Loss coefficient for amplified luminescence of laser diode arrays

A system of radiative transfer equations is used to calculate the loss coefficient for amplified luminescence fluxes propagating along and transverse to the cavity axis in the active layer of high-power laser diode arrays taking the spreading of charge carriers in the cladding and contact layers of InGaAs/GaAs/AlGaAs heterostructures into account. It is shown that the spreading of charge carriers leads to a significant change in the amplified luminescence flux which can contribute up to 18% to the lasing threshold of these laser diode arrays. The calculated loss coefficients can greatly simplify the determination of the amplified luminescence fluxes in laser diode arrays with an error of less that 16% and can be used to determine how much the amplified luminescence affects the power and dynamic characteristics of diode arrays.     

Nanoengineering of methylene blue loaded silica encapsulated magnetite nanospheres and nanocapsules for photodynamic therapy

Core–shell nanostructures have emerged as an important class of functional materials with potential applications in diverse fields, especially in health sciences. In this article, nanoengineering of novel magnetic colloidal dispersion containing surface modifiable silica with a core of single domain magnetite nanoparticles loaded with photosensitizer (PS) drug “Methylene blue” (MB) has been described. Magnetite core is produced by the well-established chemical coprecipitation technique and silica shell is formed over it by the modified hydrolysis and condensation of TEOS (tetraethyl orthosilicate). Conditions for reaction kinetics have been established to tailor the core–shell structures in the form of nanospheres and nanocapsules. MB is loaded into the nanostructures by demethylation reaction. The major conclusion drawn from this study is that the synthesis route yields stable, non-aggregated MB loaded superparamagnetic magnetite-silica nanostructures with tailored morphology, tunable loading, and excellent magnetic properties.     

Three‐dimensional imaging of chemical phase transformations at the nanoscale with full‐field transmission X‐ray microscopy

The ability to probe morphology and phase distribution in complex systems at multiple length scales unravels the interplay of nano‐ and micrometer‐scale factors at the origin of macroscopic behavior. While different electron‐ and X‐ray‐based imaging techniques can be combined with spectroscopy at high resolutions, owing to experimental time limitations the resulting fields of view are too small to be representative of a composite sample. Here a new X‐ray imaging set‐up is proposed, combining full‐field transmission X‐ray microscopy (TXM) with X‐ray absorption near‐edge structure (XANES) spectroscopy to follow two‐dimensional and three‐dimensional morphological and chemical changes in large volumes at high resolution (tens of nanometers). TXM XANES imaging offers chemical speciation at the nanoscale in thick samples (>20 µm) with minimal preparation requirements. Further, its high throughput allows the analysis of large areas (up to millimeters) in minutes to a few hours. Proof of concept is provided using battery electrodes, although its versatility will lead to impact in a number of diverse research fields.     

Solution phase synthesis of a diverse library of highly substituted isoxazoles

The iodocyclization of O-methyloximes of 2-alkyn-1-ones affords 4-iodoisoxazoles, which undergo various palladium-catalyzed reactions to yield 3,4,5-trisubstituted isoxazoles. The palladium-catalyzed processes have been adapted to parallel synthesis utilizing commercially available boronic acid, acetylene, styrene, and amine sublibraries. Accordingly, a diverse 51-member library of 3,4,5-trisubstituted isoxazoles has been generated.     

Numerical investigation of the impingement of an oblique shock on a flat plate

Summary The unsteady, compressible Navier-Stokes equations in Reynolds-averaged variables are solved for a shock wave turbulent boundary layer interaction. For the free stream Mach number 3.7 and Reynolds number 8.202×10⁶ computation is performed using MacCormack's explicit-implicit finite difference scheme with 42×42 grid points. It is found that the peak heating amplification correlation agrees well with computational results.

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Numerische Untersuchung des Auftreffens einer schiefen Stoßwelle auf eine ebene Platte

Zusammenfassung Die Navier-Stokes-Gleichungen in instationärer, kompressibler Form mit Reynolds-gemittelten Variablen werden für die gegenseitige Beeinflussing einer Stoßwelle mit einer turbulenten Grenzschicht gelöst. Die Berechnung wird anhand des MacCormack's explizit-impliziten Finite-Differenzen-Verfahrens mit 42×42 Gitterpunkten für eine Freistrahl-Machzahl von 3,7 und einer Reynoldszahl von 8,202·10⁶ durchgeführt. Die Rechenergebnisse stimmen mit den Experimenten gut überein.

     

Normal coordinate analysis of tantalum(I) and niobium(I) hexahalide anions

Urey-Bradley force field (UBFF) and orbital valence force field (OVFF) techniques have been applied to the hexachloride and the hexabromide anions (O _h symmetry) of tantalum(I) and niobium(I). Trends in stretching force constants have been discussed on the basis of (i) the periodic position of the central metal atom and (ii) the nature of the halide ligands. Comments have been made also on the suitability of the force fields used.     

Rotational structures in the 125Cs nucleus

The collective band structures of the ¹²⁵Cs nucleus have been investigated by in-beam γ-ray spectroscopic techniques following the ¹¹⁰Pd ( ¹⁹F, 4n) reaction at 75MeV. The previously known level scheme, with rotational bands built on πg_7/2, πg_9/2 and πh_11/2 orbitals, has been extended and evolves into bands involving rotationally aligned ν(h_11/2)² and π(h_11/2)² quasiparticles. A strongly coupled band has been reassigned a high-K πh_11/2 ⊗ νg_7/2 ⊗ νh_11/2 three-quasiparticle configuration and a new side band likely to be its chiral partner has been identified. Configurations assigned to various bands are discussed in the framework of Principal/Tilted Axis Cranking (PAC/TAC) model calculations.     

Synthesis of Polylactide: Effect of Dispersion of the Initiator

The ring opening polymerization of L-lactide was studied in bulk using stannous octoate as initiator. In some experiments, triphenylphosphine, a Lewis base was also used as co-initiator. The polymerization was carried out at 130°C up to 29 h. The monomer was used after recrystallizing three times with dry toluene. Experiments were carried out using a wide range of monomer to initiator ratio. The averages and distributions of molar masses of resulting PLA have been determined by means of size exclusion chromatography, SEC. It is shown that the (mode, process) procedure of dispersion of the catalyst in polymerization system affects the molar mass distribution of the product as is evidenced by the bimodality or even trimodality observed in the SEC chromatograms.