STUDIES OF ACTIVE DIACYLAMIDES OF BENZOTRIAZOLE Ⅰ. SYNTHESIS OF POLYAMIDES AND POLYESTERS*

Two new routes to polyamides and polyesters were established, based on the polycondensationof new typical active diacylamide of benzotriazole, such as 1, 1'-(isophthaloyl) bisbenzotriazole(IPBBT) and 1, 1'-(terephthaloyl)bisbenzotriazole (PBBT) with diamines, diols and diphenol underdifferent mild conditions. The N-acylation of polycondensation occurred at room temperaturewithout added catalyst, the O-acylation of polycondensation had to complete in the presence oftriethylamine as a catalyst at 60℃.     

Facile fabrication of pH-sensitive core-shell nanoparticles based on HEC and PMAA via template polymerization

Taking advantage of the specific hydrogen bonding interactions between the components, core-shell nanoparticles based on poly(methacrylic acid) (PMAA) and hydroxyethyl cellulose (HEC) can be efficiently prepared via facile one-step polymerization of MAA on HEC template in water. Various techniques were used to characterize in detail the sizes, morphology, and structures of the nanoparticles, as well as the interactions between the components. The core-shell structures of the nanoparticles were confirmed by TEM observation. Dynamic light scattering and fluorescence spectrometry were used to monitor the polymerization process, which indicates a size decrease and a hydrophobicity increase of the nanoparticles. A mechanism was proposed to explain the formation of core-shell nanoparticles during the template polymerization. The obtained nanoparticles are stable against urea, salt, temperature and in the storage; meanwhile, they exhibit pH-response: the volume of the nanoparticles increased more than six times as pH value of the medium increased from 2.8 to 3.7.     

Studies of some bioactive N-p-methacrylamidobenzoic esters

Preparations of four typical bioactive esters of N-p-methacrylamidobenzoic monomers and their reactive polymers as immobilized trypsin carriers are described. N-p-methacrylamidobenzoic active ester monomers containing ? COONB, ? COOSu, ? COOObt, or ? COOBT group can react with an aliphatic amine such as benzylamine at room temperature to give an identical product, N-benzyl-p-methacrylamidobenzamide. However, only monomers with ? COOObt or ? COOBT group can also react with an aromatic amine such as aniline to give N-phenyl-p-methacrylamidobenzamide. These monmoers polymerized readily in solution with azobisisobutyronitrile as free-radical initiator; the polymers were used to immobilize trypsin. Among the four different active esters for the immobilization of trypsin, thE HONB and HOSu active ester showed rather higher bioactivities than the HOObt or HOBT active ester under the same conditions. Both P(MABONB)-trypsin and P(MABOSu)-trypsin matrices possess higher biological activities by about four or three times that of P(MABOObt)-trypsin or P(MABOBT)-trypsin matrices, respectively. It is proposed that these rather high bioactivities may be attributed to the “specific” aminolysis of reactive polymer with ? COONB or ? COOSu active ester group by aliphatic amino substituents.     

多机械臂搬运同一物体的协调动态载荷分配

针对多机械臂共同搬运同一物体形成闭运动链的协调系统,研究了多机械臂协调动态载荷分配存在冗余情况下的实时性分配方法文中提出了“应集中惯性质量棒”的概念,进而根据各机械臂的承载能力,采用线性加权的方法发展了一种操作物体质心处零内力的载荷分配原则。最后给出了系统载荷分配的解析表达式,有效地解决了多机械臂搬运同一物体时其动态载荷分配的实时性问题。     

Propagating characters of Gaussian laser beam in plasmas with non-homogeneous radial temperature distribution

We investigate the propagation regimes of laser beam in plasmas with radial distribution of electron temperature, characterized by ratio parameter of radial Gaussian distribution. By following the WKB method and paraxial approximation, the propagation equations of laser beam are derived and discussed for two nonlinearity mechanisms respectively. Both the critical curves for different ratio parameters are plotted, and it is proved that the self-focusing or self-trapping mode could be realized only when the ratio parameter excesses 1. The variations of laser beam-width are calculated, which indicates the feasibly effective modification of propagation characters by radial distribution of electron temperature.     

多普勒效应测速实验仪的改进

对多普勒效应实验仪的机械组成部分及微处理程序进行改进,使之能够测量运动方向不在连线RS[1]（超声发射器和接收器在同一时刻的连线）上的速度。这使得实验更加贴近实际应用,有助加深学生对多普勒效应理论的理解,充分认识理论转化为实际应用的过程及其重要性。     

时间相关外场中量子系统时间演化的辛格式

对显含时间的可分线性哈密顿系统构造了2阶模方守恒-辛格式和显式辛格式,并计算了1维有限宽无限深势阱中的电子与模拟激光场的相互作用,结果与理论分析一致。为数值研究时间相关外场中的量子系统,特别是强激光与原子相互作用提供了合理和有效的方法。     

Using Collisional Electron Spectroscopy to Detect Gas Impurities in an Open Environment: CH4-Containing Mixtures

The collisional electron spectroscopy method for analyzing and determining gaseous impurities was further developed to realize the operation in an open environment. In addition, the method not only facilitates the registration of the impurity components, but also the reactive radicals generated from the discharge reaction. The sandwich-like discharge structure was used to generate a stable, non-local, negative glow equipotential plasma in an open environment, and the I–V characteristic curve of the plasma was collected using an additional sensor electrode. The collisional electron spectroscopy was obtained from the first derivative of the probe current I with respect to the probe potential V by adding a diffusion function to correct it. In addition, our experiment verifies the reliability of the sink theory.     

A Way to Prepare Core‐Shell Biocompatible Polymeric Nano‐Particles from Gelatin and Acrylic Acid

Narrowly distributed core‐shell nano‐particles at relatively high concentration (30 mg/mL) were prepared via in situ polymerization of acrylic acid in an aqueous solution of biocompatible gelatin. These polymeric nano‐particles, in aqueous solution, had cores mainly comprised of an insoluble inter‐polymer complex of poly(acrylic acid, PAA) and gelatin and shells comprised of soluble gelatin (denoted as gelatin/PAA nano‐particles). Dynamic light scattering and electrophoretic light scattering techniques were used to trace the in situ polymerization process. The structure of the gelatin/PAA nano‐particle was further locked‐in via shell crosslinking; i.e., the reaction between glutaraldehyde and gelatin. Scanning force microscopy (SFM) was used to observe the morphologies of the particles before and after cross‐linking. Furthermore, the pH responsive behaviors of the gelatin/PAA nano‐particles before and after shell crosslinking were studied.     

Synthesis and polymerization of optically active L-[α-(N-p-acryloxybenzoyl)alanine ethyl esters]

New optically active monomers L -[α-(N-p-acryloxybenzoyl)alanine ethyl esters] (I) and their polymers were synthesized. The title monomers (I) were prepared by the reaction of 1-p-acryloxybenzoyloxy-4-chlorobenzotriazoles (II) with L -alanine ethyl ester hydrochloride, by aminolysis of the active monoester. The new typical active ester (II) was synthesized by the N-hydroxy compound active-ester methods in excellent yield. Before the synthesis of the optically active monomers was carried out, a model study of the aminolysis of the two active esters was performed.