Spectroscopic evidence of the multiple- site structure of Eu(3+) ions incorporated in ZnO nanocrystals

Hexagonal Eu(3+):ZnO nanocrystals were synthesized by a modified solgel method. By means of the site-selective spectroscopy at 10 K, two kinds of luminescence sites of Eu(3+) are identified. One site exhibits a long lifetime of (5)D(0) and sharp emission and excitation peaks, which are ascribed to the inner lattice site with an ordered crystalline environment. The other site associated with the distorted lattice sites near the surface shows a relatively short lifetime of (5)D(0) and significantly broadened fluorescence lines. The energy transfer from the nanocrystal host to Eu(3+) confirms that Eu(3+) ions can, to some extent, be incorporated into the ZnO nanocrystal.     

密度矩阵重正化群的异构并行优化

密度矩阵重正化群方法（DMRG）在求解一维强关联格点模型的基态时可以获得较高的精度,在应用于二维或准二维问题时,要达到类似的精度通常需要较大的计算量与存储空间.本文提出一种新的DMRG异构并行策略,可以同时发挥计算机中央处理器（CPU）和图形处理器（GPU）的计算性能.针对最耗时的哈密顿量对角化部分,实现了数据的分布式存储,并且给出了CPU和GPU之间的负载平衡策略.以费米Hubbard模型为例,测试了异构并行程序在不同DMRG保留状态数下的运行表现,并给出了相应的性能基准.应用于4腿梯子时,观测到了高温超导中常见的电荷密度条纹,此时保留状态数达到10⁴,使用的GPU显存小于12 GB.     

Physical properties of a high molecular weight hydroxyl-terminated polydimethylsiloxane modified castor oil based polyurethane/epoxy interpenetrating polymer network composites

A series of polyurethane (PU)/epoxy resin (EP) graft interpenetrating polymer network (IPN) composites modified by a high molecular weight hydroxyl-terminated polydimethylsiloxane (HTPDMS) were prepared. The effects of HTPDMS content on the phase structure, damping properties and the glass transition temperature (Tg) of the HTPDMS-modified PU/EP IPN composites were studied by scanning electron microscopy (SEM) and dynamic mechanical analysis (DMA). Thermogravimetric analysis (TGA) showed that the thermal decomposition temperature of the composites increased with the increase of HTPDMS content. The tensile strength and impact strength of the IPN composites were also significantly improved, especially when the HTPDMS content was 10%. The modified IPN composites were expected to be used as structural damping materials in the future.     

Non-uniformity correction algorithm for IRFPA based on motion controllable micro-scanning and perimeter diaphragm strips

Non-uniformity correction is the key issue for the image quality improvement of infrared focal panel array (IRFPA) imaging. A non-uniformity correction (NUC) algorithm for IRFPA based on motion controllable micro-scanning platform and perimeter diaphragm strips is presented. We initially execute one-point calibration to the perimeter detectors, then based on controllable motion of adjacent frames, a special algebraic algorithm is proposed to transport the calibration of the perimeter detectors to those interior un-corrected ones. In this way, the bias parameter of the whole field of view (FOV) is calculated. The algorithm can be easily combined with sub-pixel imaging, thereby improving the quality of thermal imaging system (image spatial resolution and uniformity). All calculations are algebraic, with a low computation load. The algorithm can realize adaptive one point calibration without covering the central FOV rapidly. Experiments on simulated infrared data demonstrate that this algorithm requires only dozens of frames to obtain high quality corrections.     

The magnetic properties of one-dimensional spin-1 ferromagnetic Heisenberg model in a magnetic field within Callen approximation

The effect of magnetic field h on the magnetic properties of the one-dimensional spin-1 ferromagnetic Heisenberg model is studied by the double-time Green’s function method. The magnetization and susceptibility are obtained within the Callen approximation. The zero-field susceptibility is as a decreasing function of the temperature T. The magnetization m increases in the whole field region, but the susceptibility maximum χ(T_m) decreases. The position T_m of the susceptibility maximum is both solved analytically and fits well to be a power law T_m∼h^γ at low fields and to be linear increasing at high fields. The height χ(T_m) decreases as a power law χ(T_m)∼h^−β with h increasing. The exponents (γ,β) obtained in our results agree with the other theoretical results. Our results are roughly in agreement with the results obtained in the experiment of Ni(OH)(NO₃)H₂O.     

新型交叉孔道式平板热管的性能研究

提出了一种设计交叉孔道式平板热管的新思路,按照这种方法设计加工的新型结构的平板热管均热器具有较强的轴向和径向导热能力,能明显减小导热热阻;特殊的孔道结构增强了毛细作用力,能有效强化相变换热。实验测试了不同热流密度和不同充液率下该热管正常工作时的稳态温度分布,给出了不同充液率和不同热流下的热阻,得到了热管的最佳充液率,证...     

Study of diode-pumped Yb:YAG disk lasers at low temperature

A Yb:YAG disk laser with V-shaped stable resonator and active-mirror configuration,end-pumped by a 940-nm InGaAs laser diode array,is demonstrated.Performances and optimization of the disk laser at low temperature over a range of 130-200 K are investigated theoretically and experimentally.Laser output energy of 1.46 J/pulse operating at 10-Hz repetition rate is obtained with the optimum output coupler transmission of 30%,and the corresponding optical-to-optical efficiency is 48.7%.     

Diameter-dependent thermal-oxidative stability of single-walled carbon nanotubes synthesized by a floating catalytic chemical vapor deposition method

In this paper, purified single-walled carbon naotubes (SWCNTs) with three different diameters were synthesized using a floating catalytic chemical vapor deposition method with ethanol as carbon feedstock, ferrocene as catalyst, and thiophene as growth promoter. The thermal-oxidative stability of different-diameter SWCNTs was studied by using thermal analysis (TG, DTA), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) analysis. The results indicate that small diameter SWCNTs (∼1 nm) are less stable and burn at lower temperature (610 °C), however, the larger diameter SWCNTs (∼5 nm) survive after burning at higher temperature (685 °C), the oxidation rate varies inversely with the tube diameter of SWCNTs, which may be concluded that the higher oxidation-resistant temperature of larger diameter SWCNTs can be attributed to the lower curvature-induced strain by rolling the planar graphene sheet for the larger diameter, so small tubes will become thermodynamically unstable.     

Observation of size-dependent thermalization in CdSe nanocrystals using time-resolved photoluminescence spectroscopy

We report heat dissipation times in semiconductor nanocrystals of CdSe. Specifically, a previously unresolved, subnanosecond decay component in the low-temperature photoluminescence decay dynamics exhibits longer decay lifetimes (tens to hundreds of picoseconds) for larger nanocrystals as well as a size-independent, ~25-meV spectral shift. We attribute the fast relaxation to transient phonon-mediated relaxation arising from nonequilibrium acoustic phonons. Following acoustic phonon dissipation, the dark exciton state recombines more slowly via LO-phonon assistance resulting in the observed spectral shift. The measured relaxation time scales agree with classical calculations of thermal diffusion, indicating that interfacial thermal conductivity does not limit thermal transport in these semiconductor nanocrystal dispersions.