomness critical point with unconventional activated dynamical scaling while super-Ohmic damping leads to conventional behavior. We discuss applications to the superconductor-metal transition in nanowires and to the Hertz theory of the itinerant antiferromagnetic transition. 相似文献
94.
A. Ramazani-Moghaddam-Arani H. R. Amir-Ahmadi A. Biegun M. Eslami-Kalantari I. Gašparić L. Joulaeizadeh N. Kalantar-Nayestanaki St. Kistryn A. Kozela H. Mardanpour J. G. Messchendorp H. Moeini S. V. Shende E. Stephan R. Sworst 《Few-Body Systems》2008,44(1-4):27-29
Differential cross sections and vector analyzing powers for the p + d → p + d reaction have been measured using a new experimental setup (BINA) at KVI. The data are compared with published results and are found to be significantly different. 相似文献
95.
The difluorinated analogues of 3-deoxy-d-arabino-heptulosonic acid (DAH) 12, 24 and its enantiomer have been synthesised from d- and l-erythrose via a Reformatsky reaction which gave a mixture of diastereoiosmers in favour of the anti isomer. 相似文献
96.
97.
Transition metal [M = VO (IV) and/or Cu (II)] complexes with Schiff base ligand, (Z)‐2‐((2‐hydroxybenzylideneamino)phenol (H2L) have been entrapped in the super cages of zeolite‐Y by Flexible Ligand Method. Synthesized materials have been characterized by preferential physico‐chemical techniques such as inductively coupled plasma optical emission spectroscopy (ICP‐OES), elemental analyses (CHN), fourier transmission infrared spectroscopy (FTIR), electronic and UV‐reflectance spectra, Brunauer–Emmett–Teller (BET) surface area measurements, scanning electron micrographs (SEMs), X‐ray diffraction patterns (XRD) and thermogravimetric analysis (TGA). The catalytic competence of zeolite‐Y entrapped transition metal complexes was examined in Baeyer‐Villiger (BV) oxidation of cyclopentanone using 30% H2O2 as an oxidant beside neat complexes to check the aptitude of heterogeneous catalysis over the homogeneous system. The effect of experimental variables such as mole ratio of substrate to an oxidant, amount of catalyst, reaction time, varying oxidants and solvents on the conversion of cyclopentanone was also tested. Under the optimized reaction conditions, one of the zeolite‐Y entrapped transition metal complex viz. [VO(L)H2O]‐Y [where L = (Z)‐2‐((2‐hydroxybenzylideneamino)phenol] was found to be a potential contender by providing 80.22% conversion of cyclopentanone (TON: 10479.42), and the selectivity towards δ‐valerolactone was 83.56%. 相似文献
98.
Amol S. Nipate Chetan K. Jadhav Asha V. Chate Kanchan S. Taur Charansingh H. Gill 《Journal of heterocyclic chemistry》2020,57(2):820-829
An eco-friendly multicomponent synthesis of substituted imidazole derivatives catalyzed by β-cyclodextrin (β-CD) was scrutinized for the first time via a one-pot three-compound reaction of aldehyde, isatin, and ammonium acetate in H2O–EtOH at 80°C. β-CD is a supramolecule, highly efficient, biodegradable, and recyclable catalyst used to produce high yields of desired 1,8-dihydroimidazo[2,3-b]indoles. The developed protocol contains number of advantages like nontoxic, inexpensive catalyst; green reaction condition; easily available starting material; shorter reaction time; and good yields. 相似文献
99.
Asha V. Chate Ankita S. Kulkarni Chetan K. Jadhav Amol S. Nipte Girabala M. Bondle 《Journal of heterocyclic chemistry》2020,57(5):2184-2193
In this article, we have developed a straightforward, easy and exceedingly competent approach for the synthesis of 5-phenyl-5,6-dihydropyrido[2,3-d]pyrimidine-2,4,7(1H,3H,8H)-triones obtain in superior yields in a sole reaction pace with an air and humidity steady catalyst in water as a green solvent at 100°C. The present procedure paves the approach for the synthesis of biologically fascinating molecular frameworks and has reward in conditions of little catalyst loading with palpable ambiguous and straightforward-to-do reaction circumstances with easy purification process. The used β-cyclodextrin catalyst was recuperated and repeated several times devoid of noteworthy loss of catalytic activity, which is a crucial parameter of green synthesis. 相似文献
100.