全文获取类型
收费全文 | 476篇 |
免费 | 15篇 |
国内免费 | 4篇 |
专业分类
化学 | 324篇 |
晶体学 | 1篇 |
力学 | 12篇 |
数学 | 37篇 |
物理学 | 121篇 |
出版年
2022年 | 4篇 |
2021年 | 8篇 |
2020年 | 8篇 |
2019年 | 6篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 11篇 |
2015年 | 12篇 |
2014年 | 8篇 |
2013年 | 23篇 |
2012年 | 18篇 |
2011年 | 32篇 |
2010年 | 21篇 |
2009年 | 21篇 |
2008年 | 35篇 |
2007年 | 21篇 |
2006年 | 25篇 |
2005年 | 14篇 |
2004年 | 16篇 |
2003年 | 15篇 |
2002年 | 11篇 |
2001年 | 10篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1997年 | 5篇 |
1996年 | 6篇 |
1995年 | 9篇 |
1994年 | 10篇 |
1993年 | 12篇 |
1992年 | 14篇 |
1991年 | 9篇 |
1990年 | 4篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 7篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1975年 | 10篇 |
1974年 | 2篇 |
1973年 | 5篇 |
1971年 | 3篇 |
1968年 | 3篇 |
排序方式: 共有495条查询结果,搜索用时 0 毫秒
471.
R.E. Dietz L.R. Walker F.S.L. Hsu W.H. Haemmerle B. Vis C.K. Chau H. Weinstock 《Solid State Communications》1974,15(7):1185-1188
Specific heat measurements have been carried out in the short range spin correlated phase of the linear antiferromagnet (CH3)4NMnCl3 (TMMC) in order to ascertain effects due to dipolar interactions. The specific heat is linear in T at low temperatures as expected from spin wave theory. The measured coefficient is about one-third the isotropic spin-wave value, but is in better agreement with a prediction from anisotropic spin-wave theory (one-half the isotropic value). 相似文献
472.
Ling-Lie Chau 《Physics Reports》1983,95(1):1-94
The status of the quark mixing in weak interaction is reviewed. The 3×3 quark mixing matrix for the three left-handed doublet model is analyzed using various experimental information involving strange, charmed, and b-flavored particles. Its interplay with nonleptonic decays, implication on neutral particle-antiparticle mixing and CP violation in heavy quark systems, and the possible origin of the quark mixing from quark mass matrix are discussed. Finally we briefly review the status of alternative sources for CP violation, and alternative models to the three left-hand quark doublet model. 相似文献
473.
474.
Geometry optimization and harmonic vibrational frequency calculations have been carried out on the low-lying singlet and triplet electronic states of the antimony dioxide anion (SbO2-) employing a variety of ab initio methods. Both large-core and small-core relativistic effective core potentials were used for Sb in these calculations, together with valence basis sets of up to augmented correlation-consistent polarized-valence quintuple-zeta (aug-cc-pV5Z) quality. The ground electronic state of SbO2- is determined to be the X (1)A1 state, with the a (3)B1 state, calculated to be approximately 48 kcal mole(-1) (2.1 eV) higher in energy. Further calculations were performed on the X (2)A1, A (2)B2, and B (2)A2 states of SbO2 with the aim to simulating the photodetachment spectrum of SbO(2) (-). Potential energy functions (PEFs) of the X (1)A1 state of SbO2- and the X (2)A1, A (2)B2, and B (2)A2 states of SbO2 were computed at the complete-active-space self-consistent-field multireference internally contracted configuration interaction level with basis sets of augmented correlation-consistent polarized valence quadruple-zeta quality. Anharmonic vibrational wave functions obtained from these PEFs were used to compute Franck-Condon factors between the X (1)A1 state of SbO2- and the X (2)A1, A (2)B2, and B (2)A2 states of SbO2, which were then used to simulate the photodetachment spectrum of SbO2-, which is yet to be recorded experimentally. 相似文献
475.
We investigated numerically the scattering cross sections and near-field intensities of solid-silver and silver-shell (shell
thickness d = 10 nm) nanodimers that interact with incident plane wave by the use of finite-element method with three-dimensional models.
Results show that the silver-shell cases exhibit tunable surface plasmon resonances and its rotational effects can induce
more surface plasmons in a wider range of wavelength that are not observed for the solid-silver cases with the same volume
(1,046,666 nm3). 相似文献
476.
Tricyclic core skeleton of manzamine A was constructed stereoselectively from the fused nitrogen-containing bicyclic enone 3 via a novel and efficient strategy including sequential stereoselective Diels-Alder reaction, Curtius rearrangement, and intramolecular lactam formation reaction. 相似文献
477.
Pieters S Tistaert C Alaerts G Bodzioch K Mangelings D Dejaegher B Rivière C Hoai NN Van MC Quetin-Leclerq J Vander Heyden Y 《Talanta》2011,83(4):1188-1197
Because of its eminent high resolution potential and minimal solvent consumption, pressurized capillary electrochromatography (pCEC) may offer an interesting alternative to HPLC for screening applications that need to resolve complex samples. In this paper, its potential was assessed in a screening of plant extracts from Mallotus species to indicate compounds with possible antioxidant activities by means of a PLS model built from their pCEC fingerprints. The main aim of this research was to find out whether pCEC can have an added value for this application. To get a complete overview of the techniques potential for this application, it was also assessed whether the technique can meet the requirements in terms of precision, sensitivity and column robustness. Encountered benefits and downsides were reported. Fingerprints with satisfactory sensitivity and precision could be obtained by concentrating the sample 5-fold and using optimized rinsing procedures, respectively. From the generated pCEC fingerprints of 39 Mallotus samples and their respective DPPH radical scavenging activity test results, a three-component PLS model was being built. The model proved good predictive abilities and easily allowed the indication of possible antioxidant compounds in the fingerprints. Despite its much higher peak capacity, the performance of pCEC to fingerprint the majority of the Mallotus extracts did not surpass that of a custom HPLC method. This was also reflected in its comparable power to indicate possible antioxidant compounds in the fingerprints after modeling. Because of its low detection sensitivity and modest column robustness, the benefit of the lower solvent consumption was partly paid-off by the current need for more system maintenance, also limiting the sample throughput. For the considered screening application, pCEC may suit as a viable but no preferred alternative technique. 相似文献
478.
We present a simple method based on the Cu2+ induced unfolding of G‐quadruplex (G4) of human telomere sequence d[AG3(T2AG3)3] to screen a number of 3,6‐bis(1‐methyl‐4‐vinylpyridinium)carbazole diiodide (BMVC) analogues for better G4 stabilizers. Using circular dichroism (CD), the screening results suggest that the tri‐cations of 9‐substituted BMVC derivatives are better G4 stabilizers than the bi‐cations of BMVC. In addition, 3,6‐bis(1‐methyl‐4‐vinylpyrazinium)carbazole diiodide (BMVC4) is likely a better core molecule than BMVC for G4 stabilizers. 相似文献
479.
Le TT Chau NT Nguyen TT Brien J Thai TT Nourry A Castanet AS Nguyen KP Mortier J 《The Journal of organic chemistry》2011,76(2):601-608
The metalation of 4-hydroxy-6,7-dimethoxy-8-methyl-2-naphthoic acid (8) affording trianion 6 is presented and applied to the regioselective efficient construction of a series of 5,5'-didesisopropyl-5,5'-dialkylapogossypol derivatives 3 that are potent pan-active inhibitors of antiapoptotic Bcl-2 family proteins. 相似文献
480.
Jingqin Chen Adam C. Sedgwick Sajal Sen Yaguang Ren Qinchao Sun Calvin Chau Jonathan F. Arambula Tridib Sarma Liang Song Jonathan L. Sessler Chengbo Liu 《Chemical science》2021,12(29):9916
Photoacoustic imaging (PAI) relies on the use of contrast agents with high molar absorptivity in the NIR-I/NIR-II region. Expanded porphyrins, synthetic analogues of natural tetrapyrrolic pigments (e.g. heme and chlorophyll), constitute as potentially attractive platforms due to their NIR-II absorptivity and their ability to respond to stimuli. Here, we evaluate two expanded porphyrins, naphthorosarin (1) and octaphyrin (4), as stimuli responsive PA contrast agents for functional PAI. Both undergo proton-coupled electron transfer to produce species that absorb well in the NIR-II region. Octaphyrin (4) was successfully encapsulated into 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-poly(ethylene glycol) (DSPE-PEG2000) nanoparticles to afford OctaNPs. In combination with PAI, OctaNPs allowed changes in the acidic environment of the stomach to be visualized and cancerous versus healthy tissues to be discriminated.In this study, two expanded porphyrins, octaphyrin and naphthorosarin were evaluated as potential PA agents. The nanoparticle encapsulation of octaphyrin successfully enabled the visualization of acidic environments and the discrimination between cancerous and healthy tissues. 相似文献