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21.
Soo-Jin Park George G. Chase Kwang-Un Jeong Hak Yong Kim 《Journal of Sol-Gel Science and Technology》2010,54(2):188-194
Flexible mats of titania fibers are prepared by calcination of electrospun polyvinylpyrrolidone fibers containing titanium
isopropoxide precursor. Structural investigation of the calcinated nanofibers by X-ray diffraction (XRD) and electron diffraction
(ED) combined with the morphologies by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) show
the titania fibers, with an average diameter of 180 nm, were comprised of anatase and rutile crystals. The mechanical, chemical
and thermal properties of the titania fiber mats are further investigated by the techniques of Instron mechanical tester,
thermogravimetric analyzer (TGA), and Fourier transform infrared spectroscopy (FT-IR). The titania fiber mat prepared in this
method exhibited a significant flexibility with 461 MPa Young’s modulus. 相似文献
22.
Two constitutive relations have been determined from test results that characterize, respectively, the uniaxial and photomechanical behavior of a polyester-styrene copolymer for strain rates from 10?5 to 3×103 in./in./s and strains up to 40 percent. The high-strain-rate data were obtained by means of a split-Hopkinson-bar apparatus. Intermediate-strain-rate tests, performed with the aid of a drop tower, were reported in an earlier paper. Quasi-static experiments were conducted on a standard testing machine. A nonlinear, four-parameter, elastic-viscoplastic model was constructed which describes the mechanical behavior. The parameters were determined by a least-mean-squares curve-fitting procedure. The viscoplastic parameters were found to obey a power law in strain rate. The photomechanical model was found to be linear with strain well into the plastic-deformation region, while the slope of the strain-birefringence curve for each strain rate also varied by strain rate to a power. 相似文献
23.
Lone AM Bachovchin DA Westwood DB Speers AE Spicer TP Fernandez-Vega V Chase P Hodder PS Rosen H Cravatt BF Saghatelian A 《Journal of the American Chemical Society》2011,133(30):11665-11674
Peptidases play vital roles in physiology through the biosynthesis, degradation, and regulation of peptides. Prolyl endopeptidase-like (PREPL) is a newly described member of the prolyl peptidase family, with significant homology to mammalian prolyl endopeptidase and the bacterial peptidase oligopeptidase B. The biochemistry and biology of PREPL are of fundamental interest due to this enzyme's homology to the biomedically important prolyl peptidases and its localization in the central nervous system. Furthermore, genetic studies of patients suffering from hypotonia-cystinuria syndrome (HCS) have revealed a deletion of a portion of the genome that includes the PREPL gene. HCS symptoms thought to be caused by lack of PREPL include neuromuscular and mild cognitive deficits. A number of complementary approaches, ranging from biochemistry to genetics, will be required to understand the biochemical, cellular, physiological, and pathological mechanisms regulated by PREPL. We are particularly interested in investigating physiological substrates and pathways controlled by PREPL. Here, we use a fluorescence polarization activity-based protein profiling (fluopol-ABPP) assay to discover selective small-molecule inhibitors of PREPL. Fluopol-ABPP is a substrate-free approach that is ideally suited for studying serine hydrolases for which no substrates are known, such as PREPL. After screening over 300,000 compounds using fluopol-ABPP, we employed a number of secondary assays to confirm assay hits and characterize a group of 3-oxo-1-phenyl-2,3,5,6,7,8-hexahydroisoquinoline-4-carbonitrile and 1-alkyl-3-oxo-3,5,6,7-tetrahydro-2H-cyclopenta[c]pyridine-4-carbonitrile PREPL inhibitors that are able to block PREPL activity in cells. Moreover, when administered to mice, 1-isobutyl-3-oxo-3,5,6,7-tetrahydro-2H-cyclopenta[c]pyridine-4-carbonitrile distributes to the brain, indicating that it may be useful for in vivo studies. The application of fluopol-ABPP has led to the first reported PREPL inhibitors, and these inhibitors will be of great value in studying the biochemistry of PREPL and in eventually understanding the link between PREPL and HCS. 相似文献
24.
Six structural isomers of a tetrakis(arylethynyl)benzene (TAEB) chromophore functionalized with dibutylamine and BODIPY moieties as the corresponding donor and acceptor units were prepared. To evaluate the effectiveness of the donor group, two TAEB molecules and three structurally related bis(arylethynyl)benzene (BAEB) isomers containing only acceptors were also synthesized. The electronic absorption and emission spectra of each series were examined. Additionally, computational studies were employed to corroborate the relative energy levels and gaps present in each series. 相似文献
25.
W. Hiltner H. A. Freye R. J. Fosbinder J. W. Schoonover M. Kilpatrick E. F. Chase L. C. Riesch A. Janke F. Sekera G. F. Davidson J. O. Burton H. Matheson S. F. Acree G. Haugaard F. L. Vodret F. Hovorka W. C. Dearing T. Mikawa E. Newbery A. Itano S. Arakawa T. R. Ball W. B. Schmidt K. S. Bergstresser E. Vellinger A. E. Lorch F. Lux W. von Brehmer M. Déribéré A. F. Peters und A. Osol 《Fresenius' Journal of Analytical Chemistry》1935,103(7-8):285-292
Ohne Zusammenfassung 相似文献
26.
M.K. Chase 《Nuclear Physics B》1982,203(3):434-444
We prove that the S-matrix of pure quantum gravity (i.e. no matter) at two-loops has no leading (double-pole) ultraviolet divergences in dimensional regularization. 相似文献
27.
The width of the biexciton two-photon resonance in CuCl, as measured with weak probe beams, shows a marked broadening if a high density of biexcitons is injected with an intense pump beam. These results are attributed to collisions between excitonic particles. 相似文献
28.
N. Peyghambarian Dror Sarid H.M. Gibbs L.L. Chase A. Mysyrowicz 《Optics Communications》1984,49(2):125-128
It is shown that the cage model of the spectral broadening of the biexciton resonance in CuCl due to collisions is in agreement with experimental results. 相似文献
29.
Groux LF Weiss T Reddy DN Chase PA Piers WE Ziegler T Parvez M Benet-Buchholz J 《Journal of the American Chemical Society》2005,127(6):1854-1869
The reactions of a series of Pd(II) methyl compounds of general formula LPd(NCCH(3))CH(3), where L is a bulky phenoxydiazene or phenoxyaldimine ligand with the polar olefin acrylonitrile (AN), are reported. The compounds react with an excess of AN to give the products of 2,1 insertion into the Pd-Me bond, yielding dimers and/or trimers which feature bridging alpha-cyano groups. The reactions were studied by low temperature (1)H NMR spectroscopy, revealing an initial formation of compounds featuring N-bound AN, which isomerized to an (unobserved) pi-bound species that rapidly underwent 2,1 insertion into the Pd-Me bond. Intermediate oligomeric complexes retaining a Pd-Me function were observed at low [AN] in these reactions. Under pseudo first-order conditions, k(obs) values of 8.5 x 10(-5) to 2.68 x 10(-3) M(-1) (-22 degrees C to 10 degrees C, 100 equiv of AN) and activation parameters of DeltaH++ = 14.4(5) kcal mol(-1) and DeltaS++ = -19(5) eu were obtained in one case. Comparison of the overall rates of insertion between two LPd(NCCH(3))CH(3), differing in the overall charge on the supporting ligand L, showed that the complex bearing a negatively charged ligand reacts with AN twice as fast as one with no anionic charge. The rates of insertion in both of these complexes are significantly faster than reported rates for analogous reactions in cationic Pd(II) derivatives, indicating that increasing the negative charge on the complex enhances the rate of AN insertion. These results provide fundamental mechanistic insights into a crucial reaction for incorporation of polar comonomers into alpha olefins via a coordination polymerization mechanism. 相似文献
30.
L.L. Chase 《Physics letters. A》1973,46(3):215-216
Raman scattering and electrical conductivity measurements have been performed on mixed single crystals of V1?xTixO2 system. The results show that the formation of homopolar bonds between vanadium ion pairs in the orthorhombic phase produces little alteration of the conduction and vibrational properties compared with the insulator-metal transition, which occurs at a slightly higher temperature. 相似文献